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Enabling rechargeable Li-MnO_(2) batteries using ether electrolytes

SmartMat 2023年第5期4卷 131-138页

作者： Dawei Xia Hongpeng Gao Mingqian Li John Holoubek Qizhang Yan Yijie Yin Panpan Xu Zheng Chen Department of NanoEngineering University of California San DiegoLa JollaCaliforniaUSA Program of Materials Science and Engineering University of California San DiegoLa JollaCaliforniaUSA Program of Chemical Engineering University of California San DiegoLa JollaCaliforniaUSA Sustainable Power and Energy Center University of California San DiegoLa JollaCaliforniaUSA

A low-carbon future demands more affordable batteries utilizing abundant elements with sustainable end-of-life battery *** the economic and environmental advantages of Li-MnO_(2)batteries,their applica-tion so far has been largely constrained to primary ***,we demonstrate that one of the major limiting factors preventing the stable cycling of Li-MnO_(2)batteries,Mn dissolution,can be effectively mitigated by employing a common ether electrolyte,1 mol/L lithium bis(trifluorometha-nesulfonyl)imide(LiTFSI)in 1,3-dioxane(DOL)/1,2-dimethoxyethane(DME).We discover that the suppression of this dissolution enables highly reversible cycling of the MnO_(2)cathode regardless of the synthesized phase and ***,we find that both the LiPF_(6)salt and carbonate solvents present in conventional electrolytes are responsible for previous cycling *** ether electrolyte,paired with MnO_(2)cathodes is able to demonstrate stable cycling performance at various rates,even at elevated temperature such as 60℃.Our discovery not only represents a defining step in Li-MnO_(2)batteries with extended life but provides design criteria of electrolytes for vast manganese-based cathodes in rechargeable batteries.

关键词： ether-based electrolytes Li-MnO batteries Mn deposition Mn dissolution reuse of primary batteries

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OPEN-SOURCE TOOLS FOR THE REFRACTORY ENGINEER OF THE PRESENT AND THE FUTURE 17

OPEN-SOURCE TOOLS FOR THE REFRACTORY ENGINEER OF THE PRESENT...

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17th Unified International Technical Conference on Refractories, UNITECR 2022

作者： Moreira, M.H. Santos, M.F. Pandolfelli, V.C. Federal University of Sao Carlos Graduate Program in Materials Science and Engineering SP Sao Carlos Brazil

Technology advances in the last century were able to reshape the world we live in. Relationships were physically and virtually changed by innovations going from transportation (engines, airplanes), to communication, (with phones, internet, and satellites). Considering this, the abilities and skills required for the young professionals have been shifting dramatically, and the refractory industry has demanded those that understand this new world and are able to solve its challenging problems. Because of the complexity of materials knowledge, which includes the latest advances in modeling and data science, a sophisticated blend of fundamental concepts and advanced techniques that defies how to promote education effectively was generated. For instance, the heat transfer mechanisms within the refractory material can be both discussed on the fundamental level or on how to perform advanced simulations to describe it, granting the engineer the ability to solve real-life problems. The present work aims to classify this new set of needed tools, explore options to conciliate fundamentals with advanced tools and conjecture strategies to educate the present and future professionals. As a conclusion, the minimum package of skills is presented considering the association of industry, academics, students and computing, all synergistically working together to solve the new challenges and promote true innovation. © 2022 Unified International Technical Conference on Refractories, UNITECR 2022 - Proceedings. All rights reserved.

关键词： Refractory materials

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Terahertz phonon polariton concentrator based on perovskite oxides

Terahertz phonon polariton concentrator based on perovskite ...

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2023 Conference on Lasers and Electro-Optics, CLEO 2023

作者： Xu, Rui Lin, Tong Luo, Jiaming Chen, Xiaotong Blackert, Elizabeth R. Moon, Alyssa R. JeBailey, Khalil M. Zhu, Hanyu Department of Materials Science and Nano Engineering Rice University Houston United States Applied Physics Graduate Program Rice University Houston United States Program Rice University Houston United States

ISBN: (纸本)9781957171258

We report the experimental demonstration of surface phonon-polaritonic devices in a broad spectral range of 7-13 THz based on SrTiO3. We designed planar ultrafast concentrators that amplifies transient electric field by 6 times and measured an average field of 0.5 GV/m in an optically resolvable area in the far field. © 2023 The Author(s)

关键词： Perovskite

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Transport and magnetic properties of Hund's metal CaRuO3 under strain modulation

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Physical Review B 2024年第4期110卷 L041403-L041403页

