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Corrosion mechanism of Ti2AlC MAX phase coatings under the synergistic effects of water vapor and solid NaCl at 600 °C

在 synergistic 下面的 Ti2AlC 最大阶段涂层的腐蚀机制在 600 点水完成蒸汽和稳固的 NaCl ?° C

作     者:Wang, Zhenyu Ma, Guanshui Li, Zhongchang Ruan, Haitao Yuan, Jianghuai Wang, Li Ke, Peiling Wang, Aiying 

作者机构:Ningbo Inst Ind Technol Ningbo 315201 Peoples R China Chinese Acad Sci Ningbo Inst Mat Technol & Engn Zhejiang Key Lab Marine Mat & Protect Technol Key Lab Marine Mat & Related Technol Ningbo 315201 Peoples R China 

出 版 物:《CORROSION SCIENCE》 (腐蚀科学)

年 卷 期:2021年第192卷

页      面:109788-109788页

核心收录:

学科分类:080503[工学-材料加工工程] 0806[工学-冶金工程] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 

基  金:National Science and Technology Major Project [2017-VII-0012-0108] National Natural Science Foun-dation of China [52025014, 52171090, 51901238] Natural Science Foundation of Ningbo [202003N4025] 

主  题:A Sputtered films A Ceramic B STEM C Interface C High temperature corrosion 

摘      要:The corrosion behavior of Ti2AlC MAX phase coatings coated on 1Cr11Ni2W2MoV substrates in NaCl deposit in water vapor at 600 degrees C has been fully investigated. The results demonstrated that the substrates underwent serious corrosion, but the coatings performed better. The mass gain per unit area of coatings was less than 1/6 of substrates, because of the formed compact and uniform corrosion scale. Such dense corrosion scale was composed of NaxTiyOz fine grains with the size of 11 +/- 0.4 nm and amorphous Al2O3 phases which self-healed the generated defects during corrosion, benefiting from the novel layered structure of MAX phase.

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