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Investigation on Spark Plasma Sintering of Calcareous Waste Concrete Powder and Coal Fly Ash

Funtai Oyobi Fummatsu Yakin/Journal of the Japan Society of Powder and Powder Metallurgy 2023年第11期70卷 451-460页

作者： Kanda, Yasuyuki Shinjo, Tomohide Mechanical Engineering Program School of Engineering Faculty of Engineering University of the Ryukyus 1 Senbaru Nishihara-cho Okinawa Nakagami-gun903-0213 Japan Solid Mechanics and Materials Engineering Graduate School of Engineering and Science University of the Ryukyus 1 Senbaru Nishihara-cho Okinawa Nakagami-gun903-0213 Japan

This paper aims to fabricate a composite material using calcareous waste concrete powder and coal fly ash (FA) by spark plasma sintering. The effect of FA addition on the mechanical properties of the composite material were investigated. The maximum FA content was 7.5 wt%. The relative density of the composite material was approximately 1.0, independent of FA content. In contrast, the Vickers hardness, flexural strength, and flexural modulus increased with increasing FA content. However, the dispersion state of FA in the composite material was not observed by scanning electron microscopy. Powder X-ray diffraction of the composite material revealed that spurrite and wollastonite were formed identically, independent of FA content. Therefore, FA serves as a reinforcement in the composite material. © 2023 Japan Society of Powder and Powder Metallurgy.

关键词： Spark plasma sintering

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Block Sequence Effects on the Self-Assembly Behaviors of Polypeptide-Based Penta-Block Copolymer Hydrogels

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ACS Applied materials and Interfaces 2024年第5期16卷 6674-6686页

作者： Wang, Ke-Hsin Liu, Chung-Hao Tan, Dun-Heng Nieh, Mu-Ping Su, Wei-Fang Department of Materials Science and Engineering National Taiwan University No. 1 Sec. 4 Roosevelt Road Taipei10617 Taiwan Polymer program Institute of Materials Science University of Connecticut 25 King Hill Road Unit 3136 StorrsCT06269-3136 United States Department of Chemical and Biomolecular Engineering University of Connecticut StorrsCT06269 United States Department of Materials Engineering Ming-Chi University of Technology 84 Gungjuan Rd. New Taipei City243303 Taiwan

Peptide-based hydrogels have great potential for applications in tissue engineering, drug delivery, and so on. We systematically synthesize, characterize, and investigate the self-assembly behaviors of a series of polypeptide-based penta-block copolymers by varying block sequences and lengths. The copolymers contain hydrophobic blocks of poly(γ-benzyl-l-glutamate) (PBG, Bx) and two kinds of hydrophilic blocks, poly(l-lysine) (PLL, Ky) and poly(ethylene glycol) (PEG, EG34), where x and y are the number of repeating units of each block, where PBG and PLL blocks have unique functions for nerve regeneration and cell adhesion. It shows that a sufficient length of the middle hydrophilic segment capped with hydrophobic end PBG blocks is required. They first self-assemble into flower-like micelles and sequentially form transparent hydrogels (as low as 2.3 wt %) with increased polymer concentration. The hydrogels contain a microscale porous structure, a desired property for tissue engineering to facilitate the access of nutrient flow for cell growth and drug delivery systems with high efficiency of drug storage. We hypothesize that the structure of Bx-Ky-EG34-Ky-Bx agglomerates is beyond micron size (transparent), while that of Ky-Bx-EG34-Bx-Ky is on the submicron scale (opaque). We establish a working strategy to synthesize a polypeptide-based block copolymer with a wide window of sol-gel transition. The study offers insight into rational polypeptide hydrogel design with specific morphology, exploring the novel materials as potential candidates for neural tissue engineering. © 2024 The Authors. Published by American Chemical Society

关键词： Block copolymers

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Strengthening Mechanism of Cold-Rolled Co-Based Super Alloy for Diaphragm Valves under Room Temperature Tensile Loading

