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Solid electrochemiluminescence sensor by immobilization luminol in Zn-Co-ZIF CNFs for sensitive detection of procymidone in vegetables

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MICROCHIMICA ACTA 2024年第9期191卷 508-508页

作者： Lu, Juan Guo, Yanjia Shan, Xiangyu Song, Yujia li, Ruidan Tian, li li, xuwen Changchun Normal Univ Coll Chem Changchun 130032 Peoples R China Jilin Univ Coll Chem Changchun 130022 Peoples R China Technol Innovat Lab Res & Dev Econ Plants & Edible Changchun 130032 Jilin Peoples R China

A solid-state electrochemiluminescence (ECL) sensor was fabricated by immobilizing luminol, a classical luminescent reagent, on a Zn-Co-ZIF carbon fiber-modified electrode for the rapid and sensitive detection of procymidone (PCM) in vegetable samples. The sensor was created by sequentially modifying the glassy carbon electrode with Zn-Co-ZIF carbon fiber (Zn-Co-ZIF CNFs), Pt@Au NPs, and luminol. Zn-Co-ZIF CNFs, prepared through electrospinning and high-temperature pyrolysis, possessed a large specific surface area and porosity, making it suitable as carrier and electron transfer accelerator in the system. Pt@Au NPs demonstrated excellent catalytic activity, effectively enhancing the generation of active substances. The ECL signal was significantly amplified by the combination of Zn-Co-ZIF CNFs and Pt@Au NPs, which can subsequently be diminished by procymidone. The ECL intensity decreased proportionally with the addition of procymidone, displaying a linear relationship within the concentration range 1.0 x 10-13 to 1.0 x 10-6 mol L-1 (R2 = 0.993). The sensor exhibited a detection limit of 3.3 x 10-14 mol L-1 (S/N = 3) and demonstrated outstanding reproducibility and stability, making it well-suited for the detection of procymidone in vegetable samples.

关键词： Electrochemiluminescence Carbon nanofibers Modified glassy carbon electrode Procymidone Luminol

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Corrosion behavior of Cu-40Zn alloy in a periodic service between simulating atmospheric and deep sea environment

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CORROSION REVIEWS 2025年第1期43卷 127-141页

作者： Hu, Shengbo liu, Zhong Yuan, xuwen Meng, Fandi liao, Luhai Guo, Rui Yang, Wei li, Fengguang Hubei Univ Automot Technol Sch Mat Sci & Engn Shiyan 442002 Peoples R China Hubei Key Lab Energy Storage & Power Battery Shiyan 442002 Peoples R China Northeastern Univ Shenyang Natl Lab Mat Sci 3-11 Wenhua Rd Shenyang 110819 Peoples R China

The corrosion behavior of Cu-40Zn alloy in a periodic service between simulating atmospheric and deep sea environment has been systematically studied. Results showed that a layer of protective corrosion products can be formed quickly and become defective over time. During the periodic service, the HP (high hydrostatic pressure) promotes the anodic dissolution of the base and the generation of (Cu, Zn)2(OH)3Cl, which causes expansion of the corrosion products;the AP (alternating pressure) facilitates the wetting process during dry to wet stage, and the alternating force caused by AP leads to the cracks, peeling off of the corrosion products. Severe intergranular corrosion takes place, which initiates at the beta phase and is accelerated by the combination of defective corrosion products and the drying stage.

关键词： Cu-Zn alloy periodic service hydrostatic pressure EIS

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Cocrystals of axially N-embedded quasi-carbon nanohoops via modulating the electron affinity of guest acceptors

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SCIENCE CHINA-CHEMISTRY 2025年 1-8页

作者： Zhang, li Qiu, Shuhai Hu, Shunlong Xu, Hanren Sun, xuwen Jiang, Wei Qu, Da-Hui Wang, Zhaohui East China Univ Sci & Technol Feringa Nobel Prize Scientist Joint Res Ctr Key Lab Adv Mat & Joint Int Res Lab Precis Chem & Sch Chem & Mol EngnInst Fine ChemFrontiers Sci C Shanghai 200237 Peoples R China Tsinghua Univ Dept Chem Key Lab Organ Optoelect & Mol Engn Beijing 100084 Peoples R China

Organic donor-acceptor cocrystals of pi-conjugated molecues have shown diverse applications in materials science. However, most cocrystals exist in neutral forms dominated by pi-pi interactions, while the ionic congeners and corresponding properties are rarely studied due to difficulties in harnessing the degree of charge transfer. Herein, we report cocrystals of axially N-embedded quasi-carbon nanohoops (DPP-D and DPP-T) with electron deficient guests. By modulating the electron affinity of the acceptor guests, the electronic structures of the complexes can be tuned from neutral to ionic states. Specifically, DPP-D interacts with TCNB molecules to form neutral superstructures via intermolecular pi-pi interactions, giving rise to a deep-red emission in the solid state. In contrast, an ionic complex showing near-infrared region absorptions and paramagnetic character on account of strong charge-transfer interactions is generated when DDQ molecules are involved. Their unique properties can be explained by different degrees of charge transfer and assembly modes, which have clearly been manifested by crystal structures and theoretical calculations. Our studies provide rare examples of pi-conjugated macrocycle-based donor-acceptor cocrystals in both neutral and ionic forms, and give insight to the design of multicomponent carbon nanomaterials.

