The title complex ([SmN(CH 2COO) 3(H 2O) 2]·H 2O, M r =392.52) has been prepared from Sm(ClO 4) 3 and NH 2(CH 2COO) 3Na in aqueous solution. The crystal structure of the complex was determined by X ray diffractio...
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The title complex ([SmN(CH 2COO) 3(H 2O) 2]·H 2O, M r =392.52) has been prepared from Sm(ClO 4) 3 and NH 2(CH 2COO) 3Na in aqueous solution. The crystal structure of the complex was determined by X ray diffraction method. The crystal belongs to the orthorhombic system with space group Pbca, a=8.110(1), b=13\^120(2), c=20.788(2) , V=2211.9(5) 3, Z=8, F(000)=1512, μ =5\^349 mm -1 , R =0.0182 and wR =0.0385 for 1909 observed reflections with I>2σ(I) . The Sm 3+ is nine coordinated and the coordination polyhedron is a distorted, tricapped trigonal prism. The whole structure can be characterized as a two dimensional network.
The title complex was synthesized in an aqueous solution and its crystal structure was determined by Xray diffraction. The crystal crystallizes in a triclinic system, space group P1 with a= 1.306 3(2) nm , b=1....
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The title complex was synthesized in an aqueous solution and its crystal structure was determined by Xray diffraction. The crystal crystallizes in a triclinic system, space group P1 with a= 1.306 3(2) nm , b=1.319 4(4) nm, c=1.950 2(4) nm, α=90.597(14)°, β= 93.998(11)° , γ=94.093(13)°, V=3.344 1(12) nm3, Z=2, the final R indices are R 1= 0.065 4 , wR 2=0.126 2 respectively. The complex contains a novel tetranuclear cluster cation with four Er 3+ ions connected by four μ 3OH ions and six bridging carboxyl groups. Each erbium ion is coordinated by three μ 3OH, three carboxylic oxygen atoms from three αalanine and two oxygen atoms from water molecules, forming a squareantiprismatic coordination polyhedron.
The title complex was synthesized in an aqueous solution and its crystal structure was determined by Xray diffraction. The crystal crystallizes in a triclinic system, space group P1 with a= 1.306 3(2) nm , b=1....
详细信息
The title complex was synthesized in an aqueous solution and its crystal structure was determined by Xray diffraction. The crystal crystallizes in a triclinic system, space group P1 with a= 1.306 3(2) nm , b=1.319 4(4) nm, c=1.950 2(4) nm, α=90.597(14)°, β= 93.998(11)° , γ=94.093(13)°, V=3.344 1(12) nm3, Z=2, the final R indices are R 1= 0.065 4 , wR 2=0.126 2 respectively. The complex contains a novel tetranuclear cluster cation with four Er 3+ ions connected by four μ 3OH ions and six bridging carboxyl groups. Each erbium ion is coordinated by three μ 3OH, three carboxylic oxygen atoms from three αalanine and two oxygen atoms from water molecules, forming a squareantiprismatic coordination polyhedron.
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