Journal of Korean Institute of Metals and Materials

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Journal of Korean Institute of Metals and materials 2025年第5期63卷 319-329页

作者： Park, Jung-Hyun Song, Noh-Geon Choi, Jae-Ho Kang, Doo-Hong Lee, Kee-Ahn Department of Materials Science and Engineering Inha University Incheon22212 Korea Republic of Program in Semiconductor Convergence Inha University Incheon22212 Korea Republic of CN-1 Corp. Hwaseong18487 Korea Republic of Asflow Corp Hwaseong18514 Korea Republic of

Cold-rolled Co-Cr-Ni alloy (Elgiloy) and Co-Ni-Cr alloy (SPRON 51.) can be considered for diaphragm valve materials in gas valve systems. In this study, the effect of direct aging (DA) heat treatment on the tensile properties of Co-based alloys was investigated and the influence of microstructural changes on the tensile behavior was examined. The Co-Cr-Ni Elgiloy alloy exhibited a hexagonal close packed (HCP) phase formation through strain induced martensite transformation (SIMT) in both as-rolled and DA conditions, promoting finer grains due to increased sub-structured and recrystallized grains. In contrast, the Co-Ni-Cr SPRON 51. alloy showed a face centered cubic (FCC) single phase with a higher precipitates fraction and dislocation density. Both Co-based alloys showed improved hardness and strength after DA treatment, with the Co-Cr-Ni alloy demonstrating higher tensile strength and the Co-Ni-Cr alloy exhibiting higher yield strength and elongation. The Co-Cr-Ni alloy revealed fine shallow dimples and cleavage fracture mode, while Co-Ni-Cr showed larger dimples and river patterns on tensile fracture surfaces. The Co-Cr-Ni alloy’s deformation behavior was dominated by active SIMT due to low stacking fault energy (SFE), while the Co-Ni-Cr alloy primarily formed deformation twins due to higher SFE. The high tensile strength of the Co-Cr-Ni alloy was dominated by hardening effects due to a relatively fine grain size and SIMT behavior, while the high yield strength of the Co-Ni-Cr alloy was dominated by deformation twin, dislocation density, Taylor factor and high precipitate fraction. Copyright © The Korean Institute of Metals and materials.

关键词： Tensile strength

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Nanoparticles-based phototherapy systems for cancer treatment: Current status and clinical potential

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Bioactive materials 2023年第5期23卷 471-507页

作者： Jiachen Li Shiqi Wang Flavia Fontana Christos Tapeinos Mohammad-Ali Shahbazi Huijie Han Helder A.Santos Department of Biomedical Engineering W.J.Kolff Institute for Biomedical Engineering and Materials ScienceUniversity Medical Center GroningenUniversity of GroningenAnt.Deusinglaan 1Groningen9713 AVthe Netherlands W.J.Kolff Institute for Biomedical Engineering and Materials Science University Medical Center GroningenUniversity of GroningenUniversity of GroningenAntonius Deusinglaan 19713 AVGroningenthe Netherlands Drug Research Program Division of Pharmaceutical Chemistry and Technology Faculty of PharmacyUniversity of HelsinkiHelsinkiFI-00014Finland

Remarkable progress in phototherapy has been made in recent decades,due to its non-invasiveness and instant therapeutic *** addition,with the rapid development of nanoscience and nanotechnology,phototherapy systems based on nanoparticles or nanocomposites also evolved as an emerging hotspot in nanomedicine research,especially in *** this review,first we briefly introduce the history of phototherapy,and the mechanisms of phototherapy in cancer ***,we summarize the representative development over the past three to five years in nanoparticle-based phototherapy and highlight the design of the innovative nanoparticles ***,we discuss the feasibility and the potential of the nanoparticle-based phototherapy systems in clinical anticancer therapeutic applications,aiming to predict future research directions in this *** review is a tutorial work,aiming at providing useful insights to researchers in the field of nanotechnology,nanoscience and cancer.

