Research about DNA composition has been concentrated on DNA damage in the past few decades. However, it still remains a great challenge to construct a rapid, facile, and accurate approach for simultaneously monitoring...
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Research about DNA composition has been concentrated on DNA damage in the past few decades. However, it still remains a great challenge to construct a rapid, facile, and accurate approach for simultaneously monitoring four DNA bases, guanine (G), adenine (A), thymine (T), and cytosine (C). herein, a novel electrochemical sensor based on phenanthroimidazole derivative, 2-(4-bromophenyl)-1-phenyl-1H-phenanthro[9,10-d]-imidazole (PPI), is successfully fabricated by a simple electrochemical method. The bromophenyl group in PI could expand their aromatic plane, induce the pi-conjugated extension, and enhance the charge transfer and pi-pi interaction. The phenyl group at N1 position could regulate the intermolecular interaction, which could promote the possibility of intermolecular connection. The PPI polymer (poly(PPI)) with pi-electron enriched conjugation architecture has been applied in simultaneous determination of G, A, T, and C in neutral solution by square wave voltammetry (SWV) method with well-separated peak potentials at 0.714, 1.004, 1.177, and 1.353 V, respectively. The sensor functionalized with poly(PPI) exhibits wide linear response for G, A, T, and C in the concentration ranges of 3-300, 1-300, 30-800, and 20-750 mu M, respectively. With favorable selectivity, stability, and reproducibility, the sensor is successfully utilized to monitor four DNA bases in real samples, displaying a promising prospect for electrochemical sensing devices.
Sewage sludge is the promising raw material for biosorbent preparation. In this work, we evaluated theheavy metals adsorption characteristics of alkali treated sewage sludge (ATSS) by equilibrium studies. The adsorpt...
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Sewage sludge is the promising raw material for biosorbent preparation. In this work, we evaluated theheavy metals adsorption characteristics of alkali treated sewage sludge (ATSS) by equilibrium studies. The adsorption isotherms were fitted with Langmuir and Freundlich models. Comparing with untreated sewage sludge, the total adsorption capacity (qm) of ATSS (prepared with 0.125 mol/L NaOH) for Cd, Pb, Ni, increased by 0.51, 0.70 and 0.32 mmol/g, respectively. When the NaOH concentration for ATSS preparation increased from 0.125 mol/L to 0.25 mol/L, the qm of ATSS for Pb decreased from 1.05 mmol/g to 0.84 mmol/g. However, when the NaOH concentration increased from 0.25 mol/L to 7.5 mol/L, it showed increasing trend. According to the IR spectra data, the adsorption effect of biosorbent for heavy metals was mainly due to the complexation of-N-H groups and-COOH groups.
A double-turn coil omnidirectional shear-horizontal wave magnetostrictive patch transducer (DC-OSH-MPT) array for imaging detection in composite plates is presented. DC-OSH-MPT parameters are optimized in order to mak...
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A double-turn coil omnidirectional shear-horizontal wave magnetostrictive patch transducer (DC-OSH-MPT) array for imaging detection in composite plates is presented. DC-OSH-MPT parameters are optimized in order to make the transducer more suitable for imaging detection. Besides, the characteristic of the lowest shear-horizontal mode (SH0), which can be generated and received in all directions by DC-OSH-MPT bonded on composite plate, is beneficial for imaging. Due to anisotropic property of composite plates, the group velocity of SH0 mode in different azimuthal directions was experimentally measured in damage imaging. The location of simulated damage, which was a bonded circular cylinder, was estimated by DC-OSH-MPT array and ellipse imaging algorithm. The imaging results have demonstrated that DC-OSH-MPT can be considered as a spatially distributed array suitable for imaging detection in composite plates.
Recently, heat treatment between 250 °C and 500 °C has been attempted to improve quality factor (Q) of superconducting radio-frequency cavities at FNAL and KEK. Experiments of such medium temperature (mid-T)...
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Sewage sludge is the promising raw material for biosorbent preparation. In this work, we evaluated theheavy metals adsorption characteristics of alkali treated sewage sludge (ATSS) by equilibrium studies. The adsorpt...
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Sewage sludge is the promising raw material for biosorbent preparation. In this work, we evaluated theheavy metals adsorption characteristics of alkali treated sewage sludge (ATSS) by equilibrium studies. The adsorption isotherms were fitted with Langmuir and Freundlich models. Comparing with untreated sewage sludge, the total adsorption capacity (qm) of ATSS (prepared with 0.125 mol/L NaOH) for Cd, Pb, Ni, increased by 0.51, 0.70 and 0.32 mmol/g, respectively. When the NaOH concentration for ATSS preparation increased from 0.125 mol/L to 0.25 mol/L, the qm of ATSS for Pb decreased from 1.05 mmol/g to 0.84 mmol/g. However, when the NaOH concentration increased from 0.25 mol/L to 7.5 mol/L, it showed increasing trend. According to the IR spectra data, the adsorption effect of biosorbent for heavy metals was mainly due to the complexation of -N-H groups and -COOH groups.
Coal gangue, sandy soil and clay (mass ratio 45: 4: 1) as goaf filling materials acquired from coal mining processes were applied to remove Fe and Mn effectively from mining drainage. The results of an adsorption kine...
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Coal gangue, sandy soil and clay (mass ratio 45: 4: 1) as goaf filling materials acquired from coal mining processes were applied to remove Fe and Mn effectively from mining drainage. The results of an adsorption kinetic study showed that the Fe adsorption equation was y = 21.454y + 8.4712, R-2 = 0.9924 and the Mn adsorption equation was y = 7.5409x + 0.905, R-2 = 0.9957. Meanwhile, the goaf filling materials had low desorption capacity (Fe 6.765 mu g/g, Mn 1.52 mu g/g) and desorption ratio (Fe 8.98%, Mn 11.04%). Experiments demonstrated that Fe and Mn from mining drainage could be removed stably at a flow rate of 1.2 L/min, Fe inlet concentration of less than 40 mg/L, Mn inlet concentration of less than 2 mg/L and neutral or alkaline conditions. During a procedure of continuous experiments, the effluent quality could meet the requirement of the 'Code for Engineering Design of Sewage Regeneration-GB503352-2002'. A real-application project using goaf filling materials to treat mining drainage in Shendong coal mine showed that the average cost per ton of mining drainage was about 0.55 RMB, which could bring about considerable economic benefit for coal mining enterprises.
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