Surface morphology of thin polypyrrole films electrodeposited along aqueous electrolyte-organic liquid interface. Influence of temperature and solvent

作     者：Wojcik, Kamil Grzeszczuk, Maria 

作者机构：Univ Wroclaw Fac Chem PL-50383 Wroclaw Poland 

出 版 物：《JOURNAL OF SOLID STATE ELECTROCHEMISTRY》 (固体电化学杂志)

年 卷 期：2015年第19卷第5期

页      面：1293-1300页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

主　　题：Conducting polymers Electrodeposition Liquid-liquid interface Three-phase electrode SEM micrographs 

摘      要：Nitrobenzene was found dissimilar to 1,2-dichloroethane and chloroform in electrodeposition of electronically conducting polypyrrole at a water/organic solvent junction by means of the three-phase electrode. Morphologies of the two sides of the potentiostatically deposited, freestanding thin polymer films differ distinctly which might be of interest for specific applications. A low temperature of the synthesis at the liquid-liquid junction is preferable for attaining the homogeneous surface morphologies of the polymer films.