Preparation and Characterization of Singlehanded Helical Carbonaceous Nanofibers using 1,4-Phenylene Bridged Polybissilsesquioxanes

作     者：肖泽丽 GUO Yongmin 李宝宗 LI Yi 

作者机构：Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application Department of Polymer Science and Engineering College of Chemistry Chemical Engineering and Materials Science Sooehow University Suzhou 215123 China 

出 版 物：《Journal of Wuhan University of Technology(Materials Science)》 (武汉理工大学学报（材料科学英文版）)

年 卷 期：2016年第31卷第5期

页      面：1149-1154页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：Funded by the National Natural Science Foundation of China(No.21574095) the Priority Academic Program Development of Jiangsu High Education Institutions(PAPD) 

主　　题：helicity carbon optical activity nanofibers 

摘      要：Single-handed helical carbonaceous materials attracted much attention for varieties of potential applications. Herein, single-handed helical 1, 4-phenylene bridged polybissilsesquioxane nanofibers were prepared through a supramolecular templating approach using a pair of enantiomers. After carbonization at 700 ℃ for 2.0 h and removal of silica using HF aqueous solution, single-handed helical carbonaceous nanofibers were obtained. The obtained samples were characterized using the field-emission scanning electron microscopy, transmission electron microscopy, N_2 sorptions, X-ray diffraction, Raman spectroscopy and diffuse reflectance circular dichroism（DRCD）. The Raman spectrum indicated that the carbon was amorphous. The DRCD spectra indicated that the carbonaceous nanofibers exhibited optical activity. The surface area of the left-handed helical carbonaceous nanofibers was 907 m^2/g. Such material has potential applications as chirality sensor and supercapacitor electrode.