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Dynamic Surrogate Optimization of Vertically Stacked Nanosheet FET Based on Gaussian Process Regression

IEEE Access 2025年 13卷 95730-95738页

作者： Christofer N. Yalung Doldet Tantraviwat Doctor of Philosophy Program in Nanoscience and Nanotechnology (International Program/Interdisciplinary) Materials Science Research Center Faculty of Science Chiang Mai University Chiang Mai Thailand Department of Electrical Engineering Faculty of Engineering Chiang Mai University Chiang Mai Thailand Center of Excellence in Materials Science and Technology Faculty of Science Chiang Mai University Chiang Mai Thailand

While speed improvements are pivotal for advancing modern transistor technologies and ensuring faster computational performance, the tradeoffs with other critical electrical properties, such as threshold voltage ( $V_{T}$ ) and off-current ( $I_{OFF}$ ), are often overlooked. These tradeoffs can significantly impact the overall device performance. The design of vertically stacked n-type and p-type nanosheet FETs (NSFETs) was applied using a dynamic surrogate optimization-gaussian process regression (DSO-GPR) with batch assessment and halting conditions. A vertically stacked silicon-based system is created and refined. Source extension ( $S_{ext}$ ), drain extension ( $D_{ex\mathrm {t}}$ ), gate length ( $L_{g}$ ), nanosheet height (NSh), nanosheet width (NSw), and number of fin (nfin) make up the input variables. In addition to applying normalization to make the weight assignment to the goal functions easier, a penalty component was incorporated to manage the $V_{T}$ . This study demonstrates the effectiveness of the DSO-GPR framework in optimizing NSFET-based inverter designs by balancing speed, $I_{OFF}$ and $V_{T}$ . Among the three evaluated cases, case 1 achieved the fastest propagation delay (1.05 ps) due to higher $I_{ON}$ and lower $V_{T}$ , albeit with increased $I_{OFF}$ and $V_{T}$ mismatch. Case 2 provided a balanced trade-off, significantly reducing $I_{OFF}$ while maintaining a competitive delay of 1.25 ps and achieving $V_{T}$ matching at 0.11 V for both n-type and p-type NSFETs. The optimum parameters for n-type are ${L} _{g}$ = 5 nm, $N_{Sh} = 9$ nm, $N_{Sw} = 42$ nm, $S_{ext} = 3$ nm and $D_{ext} = 4$ nm, nfin = 5; for p-type, $L_{g} = 7$ nm, $N_{Sh} = 10$ nm, $N_{Sw} = 42$ nm, $S_{ext} = 3$ nm and $D_{ext} = 3$ nm, nfin = 5. Case 3 minimized leakage at the cost of delay, highlighting the trade-off between power and performance. These results validate the framework’s adaptability and automation, with performance-based stopping criteria that balance

关键词： Optimization Logic gates Ions Silicon Performance evaluation Linear programming Gaussian processes Field effect transistors Accuracy Machine learning

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A Review on Application of Poly(3,4-ethylenedioxythiophene) (PEDOT) in Rechargeable Batteries

Organic Materials

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Organic materials 2022年第4期4卷 292-300页

作者： Su, Laisuo Kumar, Shwetha Sunil Manthiram, Arumugam Reeja-Jayan, B. Materials Science and Engineering Program Texas Materials Institute The University of Texas at Austin Austin 78712 TX United States Department of Mechanical Engineering Carnegie Mellon University Pittsburgh 15213 PA United States

Since the very first patent on poly(3,4-ethylenedioxythiophene) (PEDOT) that was filed in 1988, this polymer has been widely utilized and has achieved great success owing to its high electrical conductivity and excellent stability. The application of the conducting polymer, PEDOT, in renewable energy devices, especially rechargeable batteries, is attracting increasing attention due to its potential to solve the energy and climate crisis. In this review, we summarize the research over the past few decades directed toward the application of PEDOT in rechargeable batteries aimed at improving their electrochemical performance. We focus on PEDOT synthesized via oxidative chemical vapor deposition (oCVD), a relatively new process known for its ability to grow conducting polymer thin films with uniform, pinhole-free properties, and controllable thickness and conformality. For a comparison purpose, PEDOT synthesized via solution-based methods is also briefly summarized. Finally, future research directions for applying oCVD PEDOT in rechargeable batteries are discussed. Introduction PEDOT Synthesis Methods Application of oCVD PEDOT in Rechargeable Batteries Applications of Solution-Based PEDOT in Rechargeable Batteries Conclusions and Outlook. © 2022. The Author(s).

