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A facile solution phase synthesis of directly ordering monodisperse FePt nanoparticles

直接订 monodisperse FePt nanoparticles 的灵巧的答案阶段合成

作     者:Yongsheng Yu Lin He Junjie Xu Jiaming Li Sida Jiang Guanghui Han Baojiang Jiang Wenjuan Lei Weiwei Yang Yanglong Hou Yongsheng Yu;Lin He;Junjie Xu;Jiaming Li;Sida Jiang;Guanghui Han;Baojiang Jiang;Wenjuan Lei;Weiwei Yang;Yanglong Hou

作者机构:MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and StorageSchool of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001China Beijing Key Laboratory for Magnetoelectric Materials and Devices(BKL-MMD)Beijing Innovation Center for Engineering Science and Advanced Technology(BIC-ESAT)School of Materials Science and EngineeringPeking UniversityBeijing 100871China School of PhysicsHarbin Institute of TechnologyHarbin 150001China Research Center of Basic Space ScienceHarbin Institute of TechnologyHarbin 150001China Key Laboratory of Functional Inorganic Material ChemistryMinistry of Education of the Peoples Republic of ChinaHeilongjiang UniversityHarbin 150080China 

出 版 物:《Nano Research》 (纳米研究(英文版))

年 卷 期:2022年第15卷第1期

页      面:446-451页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 070205[理学-凝聚态物理] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0702[理学-物理学] 

基  金:supported by the National Natural Science Foundation of China under Grant(Nos.51871078,51631001 and 51590882) the National Key R&D Program of China(No.2016YFA0200102) Heilongjiang Science Foundation(No.E2018028) 

主  题:L1_(0)-FePt direct ordering nanoparticles magnetic properties 

摘      要:The ordered Pt-based intermetallic nanoparticles(NPs)with small size show superior magnetic or catalytic properties,but the synthesis of these NPs still remains a great challenge due to the requirement of high temperature annealing for the formation of the ordered phase,which usually leads to sintering of the ***,we report a simple approach to directly synthesize monodisperse ordered L1_(0)-FePt NPs with average size 10.7 nm without further annealing or doping the third metal atoms,in which hexadecyltrimethylammonium chloride(CTAC)was found to be the key inducing agent for the thermodynamic growth of the Fe and Pt atoms into the ordered intermetallic structure in the synthetic *** particular,10.7 nm L1_(0)-FePt NPs synthesized by the proper amount of CTAC show a coercivity of 3.15 kOe and saturation magnetization of 45 emu/g at room *** current CTAC-assisted synthetic strategy makes it possible to deeply understand the formation of the ordered Pt-based intermetallic NP in solution phase synthesis.

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