Recently,a one-pot self-assembly method was proposed for the synthesis of mesoporous Al2O3 and MOx-Al2O3 composite ***,few attempts have been made to use mesoporous MOx-Al2O3 composites to support metal oxides for ***...
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Recently,a one-pot self-assembly method was proposed for the synthesis of mesoporous Al2O3 and MOx-Al2O3 composite ***,few attempts have been made to use mesoporous MOx-Al2O3 composites to support metal oxides for *** the present work,mesoporous MOx-Al2O3(M = Mn,Fe,Co,Ni,Cu,Ba)materials were prepared by a one-pot self-assembly method using Pluronic P123 as a structure-directing *** obtained mesoporous materials were loaded with Rh2O3 nanoparticles via impregnation with Rh(NO3)3 followed by calcination in air at 500°*** resulting catalysts were characterized by X-ray diffraction,N2 adsorption-desorption measurements,transmission electron microscopy,inductively coupled plasma optical emission spectrometry,X-ray photoelectron spectroscopy,and their catalytic activity and stability for CO oxidation and N2O decomposition were *** Rh2O3 nanoparticles were found to be on the order of1 nm in size and were highly dispersed on the high surface area mesoporous MOx-Al2O3 supports.A number of the Rh2O3/mesoporous MOx-Al2O3 catalysts exhibited higher catalytic activity than the Rh2O3/mesoporous Al2O3 prepared for comparison.
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