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Electrophoretic Deposition of Polymer Chains on an Adsorbing Surface in (2+1) Dimensions: Conformational Anisotropy and Nonuniversal Coverage

作     者:Grace M. Foo R. B. Pandey 

作者机构:Supercomputing and Visualization Unit Computer Center National University of Singapore Singapore 119260 Department of Physics and Astronomy University of Southern Mississippi Hattiesburg Mississippi 39406-5046 

出 版 物:《Physical Review Letters》 (Phys Rev Lett)

年 卷 期:1998年第80卷第17期

页      面:3767-3767页

核心收录:

学科分类:07[理学] 0702[理学-物理学] 

摘      要:Electrophoretic deposition of polymer chains flowing in a (2+1)-dimensional system is studied by computer simulations. Steady-state surface coverage (θj) is found to decay with the chain s length, i.e., θj∼Lc−α with a nonuniversal exponent α≃0.0–0.9 depending on the magnitude of driving field and temperature. Conformational crossover occurs for chains from a surface or wall to an adjacent bulk region with different scaling exponents for their longitudinal and transverse spread.

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