关键词： Phototherapy Cancer Nanoparticles Therapeutic effect Clinical potential

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Development of Injection Moulded Electromagnetic Pulse Shielded Polymer Cover 7

Development of Injection Moulded Electromagnetic Pulse Shiel...

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7th International Conference on Material Strength and Applied Mechanics, MSAM 2024

作者： Dogossy, Gábor Ronkay, Ferenc Széchenyi István University Department of Materials Science and Engineering Egyetem tér 1. GyorH-9026 Hungary John von Neumann University Department of Innovative Vehicles and Materials Izsáki út 10. KecskemétH-6000 Hungary

ISBN: (纸本)9781643685472

Technology for an electromagnetic pulse shielded injection moulded product was developed, using in-mould metal mesh and a 3D printed spacer made of the same type of acrylonitrile-butadiene-styrene as the injection moulded polymer. The functional and mechanical properties of the manufactured flat and dumbbel specimens were tested. The metal mesh increased the stiffness of the plastic, decreased its Charpy impact strength, and did not significantly affect its tensile strength. Computed tomography scans confirmed that delamination and microcracking occur during the failure due to different elongation of the plastic and metal. The attenuation at 1.GHz was 1.-1. dB, depending on the metal mesh used. The shielding properties were affected by the fact that the high pressure at the mould filling during the injection moulding process distorted the geometry of the metal mesh. © The Author(s), 2024.

关键词： Tensile strength

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Esterification of free fatty acids in waste cooking oil by heterogeneous catalysts

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Transactions of Tianjin University 2025年第4期20卷 266-272页

作者： Liyan Liu Zhimin Liu Guowu Tang Wei Tan 1. School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China2. College of Chemistry Chemical Engineering and Materials Science Shandong Normal University Jinan 250014 China

Waste cooking oil (WCO) is becoming the most promising alternative feedstock to produce biodiesel due to its low cost in China. In this study, NKC-9 ion-exchange resin and H-beta zeolite were selected as heterogeneous catalysts in the WCO esterification process and their esterification characteristics were compared by orthogonal experiments. NKC-9 resin showed higher activity and achieved a higher final conversion compared with H-beta zeolite under the same reaction conditions. Reusability experiments showed that NKC-9 resin still exhibited high activity after 5 runs. The effects of the mole ratio of alcohol to oil, reaction time, reaction temperature and the catalyst dose were investigated by multifactor orthogonal analysis. The influence of the free fatty acid (FFA) content was also investigated, and the result showed that the esterification rate could be as high as 98.4% when the FFA content was 6.3wt%.

关键词： biodiesel waste cooking oil heterogeneous catalyst esterification

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Characterizing catalyst function and transformations in the plasma reduction of CO₂ on atomic layer deposition-synthesized catalysts

RSC Applied Interfaces

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RSC Applied Interfaces 2024年第3期1卷 552-563页

作者： Conlin, Samuel K. Mehrabi, Hamed Parette, David N. Nichols, Eva M. Coridan, Robert H. Department of Chemistry and Biochemistry University of Arkansas Fayetteville 72701 AR United States Materials Science and Engineering Program University of Arkansas Fayetteville 72701 AR United States Department of Chemistry University of British Columbia Vancouver V6T 1Z1 BC Canada

The enhancement of CO2 reduction in atmospheric-pressure, non-thermal plasma has been shown using a variety of catalyst systems with ranging composition, particle sizes, and morphologies. Improvements in CO2 conversio...

