Impregnating photo-stable gold precursor onto uncalcined TS-1 to boost catalytic hydro-oxidation of propane

作     者：Zhihua Zhang Erchuan Yang Fan Liu Kesheng Xu Yuxia Zhong Jinwei Sun Shudong Shi Xuezhi Duan Xinggui Zhou 

作者机构：State Key Laboratory of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237China 

出 版 物：《Science China Chemistry》 (中国科学(化学英文版))

年 卷 期：2025年第68卷第4期

页      面：1585-1596页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the National Natural Science Foundation of China(22208093,22038003,22178100,and 21922803) the Ministry of Science and Technology of the People's Republic of China under the Research Fund for National Key R&D Program of China(2021YFA1501403) the Program of Shanghai Academic/Technology Research Leader(21XD1421000) the Shanghai Science and Technology Innovation Action Plan(22JC1403800) the Innovation Program of the Shanghai Municipal Education Commission 

主　　题：hydro-oxidation of propane acetone Au-Ti bifunctional catalysts IWI method thiol ligands stability 

摘      要：Immobilizing highly dispersed Au nanoparticles onto titanium silicalite-1(TS-1)by a simple impregnation method under light is still a challenging *** this work;a high photostable Au precursor protected by thiol ligands was firstly synthesized;and the as-prepared Au precursor displayed excellent stability under light for over 30 days;while the Au precursor without thiol ligands formed precipitates after just 2 h under ***;the Au precursor protected by thiol ligands was immobilized on the external surface of uncalcined TS-1(i.e.;TS-1-B)by the incipient wetness impregnation method(IWI method)to prepare Au/TS-1-B *** activity of as-prepared Au/TS-1-B catalyst in the hydro-oxidation of propane to acetone was 1.4 times higher than that of the catalyst prepared by the deposition-precipitation urea method(DPU method).The structures of the Au/TS-1-B catalysts prepared by different methods were analyzed by multiple *** to the Au/TS-1-B catalyst prepared by the DPU method;the Au/TS-1-B catalyst synthesized by the IWI method exhibited a narrower size distribution of Au nanoparticles and had more small Au particles(2 nm);which is the main reason for its superior ***;the effects of gold loadings;reaction temperature and Si/Ti molar ratio on the catalytic performance of the Au/TS-1-B catalyst prepared by the IWI method were also *** addition;the Au/TS-1-B catalyst prepared by the IWI method also exhibited excellent stability for over 140 h.