一种新型杂化单晶[Ga_3(PO_4)_3F_2]H_3O·(H_3NCH_2CH_2)_2NH_2的合成与结构表征

作     者：姚有为 赵永男 乐善堂 徐恒连 梁宏斌 赵大庆 

作者机构：中国科学院长春应用化学研究所稀土化学与物理开放实验室长春130022 中国科学院北京物理研究所凝聚态物理研究中心北京100080 黑龙江省科学院技术物理研究所哈尔滨150086 

出 版 物：《高等学校化学学报》 (Chemical Journal of Chinese Universities)

年 卷 期：2001年第22卷第9期

页      面：1450-1452页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：磷酸镓 水热合成 二乙烯三胺 [Ga3(PO4)3]H3O·(H3NCH2CH2)2NH2 结合表征 杂化单晶 空旷骨架磷酸盐化合物 

摘      要：A novel three dimensional fluorinated gallium phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a =1.605 6(7) nm, b = 1 011 4 (4) nm, c =1.854 6(5) nm, V =3.011 6(19) nm 3, Z =4. The three dimensional framework based on linkage of corner sharing polyhedron PO 4, GaO 4F and GaO 4F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.