关键词： batteries coating oxidative chemical vapor deposition (oCVD) polyethylene dioxythiophene (PEDOT)

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Method for assessing atomic sources of flicker noise in superconducting qubits

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npj Computational materials 2021年第1期7卷 1502-1507页

作者： Almog Reshef Maytal Caspary Toroker Department of Materials Science and Engineering Technion–Israel Institute of TechnologyHaifaIsrael The Nancy and Stephen Grand Technion Energy Program HaifaIsrael

Flicker noise causes decoherence in Josephson junction-based superconducting qubits,thus limiting their practical potential as building blocks for quantum *** is due to limited length and complexity of executable algorithms,and increased dependency on error-correcting ***,identifying and subsiding the atomic sources of flicker noise are of great importance to the development of this *** developed a method that combines ab initio DFT calculations and quantum dynamics to model charge transport across a Josephson junction,by which it is possible to more accurately assess different defects as sources of flicker *** demonstrate the use of our method in an investigation of various atomic defects,including vacancies,trapping,and substitutions,in an Al|Al_(2)O_(3)|Al Josephson *** demonstration both reveals weaknesses in previous attempts to pinpoint the atomic sources of flicker noise and highlights new candidates.

关键词： Josephson quantum limiting

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Assembly of exfoliated α-zirconium phosphate nanosheets:Mechanisms and versatile applications

Aggregate

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Aggregate 2022年第4期3卷 41-60页

作者： Hao Ding Abbas Ahmed Kuangyu Shen Luyi Sun Polymer Program Institute of Materials ScienceUniversity of ConnecticutStorrsConnecticutUSA Department of Chemical and Biomolecular Engineering University of ConnecticutStorrsConnecticutUSA Department of Biomedical Engineering University of ConnecticutStorrsConnecticutUSA

α-Zirconium phosphate(Zr(HPO_(4))_(2)⋅H_(2)O,α-ZrP)is an inorganic layered *** the first report of crystallineα-ZrP in 1964,thanks to its simple synthesis and unique physiochemical properties,α-ZrP has found widespread application in many fields including mechanical reinforcing,barrier improvement,flame retardancy,anticorrosion,catalysis,environment,energy,and *** of the ease of exfoliation ofα-ZrP to obtain single-layer nanosheets,as well as its rich surface chemistry thanks to the high density of orderly arranged surface acidic hydroxyl groups,α-ZrP single-layer nanosheets are ideal building blocks for self-assembly or assembly with other *** assembly ofα-ZrP nanosheets could form a randomly dispersed structure(isotropic),roughly ordered structure(nematic),or highly ordered structure(smectic)within liquid colloids or solid hybrids(including hydrogels).Thanks to the combination of the unique structures and the novel functions of the components,the assembled materials have found a wide verity of applications due to their excellent *** this article,the methods to synthesizeα-ZrP,the approaches and mechanisms to exfoliateα-ZrP,and the strategies to assembleα-ZrP nanosheets to form various structures,as well as the applications of the assembled materials are *** emerging prospects ofα-ZrP nanosheets as a key material in next-generation functional applications are envisioned.

关键词： application assembly exfoliation nanosheets α-zirconium phosphate

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Cyclic thermal treatment parameters of bagasse particle reinforced epoxy bio-composites for sustainable applications

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Discover Polymers 2025年第1期2卷 1-22页

作者： Oladele, Isiaka Oluwole Falana, Samuel Olumide Ilesanmi Akinbamiyorin, Michael Onuh, Linus Nnabuike Taiwo, Anuoluwapo Samuel Adelani, Samson Oluwagbenga Olajesu, Olanrewaju Favor Department of Metallurgical and Materials Engineering Federal University of Technology Akure Nigeria Department of Materials Science and Engineering Iowa State University Ames USA Faculty of Materials and Chemical Engineering University of Miskolc Miskolc Hungary Department of School of Aerospace Transport and Manufacturing School of Aerospace Transport and Manufacturing Cranfield University Cranfield UK Materials Science and Engineering Program University of Colorado Boulder USA