关键词： n-doped carbon nanohoop donor-acceptor cocrystal charge transfer interaction ionic state

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Gestational diabetes mellitus prediction model: A risk factors analysis of pregnant women with gestational diabetes mellitus but have normal oral glucose tolerance test results in the second trimester of pregnancy

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TECHNOLOGY AND HEALTH CARE 2021年第1_suppl期29卷 S57-S63页

作者： Lu, Jiayu Zhang, Song Jiang, Hongqing Yang, lin Hao, Dongmei Yang, Yimin li, xuwen Chen, Aiqing Shao, Jing liu, Xiaohong Beijing Univ Technol Fac Environm & Life Sci Beijing Int Base Sci & Technol Cooperat Intelligent Physiol Measurement & Clin Translat Beijing 100124 Peoples R China Haidian Maternal & Children Hlth Hosp Beijing 100080 Peoples R China Beijing Yes Med Devices Co Ltd Beijing 100152 Peoples R China

BACKGROUND: Oral glucose tolerance test (OGTT) is a standard for the diagnosis of gestational diabetes mellitus (GDM). However, clinically, some cases with normal results were diagnosed as GDM in the third trimester. OBJECTIVE: To establish a risk model based on energy metabolism, epidemiology, and biochemistry that could predict the GDM pregnant women with normal OGTT results in the second trimester. METHODS: Qualitative and quantitative data were analyzed to find out the risk factors, and the binary logistic backward LR regression was used to establish the prediction model of each factor and comprehensive factor, respectively. RESULTS: The risk factors including the rest energy expenditure per kilogram of body weight, oxygen consumption per kilogram of body weight, if more than the weight gain criteria of the Institute of Medicine, the increase of body mass index between the second trimester and pre-pregnancy, and fasting blood glucose. By comparison, the comprehensive model had the best prediction performance, indicating that 85% of high-risk individuals were correctly classified. CONCLUSION: Energy metabolism, epidemiology, and biochemistry had better recognition ability for the GDM pregnant women with normal OGTT results in the second trimester. The addition of metabolic factors in the second trimester also improved the overall prediction performance.

关键词： Prediction model gestational diabetes mellitus rest energy metabolism

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Enhancing CO2 hydrate sequestration through underlying methane hydrate production: A novel strategy for carbon storage

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ENERGY 2025年 326卷

作者： li, Yuxuan Zhang, Zhaobin Zhang, Bo Chalaturnyk, Rick li, Shouding He, Jianming Xie, Zhuoran Bian, Hang li, Xiao Lu, Cheng Qin, xuwen Chinese Acad Sci Inst Geol & Geophys Key Lab Deep Petr Intelligent Explorat & Dev Beijing 100029 Peoples R China Univ Chinese Acad Sci Coll Earth & Planetary Sci Beijing 100049 Peoples R China Univ Alberta Donadeo Innovat Ctr Engn Dept Civil & Environm Engn Edmonton AB T6G 1H9 Canada China Geol Survey Minist Nat Resources Beijing 100037 Peoples R China

Seafloor CO2 sequestration in the form of gas hydrates offers expansive geological opportunities for carbon neutrality strategies. Guided by phase equilibrium conditions, this study employs a self-developed multi-physical simulator to investigate how methane hydrate production beneath a CO2 sequestration zone can facilitate carbon storage. A dual-horizontal-well model is constructed and validated based on field measurements. Through numerical simulations, the effects of methane hydrate production timing, CO2 injection rate, and injection depth on carbon sequestration over a 100,000-year timescale are examined. Two novel metrics-sequestration efficiency and safe distance-are introduced. Results indicate that extracting methane hydrates in the later stages of CO2 injection is optimal. Furthermore, an efficient sequestration window exists for both injection rate and depth. By exploring the relationship between sequestration efficiency and storage safety, this study provides a new perspective for implementing CO2 sequestration pathways.

