在843 K LiCl-KCl-CeCl_3熔盐中活性铝电极上,研究了Ce(Ⅲ)离子的电化学行为和欠电位沉积Al-Ce合金。对比循环伏安曲线发现,在Al电极上Ce(Ⅲ)/Ce反应的氧化还原电势比在Mo惰性电极上更正;开路计时电位在金属铝和铈的沉积平台之间出现2...
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在843 K LiCl-KCl-CeCl_3熔盐中活性铝电极上,研究了Ce(Ⅲ)离子的电化学行为和欠电位沉积Al-Ce合金。对比循环伏安曲线发现,在Al电极上Ce(Ⅲ)/Ce反应的氧化还原电势比在Mo惰性电极上更正;开路计时电位在金属铝和铈的沉积平台之间出现2个平台,这表明Ce(Ⅲ)在A1活性电极上可以生成两种金属间化合物。以上结果在电化学机理上说明Ce(Ⅲ)离子可以在Al电极上欠电位沉积形成金属间化合物。在该实验条件下通过恒电位电解,在Al电极上得到了Al-Ce合金,验证了电化学分析的结果。经XRD表征,证实形成了AlCe和AlCe_3两种合金,结合Al-Ce合金相图分析了只产生这两种合金的原因;结合开路电位计算了生成这两种合金的标准吉布斯自由能变值。经SEM和EDS表征,证明了铈在Al电极表面分布,并形成厚度均一约28μm的Al-Ce合金镀层。
Cyclic voltammetry and chronopotentiometry were used to study the reaction mechanism of Pb（Ⅱ） and the co-deposition of Pb,Mg and Li on molybdenum electrodes in LiCl-KCl-PbCl2-MgCl2 *** diffusion coefficient of lead...
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Cyclic voltammetry and chronopotentiometry were used to study the reaction mechanism of Pb（Ⅱ） and the co-deposition of Pb,Mg and Li on molybdenum electrodes in LiCl-KCl-PbCl2-MgCl2 *** diffusion coefficient of lead ions in the melts was determined by different electrochemical *** results obtained by cyclic voltammetry and chronopotentiometry indicated that the underpotential deposition of lithium on pre-deposited Pb leads to the formation of a liquid Li-Pb alloy,and the Mg-Li-Pb alloys are formed after the addition of MgCl2.X-ray diffraction confirmed that in the Mg-Li-Pb alloy,PbLi3,Mg2Pb and Li7Pb2 phases exist by galvanostatic electrolysis at 6.21 A/cm2 for 2 h at 873 K and the phases can be controlled by changing the concentration of PbCl2 and MgCl2.
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