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Study on the electric double layer of a cylindrical reverse micelle with functional theoretical approach

Study on the electric double layer of a cylindrical reverse micelle with functional theoretical approach

作     者:WANG Zhengwu1,2, GUO Baomin2, ZHANG Gexin1 & YU Huixin1 1. Key Laboratory of Industrial Biotechnology of Ministry of Education, Southern Yangtze University, Wuxi 214036, China 2. School of Chemical and Material Engineering, Southern Yangtze University, Wuxi 214036, China 

作者机构:1. Key Laboratory of Industrial Biotechnology of Ministry of Education Southern Yangtze University Wuxi 214036 China 2. School of Chemical and Material Engineering Southern Yangtze University Wuxi 214036 China 

出 版 物:《Science China Chemistry》 (中国科学(化学英文版))

年 卷 期:2006年第49卷第3期

页      面:219-224页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基  金:This work was supported by the National Natural Science Foundation of China (Grant Nos.20473034 and 20573048) the Open Project Program of the Key Laboratory of Industrial Biotechnology, Ministry of Education of China (Grant No. KLIB-KF200504) 

主  题:cylindrical reverse micelle, electrostatic double layer, Poisson-Boltzmann equation, functional analytic theory. 

摘      要:The iterative method in functional analysis is applied to looking for asolution of the Poisson-Boltzmann equation in order to describe the problems of the distribution ofthe potentials in the electric double layer (EDL) inside the water pool for a cylindrical inversemicelle. Potentials as a function of the position of a particular point in EDL are computed, whichdisplay a quantitative agreement with those from earlier calculation of Debye and Huckel in the caseof low potentials. But it is also shown that in the higher-potential range the iterativecalculations can give more accurate results. These results indicate the utility of this functionalanalysis technique in the description of the properties of EDL for a cylindrical inverse micelle.

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