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作者机构:Nagoya Inst Technol Grad Sch Engn Dept Environm Technol Showa Ku Nagoya Aichi 4668555 Japan Olympus Co Ltd Tatsuno Nagano 3990495 Japan Nanyang Technol Univ Sch Elect & Elect Engn Singapore 639798 Singapore
出 版 物:《SURFACE SCIENCE》 (Surf Sci)
年 卷 期:2006年第600卷第18期
页 面:3663-3667页
核心收录:
学科分类:07[理学] 070203[理学-原子与分子物理] 0703[理学-化学] 0702[理学-物理学]
基 金:ASTAR, (022-101-0033) NITECH Agency for Science, Technology and Research, A*STAR Japan Society for the Promotion of Science, KAKEN, (15360007)
主 题:nanostructure sputtering C ZnO
摘 要:A very simple method to synthesize densely distributed carbon nanofibers. (CNFs) on flexible plastic substrates at room temperature with no catalyst is demonstrated. Carbon film was deposited onto polyimide, poly-ethylene-terephthalate (PET) films, Si plates and a Ni mesh, which were then sputtered with obliquely incident Ar+ ions at 3 keV at room temperature. Linear-shaped CNFs oriented in the incidence direction of the ion beam grew on the sputtered substrates, as confirmed by scanning (SEM) and transmission electron microscopes (TEM). CNF growth on a PET substrate, which is a non-heat-tolerant plastic, has never been reported so far. CNFs thus grown were characterized as amorphous without a hollow structure. The diameter of CNFs was almost identical (20-30 nm) despite a large difference in CNF length (0.1-4 mu m). In addition, the CNF-tipped cones were demonstrated to act successfully as a template to fabricate one dimensional (1-D) zinc oxide (ZnO) nanostructures on a PET substrate. Thus, it was believed that the ion-irradiation technique would open up a new approach to fabricate any kinds of 1-D nanomaterials on flexible substrates at room temperature. (c) 2006 Elsevier B.V. All rights reserved.