The enhancement of CO₂ reduction in atmospheric-pressure, non-thermal plasma has been shown using a variety of catalyst systems with ranging composition, particle sizes, and morphologies. Improvements in CO₂ conversion can be attained by choice of catalyst material. However, inhomogeneity in the material distribution arising from the synthesis affects the catalytically active surface area and dielectric environment that modulates the plasma properties near the catalyst. Atomic layer deposition (ALD) can be used to control the composition of ultra-thin layers on support materials. We used ALD to synthesize metal oxide catalyst coatings on high surface area supports. We found that TiO₂ achieved significantly higher yields of CO₂ conversion (to CO and O₂) at low reactor power compared to ZnO or Al₂O₃, materials commonly used as a support for other catalysts. We also observed an unexpected increase in the catalytic activity on ZnO with increasing power. The results here suggest that ALD can unambiguously isolate the catalytic effects of materials in plasma reactors. © 2024 RSC.

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Anomalous properties of spark plasma sintered boron nitride solids

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materials Today 2025年 86卷 42-51页

作者： Biswas, Abhijit Serles, Peter Alvarez, Gustavo A. Schimpf, Jesse Hache, Michel Kong, Jonathan Demingos, Pedro Guerra Yuan, Bo Pieshkov, Tymofii S. Li, Chenxi Puthirath, Anand B. Gao, Bin Gray, Tia Zhang, Xiang Murukeshan, Jishnu Vajtai, Robert Dai, Pengcheng Singh, Chandra Veer Howe, Jane Zou, Yu Martin, Lane W. Clancy, James Patrick Tian, Zhiting Filleter, Tobin Ajayan, Pulickel M. Department of Materials Science and Nanoengineering Rice University HoustonTX77005 United States Department of Mechanical & Industrial Engineering University of Toronto 5 King's College Road TorontoM5S 3G8 Canada Sibley School of Mechanical and Aerospace Engineering Cornell University IthacaNY14853 United States Department of Materials Science and Engineering University of California Berkeley94720 United States Department of Materials Science and Engineering University of Toronto 184 College St TorontoM5S 3E4 Canada Department of Physics and Astronomy McMaster University HamiltonL8S 4M1 Canada Applied Physics Graduate Program Smalley-Curl Institute Rice University HoustonTX77005 United States Department of Physics and Astronomy Rice University HoustonTX77005 United States Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley94720 United States

Hexagonal boron nitride (h-BN) is a brittle ceramic with a layered structure, however, recent experiments have suggested that inter-layer structural engineering could be key to new structural and functional properties. Here we report the scalable bulk synthesis of high-density crystalline h-BN solids, by using high-temperature spark plasma sintering (SPS) of h-BN powders, which show high values of mechanical strength, ductility, dielectric constant, thermal conductivity, and exceptional neutron radiation shielding capability. Through exhaustive characterizations we reveal that SPS induces non-basal plane crystallinity, twisting of layers, and facilitates inter-grain fusion with a high degree of in-plane alignment across macroscale dimensions, resulting in near-theoretical density and improved properties. Our findings highlight the importance of material design, via new approaches such as layer twisting and interlayer interconnections, to create novel ceramics with properties that could go beyond their intrinsic limits. © 2025

关键词： Ductility

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Corrosion behavior of Mg-Zn-Zr-RE alloys under physiological environment-Impact on mechanical integrity and biocompatibility

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Journal of Magnesium and Alloys 2022年第6期10卷 1542-1572页

作者： Marwa AbdelGawad Chaudhry A.Usman Vasanth C.Shunmugasamy Ibrahim Karaman Bilal Mansoor Mechanical Engineering Program Texas A&M University at QatarEducation CityDoh1Qatar Department of Mechanical Engineering Texas A&M University3123 TAMUCollege StationTX 77843United States of America Department of Materials Science and Engineering Texas A&M University3003 TAMUCollege StationTX 77843United States of America