关键词： CO 2 sequestration Methane hydrate production Multi-physical Sequestration efficiency Storage safety

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Pioneering Insights into the Reaction Kinetics of Metastable Intermolecular Composites Based on Metal Fluorides: Virtually non-existent condensed Phase Combustion Products and Ultra-Efficient Reactivity

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ADVANCED SCIENCE 2025年第14期12卷 e2415073页

作者： liu, xuwen li, Jingwei Feng, Shenghua Jia, Yongsheng Hu, Maocong Yao, Yingkang Sun, Jinshan Xie, Quanmin Sang, Hongqian Jianghan Univ State Key Lab Precis Blasting Wuhan 430113 Peoples R China Jianghan Univ Hubei Key Lab Blasting Engn Wuhan 430056 Peoples R China Anhui Univ Sci & Technol Sch Chem & Blasting Engn Huainan 232001 Peoples R China Jianghan Univ Sch Optoelect Mat & Technol Wuhan 430056 Peoples R China

As a typical representative of Metastable intermolecular composites (MICs), the energy release of nano-thermites relying on aluminum-oxygen reaction is limited by the formation of high boiling point condensed phase products. Low pressure output performance constitutes another pivotal factor influencing their efficacy. In this work, metal fluorides BiF3 at different scales were incorporated into nano-thermites as oxidants, thereby facilitating the tunability of the released energy. The boiling points of all resultant reaction products fall below the combustion temperature, theoretically abolishing the agglomeration of condensed-phase products, thus preventing the entrapment of active metals. Additionally, it facilitates the smooth conduction of heat flux, thereby averting losses in biphasic flow dynamics. The n-Al/n-BiF3 system exhibits a significant amplification in reactive kinetic properties in stark contrast to the n-Al/n-Bi2O3 system. The reduction in ignition threshold is ascribed to a novel reaction kinetics mechanism within the n-Al/BiF3 system. The highly electronegative fluorine within BiF3 corrodes the Al2O3 shell, inducing a "pre-ignition" reaction. The application of Density Functional Theory (DFT) evaluations has further corroborated the n-Al/n-BiF3 system's preeminence in electron transfer capacity between the oxidizing agent and fuel, thereby furnishing an molecular-electronic basis for its potent reactive kinetic properties.

关键词： combustion mechanism metal fluorides metastable intermolecular composites nanostructured energetic materials pre-ignition reactions

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A molecularly imprinted electrochemiluminescence sensor based on ZnO@CdTe for the detection of mevastatin

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MICROCHEMICAL JOURNAL 2024年 203卷

作者： li, Huiling Tian, li Yang, Shuning li, Chao li, Ruidan Song, Yujia Guo, Yanjia li, xuwen Changchun Normal Univ Coll chem Changchun 130032 Peoples R China Jilin Univ Coll Chem Changchun 130012 Peoples R China

In this paper, CdTe quantum dots with near-infrared fluorescence (NIR) and hexagonal prism-shaped ZnO were synthesized, and the composites were characterized for their performance. A sensitive molecularly imprinted electrochemiluminescence (ECL) sensor for the determination of mevastatin was constructed based on ZnO@CdTe and molecularly imprinted polymer (MIP). The highest ECL intensity of the system was obtained by ZnO@CdTe as the main luminophores reacted with the co-reactant K2S2O8. The ECL response generated by the reaction of ZnO@CdTe and K2S2O8 was used as the basic signal detection platform. The MIP was prepared by the electropolymerization process on the above platform, which laid the foundation for forming the mevastatin cavities with specific recognition sites. In addition, the response mechanism was investigated, and the determination conditions were optimized. The ECL intensity change values (Delta I) of the sensor showed a good linear relationship with the logarithm of mevastatin concentration in the range of 2.0 x 10-11 to 2.0 x 10-6 mol L-1, and the limit of detection was 6.7 x 10-12 mol L-1 (S/N = 3). This method obtained satisfactory results in the detection of mevastatin in tablets.

关键词： Molecularly-imprinted ZnO@CdTe Mevastatin Electrochemiluminescence

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Corn Stover-derived nanocellulose and lignin-modified particles: Pickering emulsion stabilizers and potential quercetin sustained-release carriers

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FOOD CHEMISTRY 2025年第Pt 2期465卷 142021页

作者： Wu, Xinling Zhang, Qiang Zhou, Deyi Zhang, li Zhou, Haigen Gao, Xiaodi Fang, xuwen Huo, Chao Zhang, Jinsong Jilin Univ Coll Biol & Agr Engn Changchun 130022 Peoples R China

Pickering emulsions (PEs) have wide applications in delivering nutraceuticals. However, the impact of extracting nanocellulose from corn stover on stabilizing PEs and delivering nutraceuticals remains unclear. In this study, four types of nanocellulose, cellulose nanocrystals (CNC), cellulose nanofibers (CNF), lignin-containing cellulose nanocrystals (LCNC), and lignin-containing cellulose nanofibers (LCNF) were successfully prepared from corn stover, an agricultural waste. Among them, LCNC and LCNF exhibited stable reticulated microstructures, lower crystallinity, and excellent thermal stability. Besides, lignin enhanced the nanoparticles' hydrophobicity, promoting the formation of more ideally amphiphilic particles, resulting in denser emulsions at the oil-water interface. Furthermore, emulsions stabilized by LCNC and LCNF demonstrated remarkable resistance to quercetin degradation under UV light exposure (with residual level exceeding 90 %) and improved quercetin's bioaccessibility during the in vitro digestion tests, achieving the highest bioaccessibility of 48.3 %. This study provided an innovative perspective on utilizing stover-derived materials for stabilizing PEs and delivering lipophilic nutrients.

