版权所有:内蒙古大学图书馆 技术提供:维普资讯• 智图
内蒙古自治区呼和浩特市赛罕区大学西街235号 邮编: 010021
作者机构:Taiyuan Univ Technol Coll Min & Technol Taiyuan 030024 Peoples R China Jinneng Holding Coal Grp Yanzishan Mine Taiyuan 030024 Peoples R China
出 版 物:《MICROPOROUS AND MESOPOROUS MATERIALS》 (Microporous Mesoporous Mater.)
年 卷 期:2025年第390卷
核心收录:
学科分类:0817[工学-化学工程与技术] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学]
基 金:National Natural science Foundation of China
主 题:Spontaneous coal combustion Physical adsorption Kinetics Noise algorithm Numerical simulation
摘 要:In view of the difficulty of accurately characterizing the dynamic process of coal-oxygen physisorption using existing models, this study constructed three-dimensional (3D) porous adsorption models of coal based on a noise algorithm, and the kinetics of coal oxygen physisorption was investigated based on this model. The degree of metamorphism and pore characteristics of the coal samples were determined via industrial analysis and pore structure characterization, and high-pressure isothermal adsorption experiments were carried out to determine the isothermal adsorption lines of coal oxygen at different temperatures. The experimental data were fitted to construct a mathematical model under the joint influence of temperature and pressure, and a 3D porous adsorption model for coal was constructed based on the experimental results to explore the adsorption kinetic process. Revealing that the amount of oxygen adsorbed was negatively correlated with temperature, and coal samples with less deterioration possessed larger specific surface areas and pore volumes, resulting in a stronger oxygen adsorption ability. The coal-oxygen isothermal adsorption data fitted well with the Langmuir adsorption model, and the fitted oxygen adsorption values were similar to the experimental data. Numerical simulations using the constructed models indicated that the adsorption process of oxygen on the coal particle surface could be divided into three stages: (1) the seepage stage, in which oxygen is adsorbed by the outer surface of the coal body and its surface pores;(2) the surface diffusion stage, in which oxygen diffuses to the inner region of the coal particles through their pores;and (3) the deep adsorption stage, in which oxygen is adsorbed in the deep pores of the coal particles, enabling complete adsorption. Coal-oxygen adsorption reached equilibrium in a short time, the amount of oxygen adsorbed rapidly increased during the initial stage of adsorption, approaching the maximum value at