Benefits of RE addition on Mg alloys strength and corrosion resistance are widely reported but their effects on biodegradability and biocompatibility are still of *** paper investigates the effect of RE additions on biodegradability of Mg-Zn alloys under simulated physiological *** this context,two commercial Mg-Zn-Zr-RE alloys,namely ZE41.and EZ33,with same RE addition but different concentrations are studied in Hank’s Balanced Salt Solution(HBSS)at 37℃and with pH of ***-loss,hydrogen evolution,real-time insitu drop test,electrochemical impedance spectroscopy(EIS)and potentiodynamic polarization are deployed to study corrosion *** mechanical integrity of both alloys is assessed by mechanical testing post ***,in vitro biocompatibility is evaluated by indirect cytotoxicity tests using NIH3T3 *** reveal that although both alloys showed similar microstructure,size and distribution of precipitates played a significant role on its corrosion *** and open circuit potential results show stable film formation on EZ33,while ZE41.showed passive layer formation followed by its deterioration,over the analyzed time *** real-time drop test,it was shown in ZE41.alloy that both T-phase and Zr-rich precipitates acted as micro cathodes,resulting in an unstable surface *** EZ33,Zr-rich regions did not influence corrosion response,resulting in better corrosion resistance that was corroborated by post-immersion surface morphology *** higher degradation observed in ZE41.alloy resulted in higher drop in flexural and tensile strength compared to EZ33 *** addition,cytotoxicity tests on NIH3T3 cells revealed that cell viability of EZ33 increased with increasing incubation time,contrary to ZE41.owing to its lower biodegradation behavior and despite higher concentrations of *** results show that an increase in RE concentration in EZ33,relative to ZE41.had a positive effect on

关键词： Magnesium alloy Corrosion EIS Mechanical integrity Cytotoxicity

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Biomass-Based Discrete Furan Oligomers as materials for Electrochromic Devices

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ACS Sustainable Chemistry and engineering 2024年第1期12卷 459-469页

作者： Atayde, Eduardo C. Fong, Guan-Lun Yeh, Jyun-Yi Matsagar, Babasaheb M. Wang, Yu-Cheng Chen, De-Chian Peng, Chi-How Li, Yi-Pei Yamauchi, Yusuke Ho, Kuo-Chuan Wu, Kevin C.-W. Molecular Science and Technology Program Taiwan International Graduate Program (TIGP-MST) Academia Sinica No. 128 Sec. 2 Academia Road Taipei 11529 Taiwan Department of Chemistry National Tsing Hua University No. 101 Sec. 2 Kuang-Fu Road Hsinchu 30013 Taiwan Department of Chemical Engineering National Taiwan University No. 1 Sec. 4 Roosevelt Road Taipei 10617 Taiwan Sustainable Chemical Science and Technology Program Taiwan International Graduate Program (TIGP-SCST) Academia Sinica No. 128 Sec. 2 Academia Road Taipei 11529 Taiwan School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology (AIBN) The University of Queensl Brisbane 4072 QLD Australia Department of Materials Process Engineering Graduate School of Engineering Nagoya University Nagoya 464-8603 Japan Institute of Polymer Science and Engineering National Taiwan University No.1 Sec. 4 Roosevelt Rd. Taipei 10617 Taiwan Department of Chemical Engineering and Materials Science Yuan Ze University No. 135 Yuandong Rd. Taoyuan 320 Taiwan

Electrochromic devices (ECDs) are materials that can undergo reversible changes in transmittance when exposed to different applied potentials. While many conjugated heterocyclic oligomers, such as oligothiophenes, have been developed for this purpose, there is no reported study on the use of discrete oligomeric furans as ECD materials. In this work, we introduce a furan trimer that can be utilized as a discrete electrochromic material, which transitions from light yellow to red and has a very high coloration efficiency of 1.40 cm²/C at 507 nm. We propose that the reversible π-stack formation of the oligomer radical cations is behind this phenomenon, as evidenced by both experimental and computational results. The derivability of this oligomer from biomass and its facile synthesis make it an interesting alternative for other existing organic electrochromic materials. © 2023 American Chemical Society

关键词： electrochromism furan oligomer hydroxyalkylation−alkylation reaction solvatochromism π-stacks

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