The molecular parameters of ArH＋ have been calculated with different quantum chemistry methods and basis *** on the data from QCISD/Aug cc pVTZ ab initio calculation for different configurations of ArH＋ and the expe...
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The molecular parameters of ArH＋ have been calculated with different quantum chemistry methods and basis *** on the data from QCISD/Aug cc pVTZ ab initio calculation for different configurations of ArH＋ and the experimental data,an accurate potential curve for ArH＋ has been *** molecular properties,such as dissociation energy,equilibrium bond length,and vibrational energy levels,can be accurately reproduced.
The synthesis of a novel α phosphorus containing spin trap, DEPDMPO(5 diethoxy Phosphoryl 2, 5 dimethyl 1 pyrroline \%N\% oxide) and the evaluation of its ability to spin trap the hydroxyl and the superoxide anion ra...
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The synthesis of a novel α phosphorus containing spin trap, DEPDMPO(5 diethoxy Phosphoryl 2, 5 dimethyl 1 pyrroline \%N\% oxide) and the evaluation of its ability to spin trap the hydroxyl and the superoxide anion radicals were described in the present article. The ability to trap an active superoxide anion radical generated in the photo system Ⅱ(PSII) and the stability of their spin adduct of DEPDMPO as well as three previously reported traps DMPO, DEPMPO and M 3PO were comparatively analyzed according to their chemical structures. In addition, the effects of 2 methyl and \%α\% phosphoryl substituted analogues of DMPO on the stabilities of the corresponding spin adduts were systematically
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