Ru(II)-Catalyzed ortho C-H Allylation of N-Aryl-7-azaindoles with 2-Methylidene Cyclic Carbonate

作     者：Jing Zhang Quan-Jian Luo Han-Chi Wang Jin-Heng Li Bo Sun Jing Zhang;Quan-Jian Luo;Han-Chi Wang;Jin-Heng Li;Bo Sun

作者机构：State Key Laboratory Base of Eco-Chemical EngineeringCollege of Chemical EngineeringQingdao University of Science and Technology QingdaoShandong266042China State key Laboratory of Applied Organic ChemistryLanzhou University LanzhouGansu 7300ooChina School of Chemistry and Chemical EngineeringHenan Normal UniversityXinxiangHenan 453007China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2024年第42卷第9期

页      面：985-989页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the Natural Science Foundation of Shandong Province(ZR2019BB011) the Scientific Research Foundation of Qingdao University of Science&Technology(010029022) 

主　　题：Ru(II) Allylation N-Aryl-7-azaindoles Cyclic carbonates Heterocyclic compounds C-H activation 

摘      要：A Ru(II)-catalyzed ortho allylation reaction of N-aryl-7-azaindole with readily available 2-methylidene cyclic carbonate has been *** reaction is an effective pathway for synthesizing 7-azaindole derivatives with a wide scope of substrates and high *** addition,the method can be extended to the allylation of other heterocyclic compounds and several cyclic carbonates,highlighting the practicality of this strategy for synthesis.