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Adsorption of Orange G on Activated Porous Carbon Derived from Coal Tar Pitch: Experimental and DFT Study

LANGMUIR 2024年第48期40卷 25471-25482页

作者： Huang, linlin Zhang, xuwen liu, Tingting Wang, lin li, lixin li, Da Sheng, Tao Dong, Zilong Zhao, Xinyue Heilongjiang Univ Sci & Technol Coll Environm & Chem Engn Harbin 150022 Peoples R China Harbin Inst Technol State Key Lab Urban Water Resource & Environm Harbin 150000 Peoples R China Northeast Agr Univ Sch Resources & Environm Harbin 150030 Peoples R China

A coal tar pitch-based porous carbon adsorbent (CPA) was synthesized through a straightforward method involving the heating of a mixture of KOH and coal tar pitch (CTP). This CPA exhibited a high surface area of 1811.2 m2 g-1 and a large pore volume of 0.94 cm3 g-1 when prepared with a CTP to KOH mass ratio of 1:4 at 800 degrees C. Parameters such as the heating temperature and activator dose were optimized to enhance the adsorption efficiency. The prepared CPA was extensively characterized by SEM, XRD, FTIR, and BET measurements. Notably, CPA presented a distinct adsorption performance for Orange G (OG), achieving a maximum adsorption capability of 449.7 mg g-1. Kinetic studies indicated that the adsorption process followed the pseudo-second-order model, while the adsorption isotherm data demonstrated that both chemical and physical interactions favored OG adsorption. Thermodynamic analysis revealed that the adsorption of OG on CPA was spontaneous and exothermic and increased the entropy. Density functional theory (DFT) calculations provided insights into the adsorption mechanism, highlighting electrostatic interactions, hydrogen bonds, and pi-pi interactions as the dominant processes governing OG adsorption onto the adsorbent.

关键词： Potassium hydroxide

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Stratum Corneum-Inspired Zwitterionic Hydrogels with Intrinsic Water Retention and Anti-Freezing Properties for Intelligent Flexible Sensors

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ADVANCED FUNCTIONAL MATERIALS 2025年第0期

作者： Wu, Meng Qiao, Chenyu Sui, Peng-Fei Luo, Jing-li li, Zuoli Cao, Yi Pei, Renjun Peng, xuwen Zeng, Hongbo Chinese Acad Sci Suzhou Inst Nanotech & Nanobion CAS Key Lab Nanobio Interface Suzhou 215123 Peoples R China Univ Alberta Dept Chem & Mat Engn Edmonton AB T6G 1H9 Canada Tsinghua Univ Dept Chem Engn Beijing 10084 Peoples R China

Hydrogels, which mimic the properties of natural tissues, are essential for flexible electronics in human-machine interfaces (HMIs). However, traditional hydrogels suffer from dehydration, compromising stability and functionality. To address this issue, a stratum corneum-inspired, water-retaining hydrogel is developed using hygroscopic polymers and bound water. Three types of hydrophilic monomers (non-ionic, mono-ionic, and zwitterionic) are explored, with polyzwitterions, particularly N,N-dimethyl (acrylamidopropyl) ammonium propane sulfonate (DMAAPS), forming a quasi-hydrogel that retains the softness and flexibility of conventional hydrogels. Water acts as a plasticizer, enhancing polymer chain mobility and reducing stiffness. The DMAAPS hydrogel maintains 100% weight retention under specific humidity conditions and shows skin-like softness across a wide humidity range. The Young's modulus increases from 54 to 118 kPa as relative humidity decreases from 80% to 40%. The absence of free water confers intrinsic anti-freezing properties. A triple crosslinking mechanism and conductive polymers endow the hydrogel with stretchability (> 2000%), toughness, elasticity, self-healing, and stable sensing capabilities. The hydrogel functions as an excellent flexible sensor for real-time, sensitive detection of human motion and physiological signals. An intelligent handwriting recognition platform with high accuracy is also established using double-channel signal collection and machine learning algorithms, offering insights for next-generation durable, biomimetic, and smart HMIs.

