Two EE azido-bridged coordination polymers (M(L)(N3)2, M = Co 1, Ni 2) were synthesized and characterized structurally and magnetically. 1 is a 1D Co-N3- chain presenting spin canting. 2 is a 2D (4,4)
Two EE azido-bridged coordination polymers (M(L)(N3)2, M = Co 1, Ni 2) were synthesized and characterized structurally and magnetically. 1 is a 1D Co-N3- chain presenting spin canting. 2 is a 2D (4,4)
Azide ion can link more than one metal ion in a variety of modes and mediate different types of magnetic coupling. Recently we reported a single End-to-End azide-bridged nickel (II) chain, which shows
Azide ion can link more than one metal ion in a variety of modes and mediate different types of magnetic coupling. Recently we reported a single End-to-End azide-bridged nickel (II) chain, which shows
To obtain low dimensional cyano-bridged complexes, [Cr(CN)4(L)]- (L = phen or 2,2’-bpy) was used as a building block reacted with a series of schiff base-complexes of Mn(III). Two chain complexes were
To obtain low dimensional cyano-bridged complexes, [Cr(CN)4(L)]- (L = phen or 2,2’-bpy) was used as a building block reacted with a series of schiff base-complexes of Mn(III). Two chain complexes were
Two new 3D NaCl type frameworks of [M(pyrazine)2NO2]ClO4 (M=Co, Cu) consist of (4, 4) sheets of M-pyrazine bridged by μ1,3-nitrito bridges, representing the first examples of a nitrite ion in μ1,3-bri
Two new 3D NaCl type frameworks of [M(pyrazine)2NO2]ClO4 (M=Co, Cu) consist of (4, 4) sheets of M-pyrazine bridged by μ1,3-nitrito bridges, representing the first examples of a nitrite ion in μ1,3-bri
As potential nitrogen-based ligands, the transition metal coordination chemistry and the ability to mediate magnetic coupling of cyanamide and its various forms (NCNH2, NCNH–, NCN2–] still remain unex
As potential nitrogen-based ligands, the transition metal coordination chemistry and the ability to mediate magnetic coupling of cyanamide and its various forms (NCNH2, NCNH–, NCN2–] still remain unex
Two new porous lanthanide fumarate frameworks were synthesized by hydrothermal reaction, showing framework dynamics and reversible luminescent properties upon dehydration and rehydration.
Two new porous lanthanide fumarate frameworks were synthesized by hydrothermal reaction, showing framework dynamics and reversible luminescent properties upon dehydration and rehydration.
Oxalate-bridged complexes have been a focus of magnetic studies due to the capability of the oxalate ligand to adopt bis-bidentate coordination modes to mediate magnetic coupling between paramagnetic
Oxalate-bridged complexes have been a focus of magnetic studies due to the capability of the oxalate ligand to adopt bis-bidentate coordination modes to mediate magnetic coupling between paramagnetic
Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 A series of MOFs containing two different functional cavities were synthes
Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 A series of MOFs containing two different functional cavities were synthes
Rare-earth oxysulfides M2O2S are known as wide gap (4.6-4.8 eV) semiconductors. They have been utilized as host materials for efficient luminescent use. Here we successfully synthesized monodisperse M
Rare-earth oxysulfides M2O2S are known as wide gap (4.6-4.8 eV) semiconductors. They have been utilized as host materials for efficient luminescent use. Here we successfully synthesized monodisperse M
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