A number of phenanthroline functionalized imidazolium and triazolium salts from 2-iodo-1,10-phenanthroline and imidazole and triazole derivatives have been prepared. Simple reactions of these imidazolium salts with co...
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A number of phenanthroline functionalized imidazolium and triazolium salts from 2-iodo-1,10-phenanthroline and imidazole and triazole derivatives have been prepared. Simple reactions of these imidazolium salts with copper powder at room temperature have afforded a series of dinuclear copper(I)-NHC complexes doubly bridged by N-(1,10-phenanthrolin-2-yl)imidazolylidene ligands in excellent yields. The two Phen-NHC ligands are either head-to-head or head-to-tail arranged depending upon the steric repulsion of the substituents. Reactions of imidazolium halides and copper yielded dinuclear complexes [Cu2(μ-X)(L6)2]X(X = Cl, Br, I) in nearly quantitative yields. The dinuclear [Cu2(L10)2(μ-Me CN)]2+ was similarly obtained through 1,2,4-triazolium salts and copper, and the compound consists of a bridging CH3 CN molecule representing the first example of Cu-NHC complexes with a 3c-2e bond. These Cu(I) complexes have been characterized by NMR spectra, elemental analysis, and further confirmed by X-ray diffraction analysis. These dinuclear copper-NHC complexes are highly active for cycloaddition reaction of alkynes and azides at room temperature.
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