关键词： anti-freezing flexible sensors self-healing stratum corneum-inspired materials water retention wearable electronics Zwitterionic hydrogels

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Combined Separated Oscillatory Fields Technique 37

Combined Separated Oscillatory Fields Technique

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37th European Frequency and Time Forum, EFTF 2024

作者： Sun, Fuyu li, Chao Hu, xuwen Zhang, Shougang National Time Service Center Chinese Academy of Sciences Xi'an China Chinese Academy of Sciences Key Laboratory of Time Reference and Applications Xi'an China

ISBN: (纸本)9798350354270

Ramsey's method of separated oscillatory fields (SOFs) has been originally used in beam magnetic resonance apparatuses, which leads to the establishment of atomic definition of time interval and frequency. Since then, various versions of the SOFs technique have been widely used for precise measurement of different physical quantities. Here, we present an alternative method to generate atomic beam magnetic resonance signals by combining two Ramsey cavities with phase differences of 0 and 1t. It is found that the strength of the resonance signals generated using this combined SOFs technique is approximately twice that of the resonance signals produced by the conventional SOFs techniques. In addition to generating stronger resonance, the combined Ramsey method eliminates the Rabi background superimposed on the Ramsey interference pattern without increasing the Ramsey signal linewidth. Thus, this technique serves a promising tool for high-precision measurements. © 2024 IEEE.

关键词： Velocity measurement

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Anti-allergic Effects of Ginsenosides Extracted by High Temperature and High Pressure Method

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Chemical Research in Chinese Universities 2018年第3期34卷 382-388页

作者： liU Ying li xuwen ZHANG Hanqi WU Qian SHI Xiaolei JIN Yongri College of Chemistry Jilin University Changchun 130021 P. R. China College of Food Science and Engineering Jilin University Changchun 130062 P. R. China

Ginseng（Panax ginseng C. A. Mey.） is a traditional medicinal herb in Asia. Studies have shown that ginsenosides significantly affect immnnoregulation and rare ginsenosides have anti-allergic effects. In this research, a high temperature and high pressure method was utilized to increase the contents of rare ginsenosides in the ginseng extract（GE）. The anti-allergic effects of this extract were investigated in vivo. Water was used as the extraction solvent in extracting the rare ginsenosides via the high temperature and high pressure method. Extraction time and temperature were investigated in order to increase the contents of rare ginsenosides. Rare ginsenosides were qualitatively analyzed by HPLC-ESI-MS and quantitatively analyzed by HPLC-UV. Anti-allergic effects of the extracts were assessed using the ovalbumin（OVA）-induced allergic asthma model in vivo. An extraction temperature of 145 ℃ and extraction time of 2.0 h were chosen as the optimal conditions. Compared with traditional method, the contents of total rare ginsenosides extracted were considerably higher using the new method, that is, 14.74 times that extracted by the traditional method. In our in vivo experiments, treatment with high concentration GE may have anti-allergic erects in decreasing the total amount of IgE in serum and IL-4 in bronchoalveolar lavage fluid（BALF）, aud in improving the ratio of CD4^＋ to CD8^＋ T cells. The high temperature and high pressure method was an effective method to obtain GE containing more rare ginsenosides, which maybe become anti-allergic agents.

关键词： Food allergy High temperature and high pressure method Ovalbumin Rare ginsenoside

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Optimising maize threshing by integrating DEM simulation and interpretive enhanced predictive modelling

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BIOSYSTEMS ENGINEERING 2024年 244卷 93-106页

作者： Fang, xuwen Zhang, Jinsong Zhao, Xuelin Zhang, li Zhou, Deyi Yu, Chunsheng Hu, Wei Zhang, Qiang Jilin Univ Coll Biol & Agr Engn Changchun 130022 Peoples R China

Maize threshing is a complex and dynamic process, and optimisation of operating parameters is essential to improve threshing quality and efficiency. In this study, machine learning was combined with interpretability analysis to investigate the dynamic effects of operating parameters on maize threshing quality and to optimise the threshing process. The maize cob model used to simulate threshing was validated by stacking angle and tensile test. Real-time drum operating parameters and threshing quality data obtained through Discrete Element Method (DEM) threshing simulation were used to train a threshing quality prediction network. The prediction accuracy was improved by incorporating an attention mechanism into the Long Short-Term Memory (LSTM) model with an optimised Root Mean Square Error (RMSE) of 0.0041. The global feature importance and dynamic Shapley Additive Explanations (SHAP) value analyses demonstrated that rotational speed is a key determinant of unthreshed and damaged rates and that its effect varies significantly at different stages of the threshing process. Guided by these analyses, a staged speed adjustment experiment was conducted. Specifically, an increase in rotational speed during the initial threshing phase markedly lowered the initial unthreshed rate for medium and high-speed groups to 6.63% and 2.73%, respectively, a significant improvement over the 67.70% observed in the low-speed group. The final damage rate in the high-speed group decreased by 9.79% relative to the low-speed group. This dynamic analysis approach provides a novel paradigm for optimising complex agricultural processes under varying conditions, offering interpretable insights for precise process control and improvement.

