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Surface tension of single suspended aerosol microdroplets

Chinese Chemical Letters 2024年第4期35卷 520-524页

作者： Yukai Tong Zhijun Wu Bo Zhou Min Hu Anpei Ye Key Laboratory for the Physics and Chemistry of Nanodevices School of ElectronicsPeking UniversityBeijing 100871China State Key Joint Laboratory of Environmental Simulation and Pollution Control College of Environmental Sciences and EngineeringPeking UniversityBeijing 100871China Aerospace Information Research Institute Chinese Academy of SciencesBeijing 100094China

The surface tension of troposphere aerosols can significantly influence their atmospheric processes and key properties, particularly on the morphology, the phase transition, the activation as cloud condensation nuclei, and the gas-particle partitioning. However, directly measuring the surface tension of single ambient aerosol is quite challenging, due to the limitations of their picolitre volumes and thermal motion. Here, we developed a dual laser tweezers Raman spectroscopy(DLT-RS) system to directly sense the surface tension of single airborne microdroplets(PM1.particles). A pair of aerosol droplets were trapped and driven to coalesce by the laser tweezers. Meanwhile, the backscattering light intensity and brightfield images during the coalescence process were recorded to characterize the aerosol surface tension. A remarkable advantage of directly sensing aerosol surface tension is that the solutes in aerosols are often supersaturated, which is common in atmospheric aerosols but almost unavailable in bulk *** experimentally measured the surface tension of aerosols composed of nitrates or oxalic acid/nitrate mixture. Besides, the variation of surface tension during aerosol aging process was also explored, which brings possible implications on the surface evolution of actual ambient aerosol during their atmospheric lifetime.

关键词： Surface tension Droplet coalescence Single aerosol Laser tweezers Aerosol aging

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A review of gas-phase chemical mechanisms commonly used in atmospheric chemistry modelling

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Journal of environmental Sciences 2023年第1期123卷 522-534页

作者： Yanhui Liu Jiayin Li Yufang Ma Ming Zhou Zhaofeng Tan Limin Zeng Keding Lu Yuanhang Zhang State Key Joint Laboratory of Environmental Simulation and Pollution Control College of Environmental Science and EngineeringPeking UniversityBeijing 100871China Institute of Energy and Climate Research IEK-8:TroposphereForschungszentrum Jülich GmbHJülich 52428Germany

The atmospheric chemical mechanism is an essential component of airshed models used for investigating the chemical behaviors and impacts of *** the first tropospheric chemical mechanism was proposed in the 1.60s,various mechanisms including Master Chemical Mechanism(MCM),Carbon Bond Mechanism(CBM),statewide Air {1. Research Center(SAPRC)and Regional Atmospheric Chemistry Mechanism(RACM)have been developed for different research *** work summarizes the development and applications of these mechanisms,introduces their compositions and lumping methods,and compares the ways the mechanisms treat radicals with box model *** can reproduce urban {1. events with relatively low cost compared to SAPRC and RACM,whereas the chemical behaviors of radicals and the photochemical production of ozone are described in detail in *** photolysis rates of some oxygenated compounds are low in SAPRC07,which may result in underestimation of radical *** an explicit chemical mechanism,MCM describes the chemical processes of primary pollutants and their oxidation products in *** can be used to investigate certain chemical processes;however,due to its large size,it is rarely used in regional model simulations.A box model case study showed that the chemical behavior of OH and HO_(2)radicals and the production of ozone were well described by all *** and SAPRC underestimated the radical levels for different chemical treatments,leading to low ozone production values in both *** and RACM are widely used in box model studies,while CBM and SAPRC are often selected in regional simulations.

关键词： Atmospheric chemistry Gas-phase chemical mechanism Ozone Box model

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Advanced modeling of the absorption enhancement of black carbon particles in chamber experiments by considering the morphology and coating thickness

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Frontiers of environmental Science & Engineering 2024年第9期18卷 129-142页

作者： Xiaodong Wei Jianlin Hu Chao Liu Xiaodong Xie Junjie Yin Song Guo Min Hu Jianfei Peng Huijun Wang Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologySchool of Environmental Science and EngineeringNanjing University of Information Science&TechnologyNanjing 210044China Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters Key Laboratory of Meteorological Disaster(Ministry of Education)Nanjing University of Information Science and TechnologyNanjing 210044China Nansen−Zhu International Research Centre Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China East China Air Traffic Management Bureau CAAC Shanghai 200335China State Key Joint Laboratory of Environmental Simulation and Pollution Control International Joint Laboratory for Regional Pollution Control(IJRC)(Ministry of Education)College of Environmental Sciences and EngineeringPeking UniversityBeijing 100871China Tianjin Key Laboratory of Urban Transport Emission Research&State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control College of Environmental Science and EngineeringNankai UniversityTianjin 300071China