The demand for sustainable, high-performance materials has led to increased interest in bio-based composites. However, optimizing the mechanical properties of such materials for engineering applications remains a challenge. This study addresses this gap by developing and characterizing an epoxy-based biocomposite reinforced with sugarcane bagasse particles, focusing on the influence of cyclic thermal treatment on its properties. The bagasse particles were chemically treated with 1 M NaOH to remove impurities, improve interfacial bonding with the epoxy matrix, and enhance the overall composite performance. The treated particles j were pulverized to 470 µm and incorporated into the epoxy matrix (0–20 wt%) using the hand layup method. The composites were divided into untreated and thermally treated groups, with the latter subjected to cyclic thermal treatment (100 °C for 3 h over 7 days). Mechanical, wear, and water absorption properties were evaluated, while fractured surface morphologies were analyzed using SEM. Results revealed that cyclic thermal treatment significantly enhanced the composites’ performance, with the 15 wt% heat-treated composite showing optimal properties: density of 1.102 g/cm3, flexural strength of 29.13 MPa, ultimate tensile strength of 103.50 MPa, impact strength of 3.49 kJ/m2, hardness of 64.70 HS, and wear indices of 0.034 mg. These findings demonstrate that alkali treatment and cyclic thermal treatment synergistically enhance the performance of bio-composites, making them suitable for diverse applications, including automotive, aerospace, and other engineering fields.

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Transforming organic chemistry research paradigms:Moving from manual efforts to the intersection of automation and artificial intelligence

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National science Open 2024年第2期3卷 98-127页

作者： Chengchun Liu Yuntian Chen Fanyang Mo School of Materials Science and Engineering Peking UniversityBeijing 100871China Ningbo Institute of Digital Twin Eastern Institute of TechnologyNingbo 315000China AI for Science(AI4S)-Preferred Program Peking University Shenzhen Graduate SchoolShenzhen 518055China

Organic chemistry is undergoing a major paradigm shift,moving from a labor-intensive approach to a new era dominated by automation and artificial intelligence(AI).This transformative shift is being driven by technological advances,the ever-increasing demand for greater research efficiency and accuracy,and the burgeoning growth of interdisciplinary *** models,supported by computational power and algorithms,are drastically reshaping synthetic planning and introducing groundbreaking ways to tackle complex molecular *** addition,autonomous robotic systems are rapidly accelerating the pace of discovery by performing tedious tasks with unprecedented speed and *** article examines the multiple opportunities and challenges presented by this paradigm shift and explores its far-reaching *** provides valuable insights into the future trajectory of organic chemistry research,which is increasingly defined by the synergistic interaction of automation and AI.

关键词： organic chemistry automation platform artificial intelligence algorithms

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A Comparative Study of the Effect of Compounding Methods and Processing of PLA/GNPs on the Micromorphology and Electrical Conductivity 38

A Comparative Study of the Effect of Compounding Methods and...

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38th Technical Conference of the American Society for Composites, ASC 2023

作者： Anurakparadorn, Kanat Taub, Alan Department of Materials Science and Engineering Macromolecular Science and Engineering Program University of Michigan 2300 Hayward St Ann ArborMI48109 United States Department of Mechanical Engineering University of Michigan 2350 Hayward St Ann ArborMI48109 United States

ISBN: (纸本)9781605956916

In this work, the effects of different compounding and processing techniques on the DC electrical conductivity and density of polylactic acid (PLA)/graphene nanoplatelets (GNPs) composites were studied. It is found from the study that compounding by solution mixing via an ultrasonication technique can provide slightly higher DC electrical conductivity after compression molding than mixing through a twin-screw extruder due to better dispersion quality. In addition, a composite pellet from twin screw extrusion showed a slight increase in DC electrical conductivity and anisotropy when processed by filament extrusion due to the shear alignment of GNPs during the extrusion. The fused deposition modeling (FDM) process yields high anisotropy because the crystallization along the printing path allows gaps and polymer coating between the extruded lines and layers. It was found that the 7.5 wt% GNPs composites exhibited the best properties because it provides the best dispersion quality to meet the percolation threshold. Furthermore, the micromorphology of each sample was also studied to observe the dispersion and porosity inside the composite provided by each fabrication technique. This study can be used as a reference for compounding and processing techniques. © 2023 by DEStech Publications, Inc. and American Society for Composites. All rights reserved.

关键词： Mixing

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Preface to the Special Issue:Anode materials for Rechargeable Batteries

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Acta Metallurgica Sinica(English Letters) 2021年第3期34卷 289-290页

作者： Jianmin Ma Yu-Tao Li School of Physics and Electronics Hunan UniversityChangsha 410082China Materials Science and Engineering Program and Texas Materials InstituteThe University of Texas At AustinAustinTX 78712USA

Rechargeable Li-ion batteries were first commercialized in 1991 by Sony company,and the current portable electronic devices and electric vehicles powered by rechargeable batteries have significantly accelerated the development of social *** Nobel Prize in Chemistry 2019 was also awarded jointly to John ***,*** Whittingham,and Akira Yoshino for their outstanding contribution to rechargeable Li-ion batteries.

