Self-assembly of metal-coordination cages has attracted much attention in the past two decades because of their fascinating structures and interesting host-guest ***,the anions play a decisive role since they act as n...
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Self-assembly of metal-coordination cages has attracted much attention in the past two decades because of their fascinating structures and interesting host-guest ***,the anions play a decisive role since they act as not only the balance charges but also the structure-directing ***
Introduction Thiacalix[4]arencs and its derivative sulfonylcalix[4]arenc,which are macrocyclic ligands and preferentially bond to four TM（TM=transition metal）ions by their lower-rim phenolic oxygen atoms and bridge
Introduction Thiacalix[4]arencs and its derivative sulfonylcalix[4]arenc,which are macrocyclic ligands and preferentially bond to four TM（TM=transition metal）ions by their lower-rim phenolic oxygen atoms and bridge
Introduction p-tert-Butylcalix[8]arene（HTBC8A）,1 as a bowl-shaped macrocyclic ligand possessing eight lower-rim phenolic oxygen atoms,has been utilized to construct polymetallic compounds in recent years.2Results an...
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Introduction p-tert-Butylcalix[8]arene（HTBC8A）,1 as a bowl-shaped macrocyclic ligand possessing eight lower-rim phenolic oxygen atoms,has been utilized to construct polymetallic compounds in recent years.2Results and Discussion
Introduction Thiacalix[4]arenes and its derivative sulfonylcalix[4]arene,which are macrocyclic ligands and preferentially bond to four TMⅡ (TM = transition metal) ions by their lower-rim phenolic oxygen atoms and bri...
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Introduction Thiacalix[4]arenes and its derivative sulfonylcalix[4]arene,which are macrocyclic ligands and preferentially bond to four TMⅡ (TM = transition metal) ions by their lower-rim phenolic oxygen atoms and bridge sulfur/sulfonyl oxygen atoms to form shuttlecock-like TM4-calix[4]arene subunits,have regarded as good molecular building blocks (MBBs) for construction of polynuclear entities.1
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