作者： Zhen Wang Arjyama Bordoloi Zhaoqing Ding Enling Wang Xiaofeng Wu Zeguo Lin Mingyu Yang Chenxu Liu Jinglin Zhou Meng Meng Fang Yang Qinghua Zhang Xiaoran Liu Sobhit Singh Huan-hua Wang Jiandong Guo Beijing National Laboratory for Condensed Matter Physics and School of Nuclear Science and Technology Department of Mechanical Engineering School of Physical Sciences Materials Science Program

We synthesized CaRuO3 (001) thin films on a set of substrates and investigated their electronic and magnetic properties via combining magnetotransport measurements with first-principles density-functional theory calculations. The experimental results indicate that a moderate strain can introduce the Kondo effect in the system, leading to a significant modulation of the non-Fermi liquid behavior. Moreover, when the strain reaches a certain threshold, the system undergoes a metal-semiconductor transition, accompanied by a transition from a nonmagnetic state to a plausible G-type antiferromagnetic state. We attribute the observed phenomena in CaRuO3 to strain-induced disruption of the delicate balance between the itinerant and the local Ru 4d electrons. These findings shed light on the intriguing magnetic and non-Fermi liquid behavior of CaRuO3, systematically tailored by heteroepitaxial strain.

关键词： Density of states Kondo effect Transport phenomena Ruthenates Ultrathin films Density functional calculations Physical deposition Resistivity measurements Strain engineering X-ray diffraction X-ray reflectivity

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Effect of an antiferromagnetic order on tailoring Dzyaloshinskii- Moriya interaction in Pt/Co/IrMn trilayer

Effect of an antiferromagnetic order on tailoring Dzyaloshin...

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2023 IEEE International Magnetic Conference - Short Papers, INTERMAG Short Papers 2023

作者： Chen, Sheng-Huai Yang, Chao-Yao Lai, Chih-Huang National Tsing Hua University Department of Materials Science and Engineering Hsinchu300044 Taiwan National Yang Ming Chiao Tung University Department of Materials Science and Engineering Hsinchu300093 Taiwan National Yang Ming Chiao Tung University Undergraduate Degree Program of Systems Engineering and Technology Hsinchu300093 Taiwan

ISBN: (纸本)9798350338362

Antiferromagnet (AFM) has currently participated in the spin-orbit torque (SOT) magnetoresistive random access memory (MRAM) technolopgy due to its great potential to be applied to the field-free SOT switching and promote the thermal stability of MRAM. However, effect of the introduction of AFM into the basic structure of SOT-MRAM composed of a heavy metal/ferromagnet (FM) bilayer was still not comprehensively understood. This work reports the effect of how an antiferromagnetic (AFM) order modifies the strength of Dzyaloshinskii-Moriya interaction (DMI) in a heavy metal (Pt)/FM (Co)/AFM (IrMn) trilayer, studied by SOT switching and loop-shift method. Increasing the AFM order reflected on exchange bias (Hex) through increasing the thickness of IrMn appears to significantly reduce the DMI strength of the trilayer, which leads to the reduction of the external field for yielding a complete SOT switching. The reduced DMI strength may ascribe to the Hex-hosted uni-directional anisotropy suppressing the neighboring spin canting in the FM layer. This stabilization for the magnetic moments via the Hex-hosted uni-directional anisotropy also improved the stability of SOT switching on the random read/write characterization, in which the strong AFM order would promote the memristivity for neuromorphic application and the weak AFM order would give rise to the stochasticity for the purpose of physically unclonable functionality. This work demonstrates the significance of an intrinsic tuning over the AFM order would serve as a switch to turn the SOT device into a stochastic/memristive cell to bridge probabilistic and neuromorphic computing. © 2023 IEEE.

关键词： Stochastic systems

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Revisiting a hidden order at an ferromagnet/antiferromagnet interface and its switching dynamics

Revisiting a hidden order at an ferromagnet/antiferromagnet ...

