Water pollution caused by CrO(4)(2-)has become a global concern due to its high aqueous solubility and good mobility in the underground environment. Recently, water stable zirconium based metal-organic frameworks (Zr-...
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Water pollution caused by CrO(4)(2-)has become a global concern due to its high aqueous solubility and good mobility in the underground environment. Recently, water stable zirconium based metal-organic frameworks (Zr-MOFs) have been tested as adsorbents to remove pollutants from contaminated water. However, the low adsorption capacity of Zr-MOFs towards ionic pollutants is unsatisfactory due to their neutral nature. Herein, a cationic Zr-MOF (Zr-C-MOF) was obtained by directly introducing a pyridinium salt as a ligand with an impressive ion exchange capability. Zr-C-MOF demonstrated enhanced acidic resistance and selectively high adsorption of CrO42-. The characteristics of the obtained Zr-C-MOF were confirmedviavarious techniques including PXRD, FT-IR spectroscopy,H-1-NMR spectroscopy, TGA, SEM, EDX and XPS. Batch adsorption studies have been conducted to gain a deep understanding of the kinetics mechanism, pH effects, adsorption isotherm and the effects of other competing ions. The kinetics and adsorption isotherm of CrO(4)(2-)adsorption onto Zr-C-MOF were found to well fit the pseudo-second-order rate equation and the Langmuir model, respectively. The comparison of FT-IR, PXRD, SEM, EDX and XPS results of the samples before and after CrO(4)(2-)adsorption revealed the adsorption mechanism of the anion exchange process.
A metal-organic framework, UiO-66-NH2, was designed, synthesized and characterized in this study. By conducting solvothermal method, Salicylaldehyde (Sal) and 2,4-dihydroxybenzaldehyde (MHBA) were grafted onto UiO-66-...
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A metal-organic framework, UiO-66-NH2, was designed, synthesized and characterized in this study. By conducting solvothermal method, Salicylaldehyde (Sal) and 2,4-dihydroxybenzaldehyde (MHBA) were grafted onto UiO-66-NH2 via post-treatment to obtain the functionalized material UiO-66-Sal and UiO-66-MHBA. The three materials above were characterized, and the effects of solid-liquid ratio, pH, ionic strength, and oscillation time on U(VI) adsorption were studied. The relevant experimental results fitted well with pseudo-second-order kinetic equation and thermodynamic adsorption model.
作者:
du, ShengWu, ZhengxingWang, JianQi, suwenYu, JunzhiChinese Acad Sci
Inst Automat State Key Lab Management & Control Complex Syst Beijing 100190 Peoples R China Univ Chinese Acad Sci
Sch Artificial Intelligence Beijing 100049 Peoples R China Shenzhen Univ
Sch Med Dept Biomed Engn Shenzhen 518060 Peoples R China Chinese Acad Sci
Inst Automat State Key Lab Management & Control Complex Syst Beijing 100190 Peoples R China Peking Univ
Coll Engn State Key Lab Turbulence & Complex Syst Dept Mech & Engn SciBIC ESAT Beijing 100871 Peoples R China
This article presents the mechanical design and locomotion control of a novel tuna-inspired robot system for both fast swimming and high maneuverability. Mechanically, the developed robotic fish named CasiTuna compris...
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This article presents the mechanical design and locomotion control of a novel tuna-inspired robot system for both fast swimming and high maneuverability. Mechanically, the developed robotic fish named CasiTuna comprises three important parts, i.e., an innovative two-motor-actuated propulsive mechanism, a buoyancy adjustment structure, and a pair of pectoral fins. Unlike most robotic fishes' multiple concatenated links-based propulsive mechanism, CasiTuna's two-motor-actuated one places both motors in the anterior body and utilizes a transmission system to achieve tuna-like lateral undulations. Meanwhile, the buoyancy adjustment mechanism in conjunction with pectoral fins endows the robot with the capability of three-dimensional maneuverability. Kinematic and dynamic analyses are further conducted to reveal the interactive hydrodynamic forces. Regarding the locomotion control method, a bio-inspired central pattern generator-based controller is adopted to achieve multimodal swimming. In particular, two kinds of turning maneuvers are implemented and discussed. Aquatic experiments, including straight swimming, circular turning, and nearly static pitching validate the effectiveness of proposed mechatronic design and locomotion control methods. Remarkably, CasiTuna achieved a peak forward speed of 0.8 m/s (corresponding to 1.52 body lengths per second) and a minimum turning radius of less than 0.3 body lengths.
