Formulation- Properties Versatility of Wood Fiber Biocomposites Based on Polylactide and Polylactide/ Thermoplastic Starch Blends

作     者：Mihai, Mihaela Legros, Nathalie Alemdar, Ayse 

作者机构：Natl Res Council Canada Quebec City PQ J4B 6Y4 Canada FPInnovat Wood Biomat Dept Quebec City PQ G1P 4R4 Canada 

出 版 物：《POLYMER ENGINEERING AND SCIENCE》 (聚合物工程与科学)

年 卷 期：2014年第54卷第6期

页      面：1325-1340页

核心收录：

学科分类：0817[工学-化学工程与技术] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 

主　　题：Wood fibres Fiber programmable logic arrays Blends BIOCOMPOSITE Polylactides Tensile Strength transaction processing system 

摘      要：This article discusses the interrelation between formulation, processing, and properties of biocomposites composed of a bioplastic reinforced with wood fibers. Polylactide (PLA) and polylactide/thermoplastic starch blends (PLA/TPS) were used as polymeric matrices. Two grades of PLA, an amorphous and a semicrystalline one, were studied. TPS content in the PLA/TPS blends was set at 30, 50, and 70 wt%. Two types of wood fiber were selected, a hardwood (HW) and a softwood (SW), to investigate the effect of the fiber type on the biocomposite properties. Finally, the impact of different additives on biocomposite properties was studied with the purpose to enhance the bioplastic/wood fiber adhesion and, therefore, the final mechanical performance. The biocomposites containing 30 wt% of wood fibers were obtained by twin-screw extrusion. The properties of the biocomposites are described in terms of morphology, thermal, rheological, and mechanical properties. Furthermore, the biocomposites were tested for humidity and water absorption and biodegradability. An almost 100% increase in elastic modulus and 25% in tensile strength were observed for PLA/wood fiber biocomposite with the best compatibilization strategy used. The presence of the TPS in the biocomposites at 30 and 50 wt% maintained the tensile strength higher or at least equal as for the virgin PLA. These superior tensile results were due to the inherent affinity between the matrices and wood fibers improved by the addition of a combination of coupling and a branching agent. In addition to their outstanding mechanical performance, the biocomposites showed high biodegradation within 60 days. POLYM. ENG. SCI., 54:1325-1340, 2014. (c) Her Majesty the Queen in Right of Canada 2013