Effect of Process Variable on Production of Thermoplastic Vulcanizates Based on Sebs/Pp/Lldpe Via Reactive Extrusion

作     者：Dana, Mehri Zohuri, Gholam Hossein Nabid, Mohammad Reza Shahidi, Saeid Asadi Yazdanbakhsh, Sohail 

作者机构：Department of Polymer & Materials Chemistry Faculty of Chemistry and Petroleum Science Shahid Beheshti University GC ***Tehran Iran Department of Materials Engineering Pouya Gostar Khorasan Co. of Part Lastic Group Mashhad Iran Department of Chemistry Faculty of Science Ferdowsi University of Mashhad Mashhad Iran Environmental Chemistry Research Centre Department of Chemistry Faculty of Science Ferdowsi University of Mashhad Mashhad Iran 

出 版 物：《SSRN》 

年 卷 期：2024年

核心收录：

主　　题：Tensile strength 

摘      要：Properties of thermoplastic vulcanizates (TPVs) depend on their microstructure. Processing conditions including shear rate, processing temperature and shearing time can affect the final microstructure of TPVs. The object of this study is to investigate the effect of temperature (210-230 °C, 170-190 °C, 150-170 °C and 140-160 °C) and speed of production process on the properties of TPV based on poly(styrene-b-(ethylene-co-butylene)-b styrene) triblock copolymer (SEBS)/ polypropylene (PP)/ linear low-density polyethylene (LLDPE) prepared via reactive extrusion. Melt flow index (MFI) of the prepared samples was sharply decreased (from 24.4 to 2.63 g/10 min at 190 °C, 10 kg) with decreasing temperature (from 210-230 °C to 170-190 °C). However, hardness of the prepared TPVs was increased to a limiting value (80 shore A) with decreasing the process temperature. Compression set sharply decreased (from 70% to 49% at 120 °C, 70 h) and it has reached to a limiting value (46%). The process temperature, however, is not significantly affected on the tensile strength and tensile strength at 20% extension of the TPV. The elongation has the lowest value in 170-190 °C. Result of elongation at break after aging was improved (from 12.2% to 3.3%) with decreasing process temperature (from 140-160 °C to 210-230 °C). The lowest value of tensile strength (4.1%) was obtained in 170-190 °C after aging. Due to the increase in speeds of the twin screw extruder (180 to 250 rpm, in 140-160 °C) surface quality was suitable and smooth. Also TPV samples were prepared by either one-step or two-step reactors using the extruder system and the results were compared. In the one-step method, a pronounced higher value in elongation at break (897%) and MFI (6.8 g/10min at 190 °C, 10 kg) were observed. It was found that the results of heat aging were improved using the two-step process. The two-step process led to higher tensile stress at 20% extension (from 2.7 to 3.3 MPa), too. In addition, a comprehensiv