Nanocarbon-Enhanced 2D Photoelectrodes:A New Paradigm in Photoelectrochemical Water Splitting

作     者：Jun Ke Fan He Hui Wu Siliu Lyu Jie Liu Bin Yang Zhongjian Li Qinghua Zhang Jian Chen Lecheng Lei Yang Hou Kostya Ostrikov Jun Ke;Fan He;Hui Wu;Siliu Lyu;Jie Liu;Bin Yang;Zhongjian Li;Qinghua Zhang;Jian Chen;Lecheng Lei;Yang Hou;Kostya Ostrikov

作者机构：Key Laboratory of Biomass Chemical Engineering of Ministry of EducationCollege of Chemical and Biological EngineeringZhejiang UniversityHangzhou 310012People’s Republic of China School of Chemistry and Environmental EngineeringWuhan Institute of Technology206 Guanggu 1st RoadWuhan 430205People’s Republic of China Department of Environmental Science and EngineeringNorth China Electric Power University619 Yonghua N StBaoding 071003People’s Republic of China Institute of Zhejiang University-QuzhouQuzhou 324000People’s Republic of China Ningbo Research InstituteZhejiang UniversityHangzhou 315100People’s Republic of China State Key Laboratory of Industrial Control TechnologyCollege of Control Science and EngineeringZhejiang UniversityHangzhou 310012People’s Republic of China School of Chemistry and Physics and Centre for Materials ScienceQueensland University of TechnologyBrisbaneQLD 4000Australia 

出 版 物：《Nano-Micro Letters》 (纳微快报（英文版）)

年 卷 期：2021年第13卷第2期

页      面：45-73页

核心收录：

学科分类：081705[工学-工业催化] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：the support from the National Natural Science Foundation of China(21878271,51702284,21878270,and 21961160742) the Zhejiang Provincial Natural Science Foundation of China(LR19B060002) the Fundamental Research Funds for the Central Universities the Startup Foundation for Hundred-Talent Program of Zhejiang University the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang(2019R01006) Key Laboratory of Marine Materials and Related Technologies,CAS Zhejiang Key Laboratory of Marine Materials and Protective Technologies(2020K10) the support of the NSFC 21501138 the Natural Science Foundation of Hubei Province(2019CFB556) Science Research Foundation of Wuhan Institute of Technology(K2019039) the Australian Research Council(ARC)and QUT Centre for Materials Science for partial support 

主　　题：Advanced nanocarbons Co-catalysts 2D layered structure Integrated photoelectrodes Photoelectrochemical water splitting 

摘      要：Solar-driven photoelectrochemical(PEC)water splitting systems are highly promising for converting solar energy into clean and sustainable chemical *** such PEC systems,an integrated photoelectrode incorporates a light harvester for absorbing solar energy,an interlayer for transporting photogenerated charge carriers,and a co-catalyst for triggering redox ***,understanding the correlations between the intrinsic structural properties and functions of the photoelectrodes is *** we critically examine various 2D layered photoanodes/photocathodes,including graphitic carbon nitrides,transition metal dichalcogenides,layered double hydroxides,layered bismuth oxyhalide nanosheets,and MXenes,combined with advanced nanocarbons(carbon dots,carbon nanotubes,graphene,and graphdiyne)as co-catalysts to assemble integrated photoelectrodes for oxygen evolution/hydrogen evolution *** fundamental principles of PEC water splitting and physicochemical properties of photoelectrodes and the associated catalytic reactions are *** strategies for the assembly of 2D photoelectrodes with nanocarbons to enhance the PEC performances are *** mechanisms of interplay of 2D photoelectrodes and nanocarbon co-catalysts are further *** challenges and opportunities in the field are identified to guide future research for maximizing the conversion efficiency of PEC water splitting.