Improvement in Toughness of Poly(ethyiene 2,5-furandicarboxyiate) by Melt Blending with Bio-based Polyamidel 1 in the Presence of a Reactive Compatibilizer

作     者：Yong Yang An-Ping Tian Ya-Jin Fang Jing-Gang Wang Jin Zhu 

作者机构：Key Laboratory of Bio based Polymeric Materials Technology and Application of Zhejiang ProvinceNingbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China Weihai Honglin Electronic TechnologyCOLTDWeihai 264205 China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2020年第38卷第10期

页      面：1099-1106,I0006页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：This work was financially supported by the National Natural Science Foundation of China(No.51803224) 

主　　题：Poly(ethylene 2.5-furandicarboxylate) Polyamide11 Bio based polymers Reactive compatibilization Toughening 

摘      要：The objective of this study was to improve the toughness of bio based brittle poly(ethylene 2,5-furandicarboxylate)(PEF)by melt blending with bio based polyamide11(PA11)in the presence of a reactive multifunctional epoxy compatibilizer(Joncryl ADR-4368).The morphological,thermal,rheological,and mechanical properties of PEF/PA11 blends were *** with neat PEF,the toughness of PEF/PA11 blend was not improved in the absence of the reactive compatibilizer due to the poor compatibility between the two *** Joncryl was incorporated into PEF/PA11 blends,the interfacial tension between PEF and PA11 was obviously reduced,reflecting in the fine average particle size and narrow distribution of PA11 dispersed phase as observed by scanning electron microscopy(SEM).The complex viscosities of PEF/PA11 blends with Joncryl were much higher than that of PEF/PA11 blend,which could be ascribed to the formation of graft copolymers through the epoxy groups of Joncryl reacting with the end groups of PEF and PA11 molecular ***,the compatibility and interfacial adhesion between PEF and PA11 were greatly improved in the presence of *** compatibilized PEF/PA11 blend with 1.5 phr Joncryl exhibited significantly improved elongation at break and unnotch impact strength with values of 90.1%and 30.3kJ/m2,respectively,compared with those of 3.6%and 3.8 kJ/m2 for neat PEF,*** work provides an effective approach to improve the toughness of PEF which may expand its widespread application in packaging.