关键词： Simulation Neural network forecast Game theory Agricultural optimisation Interpretable models Data-driven agriculture

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Corrosion behavior of Cu-40Zn alloy in a periodic service between simulating atmospheric and deep sea environment

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CORROSION REVIEWS 2025年第1期43卷 127-141页

作者： Hu, Shengbo liu, Zhong Yuan, xuwen Meng, Fandi liao, Luhai Guo, Rui Yang, Wei li, Fengguang Hubei Univ Automot Technol Sch Mat Sci & Engn Shiyan 442002 Peoples R China Hubei Key Lab Energy Storage & Power Battery Shiyan 442002 Peoples R China Northeastern Univ Shenyang Natl Lab Mat Sci 3-11 Wenhua Rd Shenyang 110819 Peoples R China

The corrosion behavior of Cu-40Zn alloy in a periodic service between simulating atmospheric and deep sea environment has been systematically studied. Results showed that a layer of protective corrosion products can be formed quickly and become defective over time. During the periodic service, the HP (high hydrostatic pressure) promotes the anodic dissolution of the base and the generation of (Cu, Zn)2(OH)3Cl, which causes expansion of the corrosion products;the AP (alternating pressure) facilitates the wetting process during dry to wet stage, and the alternating force caused by AP leads to the cracks, peeling off of the corrosion products. Severe intergranular corrosion takes place, which initiates at the beta phase and is accelerated by the combination of defective corrosion products and the drying stage.

关键词： Cu-Zn alloy periodic service hydrostatic pressure EIS

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A Novel Flavone from the Leaves of Murraya paniculata

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CHEMISTRY OF NATURAL COMPOUNDS 2018年第6期54卷 1061-1063页

作者： li, Peng Zhang, Yue Wang, Ziqi Chen, Honghui li, xuwen Jin, Yongri Jilin Univ Coll Chem Changchun 130012 Jilin Peoples R China

A phytochemical investigation of the leaves of Murraya paniculata (L.) Jack resulted in a novel compound, 3,5-dihydroxy-5,7,4-trimethoxyflavone, together with 13 known compounds. The structure of the novel compound wa... 详细信息

关键词： Murraya paniculata (L.) Jack leaves flavonoids

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Cocrystals of axially N-embedded quasi-carbon nanohoops via modulating the electron affinity of guest acceptors

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SCIENCE CHINA-CHEMISTRY 2025年 1-8页

作者： Zhang, li Qiu, Shuhai Hu, Shunlong Xu, Hanren Sun, xuwen Jiang, Wei Qu, Da-Hui Wang, Zhaohui East China Univ Sci & Technol Feringa Nobel Prize Scientist Joint Res Ctr Key Lab Adv Mat & Joint Int Res Lab Precis Chem & Sch Chem & Mol EngnInst Fine ChemFrontiers Sci C Shanghai 200237 Peoples R China Tsinghua Univ Dept Chem Key Lab Organ Optoelect & Mol Engn Beijing 100084 Peoples R China

Organic donor-acceptor cocrystals of pi-conjugated molecues have shown diverse applications in materials science. However, most cocrystals exist in neutral forms dominated by pi-pi interactions, while the ionic congeners and corresponding properties are rarely studied due to difficulties in harnessing the degree of charge transfer. Herein, we report cocrystals of axially N-embedded quasi-carbon nanohoops (DPP-D and DPP-T) with electron deficient guests. By modulating the electron affinity of the acceptor guests, the electronic structures of the complexes can be tuned from neutral to ionic states. Specifically, DPP-D interacts with TCNB molecules to form neutral superstructures via intermolecular pi-pi interactions, giving rise to a deep-red emission in the solid state. In contrast, an ionic complex showing near-infrared region absorptions and paramagnetic character on account of strong charge-transfer interactions is generated when DDQ molecules are involved. Their unique properties can be explained by different degrees of charge transfer and assembly modes, which have clearly been manifested by crystal structures and theoretical calculations. Our studies provide rare examples of pi-conjugated macrocycle-based donor-acceptor cocrystals in both neutral and ionic forms, and give insight to the design of multicomponent carbon nanomaterials.

