新配合物[Cd(H_2O)_2(phen)_2](PA)_2的制备及晶体结构

作     者：李大光 傅维勤 游效曾 Wei Chen 

作者机构：广东工业大学轻工化工学院 南京大学配位化学研究所南京210093 南京大学配位化学研究所 马来亚大学化学系 

出 版 物：《无机化学学报》 (Chinese Journal of Inorganic Chemistry)

年 卷 期：2002年第18卷第2期

页      面：209-213页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：国家自然科学基金资助项目(No.29631040) 

主　　题：Cd(Ⅱ)配合物 二氮杂菲 苦味酸盐 晶体结构 制备 含能材料 镉配合物 

摘      要：The new compound was prepared by the reaction of Cd(ClO4)2·6H2O,1,10 phenanthroline (phen)and picric acid (HPA)(ratio 1∶3∶2) in methanol aqueous solution refluxing for 4 hours. The crystals used for X ray analysis was obtained by slow evaporation of the solution at room temperature. The crystal compound is in triclinic with space group with a=1.1363(4)nm,b=1.2593(2)nm,c=1.3972(4)nm,α=93.97(2)?,β=100.84(3)?,γ=106.29(2)?,Z=2,V=1.8690(9)nm3,Dc=1.715g·cm-3, μ(MoKα)=0.677mm-1,F(000)=972,R=0.0907,wR=0.2240. In the complex, the Cd? cation is octahedrally coordinated to two 1,10 phenanthroline ligands and two water molecules incis disposition. As outer sphere, picrate anions are combined with inner by hydrogen bond and static electricity interaction.