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作者机构:Key Laboratory of Rubber-PlasticsMinistry of EducationQingdao University of Science&TechnologyQingdao266042China State Key Laboratory of Chemical Resource EngineeringBeijing University of Chemical TechnologyBeijing100029China
出 版 物:《Chinese Journal of Polymer Science》 (高分子科学(英文版))
年 卷 期:2022年第40卷第11期
页 面:1493-1502页
核心收录:
学科分类:08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学]
主 题:Illite SBR Composite Dynamic hysteresis loss Static mechanical properties
摘 要:Despite growing interest in nano-sized fillers,micro-sized fillers with desired compatibility are still used for reinforcing rubbers,owing to their lower production cost and easier processing relative to nano-sized ***,the abundant and eco-friendly clay minerals are recognized as the materials of the twenty-first ***,illite,a naturally occurring clay having dimension in micrometric scale,has been selected as filler to reinforce the *** improve the compatibility of illite with SBR,the illite was modified by either bis[3-(triethoxysilyl)propyl]tetrasulfide(Si69-illite)or 3-mercaptopropyltriethoxysilane(KH580-illite).The interfacial interactions of SBR composites filled with pristine illite(illite/SBR)and Si69-illite(Si69-illite/SBR),or KH580-illite(KH580-illite/SBR)were characterized by bound rubber content and Payne effect measurements,while dynamic hysteresis losses of these uncured and cured composites were also analyzed under various strain *** was found that the filler-rubber interactions were greatly improved for Si69-illite/SBR and KH580-illite/SBR systems compared to the illite/SBR *** leads to an increment of modulus at 300%strain of the composites from 3.46 MPa for illite/SBR to 7.70 MPa for Si69-illite/SBR and12.96 MPa for KH580-illite/***,lower rolling resistance and better wear resistance without compromising wet traction of Si69-illite/SBR and KH580-illite/SBR have been *** demonstrates the high possibility of Si69 and KH580 modified illites as promising alternative fillers for reinforcing rubbers.