UHV transformer is an important device in power system. Transformer explosions happen frequently, and most of them will cause fire, which will cause serious economic loss and casualty risk. There is no relative author...
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ISBN:
(纸本)9780738146331
UHV transformer is an important device in power system. Transformer explosions happen frequently, and most of them will cause fire, which will cause serious economic loss and casualty risk. There is no relative authoritative engineering solution to transformer explosion accident. Aiming at this problem, this paper puts forward the idea of anti-explosion and pressure relief balanced design of UHV transformer, and gives the design scheme of pressure relief device which supports the balanced design. In the numerical simulation, the common explosion condition is considered and the structural responses of transformer box is obtained. According to the responses, the layout suggestion of the pressure relief device is given, and the design scheme of the device is improved.
Based on boron-dipyrromethene (BODIPY), taking 2-hydroxy-N-(2-hydroxyphenyl)benzamide as recognition site, a new fluorescent probe HHPBA-BODIPY aimed at sensitively detecting Cu ions was designed, synthesized and *** ...
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Based on boron-dipyrromethene (BODIPY), taking 2-hydroxy-N-(2-hydroxyphenyl)benzamide as recognition site, a new fluorescent probe HHPBA-BODIPY aimed at sensitively detecting Cu ions was designed, synthesized and *** emission spectra of HHPBA-BODIPY exhibited an intensive green fluorescence around 510 nm, with a maximum absorption near 500 nm. When Cu2+ ions are present, the fluorescence at 510 nm can be quenched with a good linearity between the copper ion concentrationand the fluorescence intensity and the detection limit is 0.35 mu M. HHPBA-BODIPY is also selective toward Cu2+, while other metal ions show no interfere except Fe3+ and Cr3+ ions. In addition, HHPBA-BODIPY also proved efficient to detect Cu2+ in water samples which offers the possibility to detect trace amount of Cu2+ for environmental monitoring. Copper ions;BODIPY;fluorescent probe.
To avoid the interference of biofouling on the adsorbents towards uranium extraction from seawater, a silver-incorporated antibacterial amidoximated nanofiber adsorbent (PAO@AgNP) was designed and prepared via electro...
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To avoid the interference of biofouling on the adsorbents towards uranium extraction from seawater, a silver-incorporated antibacterial amidoximated nanofiber adsorbent (PAO@AgNP) was designed and prepared via electrospinning in this study. The uranium adsorption experiments conducted in uranium-spiked seawater showed the material possessed good uranium adsorption capacity (11.89 mg/g), and the antibacterial experiments demonstrated that PAO@AgNP could effectively remove Escherichia coli and Staphylococcus aureus, the released silver could interrupt cellular respiration, lead to lipid peroxidation and eventually apoptosis.
Terrestrial Trunked Radio (TETRA) based communication system can provide command dispatching, data transmission and telephone services on one platform. In Rail transit network, communication and short data transmissio...
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Power transformer is the key equipment in the power system. In recent years, transformer explosion occurred frequently, most of which caused fire and resulted in heavy losses. Research in this field is still in the in...
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Activating the oxygen anionic redox presents a promising avenue for developing highly active oxygen evolution reaction (OER) electrocatalysts for proton-exchange membrane water electrolyzers (PEMWE). Here, we engineer...
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