Inverted(p-i-n)perovskite solar cells(PerSCs)have attracted much attention owing to their low temperature processability,less hysteresis effect and easy integration as a subunit for the tandem *** unsatisfactory inter...
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Inverted(p-i-n)perovskite solar cells(PerSCs)have attracted much attention owing to their low temperature processability,less hysteresis effect and easy integration as a subunit for the tandem *** unsatisfactory interface contacts and energy level barrier between adjacent interlayers on the cathode side are one of the key challenges for the development of p-i-n ***,perylene diimidebased(PDI)ionene polymer was synthesized and developed as a cathode interlayer(CIL)to enhance interface contact,reduce the energy level barrier and prevent the migration of *** compact PNPDI CIL with high conductivity and appropriate lowest unoccupied molecular orbital(LUMO)level,resulted in a high efficiency device(20.03%),which is higher than the control device with bathophenanthroline(Bphen)(19.48%).Bphen-based CIL shows better adjusting ability of the work function of cathode metal but exhibits poor film-forming ***,the synergistic effect of 1+1>2 can be obtained by combining Bphen and PNPDI into one *** expected,the device performance was further improved by using the mixed CIL of Bphen and PNPDI,and 21.46%power conversion efficiency(PCE)was ***’s more,the compact and hydrophobic mixed CIL dramatically enhanced the resistance to I-ions and moisture,which led to much enhanced device stability.
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