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2023 IEEE International Magnetic Conference - Short Papers, INTERMAG Short Papers 2023

作者： Yang, Chao-Yao Chen, Sheng-Huai Lai, Chih-Huang National Yang Ming Chiao Tung University Department of Materials Science and Engineering Hsinchu300093 Taiwan National Yang Ming Chiao Tung University Undergraduate Degree Program of Systems Engineering and Technology Hsinchu300093 Taiwan National Tsing Hua University Department of Materials Science and Engineering Hsinchu300044 Taiwan

ISBN: (纸本)9798350338362

Study on the exchange bias (Hex) switching in a ferromagnet (FM)/antiferromagnet (AFM) bilayer driven by the spin-orbit torque (SOT) has been an explicit research field and current focus has been devoted to determining the approaches to drive the Hex switching along with specific SOT applications. Hex is magnetically dominant but only reveals the partial facet of IrMn, which is only responsible for the ferromagnetic component at the interface of AFM. Therefore, the complete facet of AFM and its interaction with SOT at an FM/AFM interface is still not fully uncovered. This research reports an SOT-driven hidden order transition behind Hex in a heavy metal (Pt)/FM (Co)/AFM (IrMn) trilayer along with the issue of switching activity at Co/IrMn interface. The exchange coupling across Co/IrMn interface allows a long-range spin order in the form of an exchange-spring configuration, yielding two kinds of order in IrMn: a canting-induced ferromagnetic order for hosting Hex and a hidden Néel order for preserving the antiferromagnetic nature. The former appears to be strongly coupled to the magnetization state of Co during the SOT switching, so it can be reversibly switched with Co on the Hex switching. On the contrary, the hidden Néel order transition re-orientated to the current direction appears to be irreversibly driven by SOT and independent on the current polarity, which can reflect on the magnetoresistance (MR) measurement and X-ray magnetic linear dichroism (XMLD) spectroscopy. Finally, a micromagnetic simulation reveals the dynamic IrMn spins are mainly based on a canting type interface instead of an uncompensated type via an exchange-spring coupling with Co. © 2023 IEEE.

关键词： Binary alloys

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Effect of Yttrium Treatment on Germanium-Oxide-Based Interfacial Layer of Ge P-Channel Metal–Oxide–Semiconductor Field-Effect Transistor Fabricated Through In Situ Plasma-Enhanced Atomic Layer Deposition

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IEEE Transactions on Electron Devices 2024年第3期71卷 1-6页

作者： Li, Hui-Hsuan Lin, Kuan-Yu Tsai, Yi-He Lin, Yu-Hsien Chien, Chao-Hsin Institute of Electronics National Yang Ming Chiao Tung University Hsinchu Taiwan Graduate Program for Nanotechnology Department of Materials Science and Engineering National Yang Ming Chiao Tung University Hsinchu Taiwan Department of Electronic Engineering National United University Miaoli Taiwan

This study investigated the effect of yttrium (Y) treatment on a germanium (Ge)-oxide-based interfacial layer (IL) through in situ plasma-enhanced atomic layer deposition (PEALD). Time-of-flight secondary-ion mass spectrometry revealed that the surface reaction and deposition could be successfully performed with a Y precursor, and X-ray photoelectron spectroscopy (XPS) revealed that Y treatment on an IL can suppress GeO

$_{\text{x}}$

volatilization. A metal–oxide–semiconductor capacitor gate-stack with a Y-GeO

$_{\text{x}}$

IL has a low leakage current density (2.1

$\times$

$^{-\text{5}}$

A/cm

$^{\text{2}}$

) and a low interface trap density (approximately 5.5

$\times$

$^{\text{11}}$

$^{-\text{1}}$

$^{-\text{2}}$

) under optimized temperatures. Moreover, the Ge P-channel metal–oxide–semiconductor field-effect transistor (P-MOSFET) containing a gate-stack with a Y-treated Ge-oxide-based IL exhibited a high I

$_{\biosc{on}}$

$_{\biosc{off}}$

ratio and low OFF-state current. Therefore, applying the proposed Y treatment on the IL of a Ge P-MOSFET can help achieve a subnanometer equivalent oxide thickness (EOT) and an

关键词： Ge-oxide-based germanium germanium oxide (GeOx) in situ interfacial layer (IL) plasma-enhanced atomic layer deposition (PEALD) Y-GeOx yttrium

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An ultraefficient surface functionalized Ti3C2Tx MXene piezocatalyst: synchronous hydrogen evolution and wastewater treatment

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Journal of materials Chemistry A 2023年第6期12卷 3340-3351页

作者： Lai, Sz-Nian Chen, Winston Yenyu Yen, Chao-Chun Liao, Yin-Song Chen, Po-Han Stanciu, Lia Wu, Jyh Ming Department of Materials Science and Engineering National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan PhD Program in Prospective Functional Materials Industry National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan High Entropy Materials Center National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan Tsing Hua Interdisciplinary Program National Tsing Hua University 101 Section 2 Kuang Fu Road Hsinchu300 Taiwan School of Materials Engineering Purdue University 610 Purdue Mall West LafayetteIN47907 United States Department of Materials Science and Engineering National Chung Hsing University 145 Xingda Road Taichung402 Taiwan