关键词： charge jointly enough

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Sensitivity improvement of fluoroalkylated EUV resist with electron-rich vinyl units 41

Sensitivity improvement of fluoroalkylated EUV resist with e...

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Advances in Patterning materials and Processes XLI 2024

作者： Kim, Gayoung Ku, Yejin Lee, Jin-Kyun Kim, Jiho Park, Byeong-Gyu Lee, Sangsul Jang, Yu Ha Jung, Byung Jun Koh, Chawon Nishi, Tsunehiro Kim, Hyun-Woo Program in Environment and Polymer Engineering Inha University Incheon22212 Korea Republic of Department of Polymer Science and Engineering Inha University Incheon22212 Korea Republic of Pohang Accelerator Laboratory Postech Pohang37673 Korea Republic of Department of Materials Science and Engineering University of Seoul Seoul02504 Korea Republic of Samsung Electronics Co. Ltd. Semiconductor R&d Center Suwon18448 Korea Republic of Department of Materials Science and Engineering Yonsei University Seoul03722 Korea Republic of

ISBN: (纸本)9781510672208

In this study, we present a method to enhance the sensitivity of fluorinated EUV resists by leveraging the rapid coupling reaction between electrophilic carbon radicals and electron-rich alkenes. To validate the impact of the vinyl groups, DVS-HNF was synthesized by introducing fluorinated alkyl chains and silyl vinyl functional groups into the model compound. Additionally, TMS-HNF and EDMS-HNF, which do not contain a vinyl moiety, were synthesized for comparison. To evaluate the patterning properties of the three materials, e-beam lithography experiments were conducted, resulting in the formation of negative-tone patterns for all three materials. Comparing sensitivities, DVS-HNF with two vinyl moieties exhibited the most excellent sensitivity, confirming the effective collaboration between fluorinated alkyl radicals and vinyl groups. After performing an EUV lithography experiment on DVS-HNF, it was confirmed that a 30 nm negative-tone pattern was successfully formed with excellent sensitivity. These results substantiate the potential of the single-component molecular resist for high performance EUV lithography. © COPYRIGHT SPIE. Downloading of the abstract is permitted for personal use only.

关键词： Extreme ultraviolet lithography

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Superhydrophobic fluoride conversion coating on bioresorbable magnesium alloy——fabrication,characterization,degradation and cytocompatibility with BMSCs

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Journal of Magnesium and Alloys 2021年第4期9卷 1252-1266页

作者： Chunyan Zhanga Shiyu Zhang Dongwei Sun Jiajia Lin Fancheng Meng Huinan Liu School of Materials Science&Engineering Chongqing University of TechnologyNo.69 Hongguang AvenueChongqing 400054China Department of Bioengineering and the Materials Science and Engineering ProgramUniversity of CaliforniaRiverside900 University AvenueMSE 205RiversideCA 92521USA

A micro-nano structure CaF_(2)chemical conversion layer was prepared on fluoride-treated AZ31 alloy,then the composite fluoride conversion film(CaF_(2)/MgF_(2))was modified by stearic acid(SA)and fabricated a superhydrophobic *** fluoride-treated magnesium,fluoride conversion film and superhydrophobic coating were characterized by SEM,EDS,XRD and *** properties of coatings1 adhesion and corrosion resistance were evaluated via tape test and electrochemical *** cytocompatibility of the MgF_(2),CaF_(2)and superhydrophobic CaF_(2)/SA surface was investigated with bone marrow-derived mesenchymal stem cells(BMSCs)by direct culture for 24 *** results showed that the superhydrophobic fluoride conversion coating composed of inner MgF_(2)layer and the outer CaF_(2)/SA composite layer had an average water contact angle of 152°.SA infiltrated into the micro-nano structure CaF_(2)layer and formed a strong adhesion with CaF_(2)***,the super-hydrophobic coating showed higher barrier properties and corrosion resistance compared with the fluoride conversion film and fluoride-treated AZ31 *** BMSC adhesion test results demonstrated MgF_(2)CaF_(2)and CaF_(2)/SA coatings were all nontoxic to *** the condition of in direct contact with cells,MgF_(2)showed higher cell density and enhanced the BMSCs proliferation,while CaF_(2)and CaF_(2)/SA coating showed no statistically difference in cell density compared with glass reference but the CaF_(2)and CaF_(2)/SA coating were not conducive to BMSCs adhesion.

关键词： Biodegradable Magnesium alloy Superhydrophobic Fluoride conversion film Cytocompatibility

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