关键词： n-doped carbon nanohoop donor-acceptor cocrystal charge transfer interaction ionic state

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Varicella vaccine effectiveness evaluation in Wuxi, China: A retrospective cohort study

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EPIDEMIOLOGY & INFECTION 2024年 152卷 e105-e105页

作者： Xiu, Shixin Xu, Zhuping Wang, xuwen Zhang, li Wang, Qiang Yang, Min Shen, Yuan Nanjing Med Univ Affiliated Wuxi Ctr Dis Control & Prevent Wuxi Ctr Dis Control & Prevent Dept Immunizat Wuxi Peoples R China Nanjing Med Univ Affiliated Wuxi Ctr Dis Control & Prevent Wuxi Ctr Dis Control & Prevent Dept Chron Communicable Dis Wuxi Peoples R China Jiangyin Cty Ctr Dis Control & Prevent Publ Hlth Dept Wuxi Peoples R China Fudan Univ Sch Publ Hlth Dept Epidemiol Shanghai Peoples R China Nanjing Med Univ Affiliated Wuxi Ctr Dis Control & Prevent Wuxi Ctr Dis Control & Prevent Wuxi Peoples R China

Varicella is a vaccine-preventable infectious disease. Since 1 December 2018, the varicella vaccine has been included in the local Expanded Programme on Immunization (EPI) in Wuxi, China, and children born after 1 December 2014 are eligible for free vaccination. To evaluate the effect of varicella vaccination in Wuxi city, we selected 382 397 children born from 2012 to 2016 as subjects. Their disease data were obtained from the Chinese Disease Prevention and Control Information System, and their vaccination data were obtained from the Jiangsu Province Vaccination Integrated Service Management Information System. The incidence of breakthrough varicella cases increased in the first 4 years and reached the peak in the fifth year. With the increase of vaccination rate, the incidence of varicella decreased significantly. The vaccine effectiveness (VE) was found to be 88.17%-95.78% for one dose and 98.65%-99.93% for two doses. Although the VE per dose decreased from 99.57% in the first year to 93.04% in the eighth year, it remained high. These findings confirmed the effectiveness of varicella vaccination in children, supported the use of a two-dose varicella vaccination strategy to achieve better protection, and provided important insights into the optimal vaccination strategy for varicella prevention in children.

关键词： screening method vaccine effectiveness varicella vaccine number of varicella cases vaccination rates

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Parameters Optimization Method for ADRC of Permanent Magnet Synchronous Motor Based on CMA-ES 43

Parameters Optimization Method for ADRC of Permanent Magnet ...

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43rd Chinese Control Conference (CCC)

作者： Jiang, Tianjian Yang, Yang li, Zhiyuan Yang, Tianqi Chen, xuwen Nanjing Univ Posts & Telecommun Coll Automat Nanjing 210023 Peoples R China Nanjing Univ Posts & Telecommun Coll Aritif Intelligence Nanjing 210023 Peoples R China Nanjing Univ Posts & Telecommun Coll Internet Things Nanjing 210023 Peoples R China

ISBN: (纸本)9798350366907;9789887581581

Active disturbance rejection control (ADRC) is widely used to control permanent magnet synchronous motors (PMSM). However, the settings of gain parameters in ADRC is often dependent on engineers' experience. Also, it is difficult to design the parameters accurately by hand to achieve satisfactory results. A method based on evolution strategy with covariance matrix adaptation (CMA-ES) for optimizing the gain parameters of ADRC is proposed. By setting up some optimization tasks and using the CMA-ES algorithm, reinforcement learning is performed on the parameters of ADRC. In view of the high population size and complexity of CMA-ES, we adopt a parallel computation method to speed up the optimization process. The method can effectively optimize the ADRC gain parameters to adapt to the specified application environment, and at the same time reduce the dependence of setting ADRC parameters on human experience as well as time consumption. Finally, we verify that this CMA-ES-based parameter optimization method can effectively improve the control performance of the motor by running simulations and comparing the motor speed changes before and after optimization.

关键词： Permanent-magnet Synchronous Motor Active Disturbance Rejection Control Field-oriented Control Swarm Optimization High Throughput Computing Modern Control

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