关键词： Corn Stover nanocellulose lignin Pickering emulsion Quercetin delivery In vitro digestion

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Development and Validation of a Screening Tool for Generalized Anxiety and Major Depressive Disorder in Patients with Chronic Obstructive Pulmonary Disease

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LUNG 2025年第1期203卷 1-12页

作者： liu, Meishan Yang, xuwen Wang, Dong Fang, Jiexin li, Boyu An, li Chang, Yuhan liu, Haiman Hu, Yongdong Huang, Kewu Capital Med Univ Beijing Inst Resp Med Dept Resp & Crit Care Med 8Gongti South Rd Beijing 100020 Peoples R China Capital Med Univ Beijing Chao Yang Hosp 8Gongti South Rd Beijing 100020 Peoples R China Capital Med Univ Beijing Chao Yang Hosp Dept Clin Psychol 8Gongti South Rd Beijing 100020 Peoples R China Capital Med Univ Beijing Chao Yang Hosp Dept Pharm Beijing Peoples R China

PurposeAnxiety and depression are often underdiagnosed in patients with chronic obstructive pulmonary disease (COPD). This study aimed to develop and validate a screening tool for anxiety and depression in COPD *** COPD patients were consecutively recruited from November 2021 to October 2023 and underwent a psychiatric interview to diagnose generalized anxiety disorder (GAD) and/or major depressive disorder (MDD) based on the Diagnostic and Statistical Manual of Mental Disorders, Fifth Edition. Patients were split into training and validation sets according to their recruitment time. We assessed known risk factors and used core items from the Patient Health Questionnaire Anxiety and Depression Scale (PHQ-ADS) to develop a prediction nomogram. Multivariable logistic regression with least absolute shrinkage and selection operator (LASSO) were used to construct the *** the enrolled COPD patients (n = 329), 58 (25.6%) in the training cohort and 33 (32.4%) in the validation cohort were diagnosed with GAD and/or MDD. Three variables were identified in the prediction nomogram: COPD Assessment Test score and two core items from PHQ-ADS. The under the curve (AUC) value for the nomogram was 0.826 (95% CI: 0.755-0.897) and 0.855 (95% CI: 0.767-0.942) in the training and validation cohorts, respectively. The calibration curve was close to the diagonal. The discriminatory power of the screening nomogram was comparable to that of PHQ-ADS (AUC: 0.826 vs. 0.831, P = 0.832).ConclusionThe new screening tool for GAD and MDD in COPD patients is concise and valid, with discriminatory power comparable to existing anxiety/depression screening questionnaires.

关键词： Chronic obstructive pulmonary disease Anxiety Depression Screening Nomogram

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NT-seq: a chemical-based sequencing method for genomic methylome profiling

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GENOME BIOLOGY 2022年第1期23卷 1页

作者： li, xuwen Guo, Shiyuan Cui, Yan Zhang, Zijian Luo, Xinlong Angelova, Margarita T. Landweber, Laura F. Wang, Yinsheng Wu, Tao P. Baylor Coll Med Dept Mol & Human Genet Houston TX 77030 USA Univ Calif Riverside Genet Genom & Bioinformat Grad Program Riverside CA 92521 USA Columbia Univ Dept Biochem & Mol Biophys New York NY USA Columbia Univ Dept Biol Sci New York NY 10027 USA Univ Calif Riverside Dept Chem Riverside CA 92521 USA Baylor Coll Med Huffington Ctr Aging Houston TX 77030 USA Baylor Coll Med Dan L Duncan Comprehens Canc Ctr Houston TX 77030 USA

DNA methylation plays vital roles in both prokaryotes and eukaryotes. There are three forms of DNA methylation in prokaryotes: N-6-methyladenine (6mA), N-4-methylcytosine (4mC), and 5-methylcytosine (5mC). Although many sequencing methods have been developed to sequence specific types of methylation, few technologies can be used for efficiently mapping multiple types of methylation. Here, we present NT-seq for mapping all three types of methylation simultaneously. NT-seq reliably detects all known methylation motifs in two bacterial genomes and can be used for identifying de novo methylation motifs. NT-seq provides a simple and efficient solution for detecting multiple types of DNA methylation.

关键词： DNA methylation Next-generation sequencing Whole-genome epigenetic profiling

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