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作者机构:Guelph-Waterloo Program for Graduate Work in Physics and Department of Physics University of Waterloo Waterloo Ontario Canada N2L 3G1
出 版 物:《Physical Review E》 (物理学评论E辑:统计、非线性和软体物理学)
年 卷 期:1998年第57卷第3期
页 面:3652-3652页
核心收录:
学科分类:07[理学] 070203[理学-原子与分子物理] 0702[理学-物理学]
摘 要:A dendrimer is a hyperbranched macromolecule that is grown from a central core generation by generation. We demonstrate through Monte Carlo simulations of a dendrimer model in two dimensions that when the terminal monomers and the interior monomers interact through an effective Flory-Huggins parameter χ, an angularly dependent domain structure forms in the molecule for sufficiently large χ. Based on the simulation data, we further show that the formation of the domain pattern is a smooth crossover, not a phase transition, from a mixed structure.