Recent advances in fire-retardant carbon-based polymeric nanocomposites through fighting free radicals

作     者：Ting Sai Shiya Ran Zhenghong Guo Pingan Song Zhengping Fang 

作者机构：Laboratory of Polymer Materials and EngineeringNingboTech UniversityNingboChina MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhouChina Center for Future MaterialsUniversity of Southern QueenslandSpringfield CentralQueenslandAustralia School of Agriculture and Environmental ScienceUniversity of Southern QueenslandSpringfield CentralQueenslandAustralia 

出 版 物：《SusMat》 (可持续发展材料（英文）)

年 卷 期：2022年第2卷第4期

页      面：411-434页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：This work was financially supported by the National Natural Science Foundation of China(grant numbers:51991355,51873196,and 52173083) the Australian Research Council(grant numbers:FT190100188 and DP190102992) the Non-profit Project of Science and Technology Department of Ningbo(grant number:2019C50029) Public Technical Application Project of Zhejiang in Industry(grant number:LGG21E030004) 

主　　题：fire retardants free radical capturers polymer nanocomposites thermal stability 

摘      要：Polymeric materials are ubiquitously utilized in modern society and continuously improve quality of ***,most of them suffer from intrinsic flammability,significantly limiting their practical ***,free-radical reaction is a critical“triggerfor their thermal pyrolysis and following combustion process regardless of the anaerobic thermal pyrolysis in the condensed phase or aerobic combustion of polymers in the gaseous *** addition of free radical scavengers represents a promising and effective means to enhance the fire safety of polymeric *** review aims to offer a state-of-the-art overview on the creation of fire-retardant polymeric nanocomposites by adding fire retardants with an ability to trap free *** specific modes of action(condensed-phase action,gaseous-phase action,and dual-phases action)and performances in some typical polymers are reviewed and discussed in *** this,some key challenges associated with these free-radical capturers are discussed,and design strategies are also *** review provides some insights into the modes of action of free radical capturing agents and paves the avenue for the design of advanced fire-retardant polymeric nanocomposites for expanded real-world applications in industries.