Matrix-bound phosphine in Ny-Alesund Area of Arctic

作     者：封颖 Wang Qiang Yao Ziwei Geng Jinju 

作者机构：Institute of Science and Technology Information of China Beijing 100038P. R. China College of Environmental Science and Engineering Peking University Beijing 100871 P. R. China National Marine Environmental Monitoring Center Dalian 116023 P. R. China State Key Laboratory of Pollution Control and Resource Reuse School of Environment Nanjing University Nanjing 210093 P. R. China 

出 版 物：《High Technology Letters》 (高技术通讯（英文版）)

年 卷 期：2009年第15卷第3期

页      面：331-336页

核心收录：

学科分类：070902[理学-地球化学] 0709[理学-地质学] 07[理学] 

基　　金：Supported by the National High Technology. Research and Development Program of China (No. 2008AA09Z114) the Polar Science Research Founda- tion (No. 20070214) the Opening Foundation of State Key Laboratory of Pollution Control and Resource Reuse of Nanjing University (No. PCRRF08016) the National Ocean Science Foundation (No. 2008614) 

主　　题：matrix-bound phosphine （MBP） Arctic Pole area distribution Porg rock 

摘      要：Phosphine, a ubiquitous trace gas in the atmosphere, acts as a carrier of gasous phosphorus in the biogeochemical cycle. The research of phosphine will show new light on the mechanisms of how the phos- phorus supplement influence the biogeochemical cycle and global wanning. In this paper, we detect the phosphine in Arctic Pole area for the first time. The result shows that matrix-bound phosphine（MBP） ex- ists in all the samplings. Phosphine distributions varied with different environmental origins. Average phosphine concentrations in tundra soil, lake sediments, sea sediments, seabird-droppings and deer guanos were 14.17ng/kg dry, 35.44 kg dry, 67.20 kg dry, 32.9 ng/kg dry, and 25.52 ng/kg dry re- spectively. Correlation analysis shows that there is an obviously positive correlation between Porg and MBP. It could be concluded that anaerobic decomposition of Porg and the mechano-chemistry action of the rock probably are the possible reasons explaining the mechanism of MBP production in Arctic Pole area.