Two cyano\|bridged complexes {\\-2\[Fe(CN)\-6\]}\-∞(L=NH\-2CH\-2CH\-2CH\-2OH(ampt)(1),NH\-2CH\-2CH(CH\-3)OH(amtt)(2)) and cyanobridged Ni\+Ⅱ\-6Fe\+Ⅱ cluster \[Fe(CN—Ni(tetren))\-6\](ClO\-4)\-8(tetren)(3) were synt...
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Two cyano\|bridged complexes {\\-2\[Fe(CN)\-6\]}\-∞(L=NH\-2CH\-2CH\-2CH\-2OH(ampt)(1),NH\-2CH\-2CH(CH\-3)OH(amtt)(2)) and cyanobridged Ni\+Ⅱ\-6Fe\+Ⅱ cluster \[Fe(CN—Ni(tetren))\-6\](ClO\-4)\-8(tetren)(3) were synthesized,and have been characterized by elemental analysis and IR *** experimental results show that the oxide state of Fe is changed from Fe\+Ⅲ to Fe\+Ⅱ after the synthesis *** magnetization versus T and magnetic susceptibility of (2) were measured and showed that the interaction between Cu\+Ⅱ ions separated by diamagnetic low spin Fe\+Ⅱ is weak antiferromagnetic.
Recent years, much effort has been devoted to the controllable synthesis of inorganic nanotubes since the discovery of carbon nanotubes (CNT) in 1991. Here, we report a facile synthesis of single crys
Recent years, much effort has been devoted to the controllable synthesis of inorganic nanotubes since the discovery of carbon nanotubes (CNT) in 1991. Here, we report a facile synthesis of single crys
Dicyanamide bridged complexes have achieved much attention due to their interesting polymeric topologies and magnetic properties. In this work, two isomeric complexes of Mn(II) and Cd(II) have been st
Dicyanamide bridged complexes have achieved much attention due to their interesting polymeric topologies and magnetic properties. In this work, two isomeric complexes of Mn(II) and Cd(II) have been st
It is well known that the associative magnetic properties of transition metal complexes in the solid state are influenced by the close metal?metal distances, by the presence of bridging atoms or pathw
It is well known that the associative magnetic properties of transition metal complexes in the solid state are influenced by the close metal?metal distances, by the presence of bridging atoms or pathw
Intramolecular charge-transfer (ICT) process has attracted great interest these years. The modification of acceptor unit in the D-A molecules, especially those constructed from TTF building blocks, ex
Intramolecular charge-transfer (ICT) process has attracted great interest these years. The modification of acceptor unit in the D-A molecules, especially those constructed from TTF building blocks, ex
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