The Ti3C2Tx surface contains hydroxyl groups that can be modified through self-assembled monolayers by using (3-chloropropyl) trimethoxysilane (CPTMS) and fluoroalkylsilane (FOTS). This study demonstrates that an ultrahigh level of piezoelectricity can be achieved by modifying the Si-O bond of organo-silane headgroups in Ti3C2Tx. The theoretical calculation of surface functionalized Ti3C2Tx-FOTS reveals that its Si-O bond causes localized lattice distortion and enhances the noncentrosymmetric structure on the Ti3C2Tx surface. Ti3C2Tx-FOTS exhibits significantly higher butterfly loops than pristine Ti3C2Tx. The calculated rate constant of Ti3C2Tx-FOTS for dye degradation was 0.9 min−1, 15-fold higher than that of Ti3C2Tx-CPTMS and 111-fold higher than that of pristine Ti3C2Tx. The hydrogen evolution rate of Ti3C2Tx-FOTS is 900.46 μmo1 g−1 h−1, three times higher than that of Ti3C2Tx. The bifunctional surface functionalized Ti3C2Tx-FOTS can simultaneously catalyse the hydrogen evolution reaction (HER) and decomposition of wastewater, demonstrating that Ti3C2Tx-FOTS, obtained through the surface engineering of Ti3C2Tx, is a superior piezocatalyst. © 2024 The Royal Society of Chemistry.

关键词： Rate constants

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A Kinetic Theory for the Mechanics and Remodeling of Transient Anisotropic Networks

SSRN

引用

SSRN 2024年

作者： Vernerey, Franck J. Rezai, Behnam Lamont, Samuel C. Department of Mechanical Engineering Program of Materials Science and Engineering University of Colorado Boulder United States

We present a statistically-based theoretical framework to describe the mechanical response of dynamically cross-linked semi-flexible polymer networks undergoing finite deformation. The theory starts from a statistical description, via a distribution function, of the chain conformation and orientation. Assuming a so-called tangent affine deformation of the chains, this distribution is then allowed to evolve in time due to a combination of elastic network distortion and a permanent chain reconfiguration enabled by dynamic cross-links. After presenting the evolution law for the chain distribution function, we reduce the theory to the evolution of the network conformation tensor in both its natural and current state. With this model, we use classical thermodynamics to determine how the stored elastic energy, energy dissipation, and true stress evolve in terms of the network conformation. We show that the model degenerates to classical anisotropic hyperelastic models when cross-links are permanent, while we recover the classical form of the transient network theory (that describes hyper-viscoelasticity) when chains are fully flexible. Theoretical predictions are then illustrated and compared to the literature for both basic model problems and biomechanically relevant situations. © 2024, The Authors. All rights reserved.

关键词： Statistical mechanics

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Surface analysis of different wood polymer composites exposed to artificial weathering

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Journal of Wood Chemistry and Technology 2024年第2期44卷 88-101页

作者： Andrey Pereira Acosta Sandro Campos Amico Rafael de Avila Delucis André Luiz Missio Marlon Bender Bueno Rodrigues Ana Carolina Rodrigues Ribeiro Matheus de Paula Goularte Darci Alberto Gatto a PostGraduate Program in Mining Metallurgical and Materials Engineering Federal University of Rio Grande do Sul Porto Alegre Brazil b PostGraduate Program in Materials Science and Engineering Federal University of Pelotas Pelotas Brazil c Materials Engineering Undergraduate Course Federal University of Pelotas Pelotas Brazil

This study presents a superficial analysis of different wood polymer composites (WPC) comprising polystyrene (WPSC), poly(furfuryl alcohol) (WPFAC), and pine resin (WPRC) when exposed to artificial weathering. The study investigates the influence of resin type on the composites, focusing on their chemical, colorimetric, morphological, and thermal properties. The main findings indicate WPSC exhibits poor resistance to weathering, allowing ultraviolet radiation damage on the lignocellulosic component of the composite, leading to oxidized groups formation. Conversely, WPFAC and WPRC demonstrate good wood protection capabilities by preventing significant deterioration of holocellulose and acting as filters for radiation and moisture. Moreover, WPFAC exhibits the lowest decrease in carbonyl index and O/C ratio, with reductions of 2.6 and 11.6%, respectively. These findings are significant as they demonstrate that poly(furfuryl alcohol) and pine resin can be used to produce WPCs that delay and mitigate wood degradation by weathering, contributing to the increased potential utilization of *** AbstractDisplay full size

关键词： Chemical changes discoloration surface color UV degradation

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