Measurements studies have shown that the absorption of radiation by black carbon(BC)increases as the particles ***,there are significant discrepancies between the measured and modeled absorption enhancement(E_(abs)),largely due to the simplifications used in modeling the mixing states and shape *** took advantage of chamber experiments on BC aging and developed an efficient method to resolve the particle shape based on the relationship between the coating fraction(ΔD_(ve)/D_(ve),0)and fractal dimension(D_(f)),which can also reflect the variations of D_(f)during the whole BC aging *** with externally and partly mixed states(0≤ΔD_(ve)/D_(ve),0≤0.5)can be considered to be uniformly distributed with the D_(f)values of 1.8–2.1.whereas the Df values are constrained in the range 2.2–2.8 for fully mixed states(ΔD_(ve)/D_(ve),0>0.5).The morphological parameters(i.e.,the effective density and the dynamic shape factor)were compared with the measured values to verify the simulated *** simulated mean deviations of morphological parameters were smaller than 8%for the method resolving the particle *** applying a realistic shape and refractive index,the mass absorption cross for fully mixed states can be improved by 1.%compared with a simplified core–shell *** on our understanding of the influence of D_(f)andΔD_(ve)/D_(ve),0 on E_(abs),we propose a two-stage calibration equation to correct the E_(abs)values estimated by the core–shell model,which reduces the simulation error in the Mie calculation by 6%–1.%.

关键词： Black carbon Mixing states Fractal dimension Dynamic shape factor Absorption enhancement

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Performance comparison of lithium fractionation from magnesium via continuous selective nanofiltration/electrodialysis

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Chinese Journal of Chemical Engineering 2023年第7期59卷 42-50页

作者： Yong Xu Qingbai Chen Yang Gao Jianyou Wang Huiqing Fan Fei Zhao Tianjin Key Laboratory of Environmental Technology for Complex Trans-Media Pollution College of Environmental Science and EngineeringNankai UniversityTianjin 300350China College of Chemical Engineering and Material Quanzhou Normal UniversityQuanzhou 362000China Center for Water and Ecology State Key Joint Laboratory of Environment Simulation and Pollution ControlSchool of EnvironmentTsinghua UniversityBeijing 100084China

Although selective nanofiltration(SNF)and selective electrodialysis(SED)have been widely adopted in the field of Mg^(2+)/Li^(+)separation,their differences have not been illustrated *** this study,for the first time,SNF and SED processes in continuous mode were studied for Li+fractionation from the same brine with high Mg/Li ratios and their differences were discussed in *** a fair analysis of the two processes,typical factors were ***,the optimal operating pressure and feed flow rate for SNF were 2.4 MPa and 1.0 L·h^(-1.,respectively,while the optimal cell-pair voltage and replenishment flow rate for SED were 1.0 V and 1. L·h^(-1.,*** the Li^(+)fractionation capacity of the two processes were similar,the selectivity coefficient of SNF was 24.7% higher than that of SED and,thus,the Mg/Li ratio in purified stream of the former was 1..0% lower than that of the *** to higher ion driving force,SED had clear advantages in recovery ratio and concentration ***,the specific energy consumption of SED was 20.1. lower than that of *** study provided a better understanding and guidance for the application and improvement of the two technologies.

关键词： High Mg/Li brine Purification Membrane Nanofiltration Electrodialysis Lithium recovery

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Seasonal changes of chemodiversity along with microbial succession in a municipal wastewater treatment plant

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Journal of environmental Sciences 2025年第4期150卷 318-331页

作者： Yunwei Cui Junya Zhang Luoyao Wen Jibao Liu Zhineng Hao Chunzhong Wei Yanbo Jiang Yuansong Wei Peihong Shen College of Life Science and Technology Guangxi UniversityNanning 530005China State Key Joint Laboratory of Environmental Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China State Key Laboratory of Environmental Chemistry and Ecotoxicology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Guangxi Beitou Environmental Protection&Water Group Co. LTD.Nanning 530025China

The relationship between chemodiversity and microbial succession in wastewater treatment plants(WWTPs)is highly intricate and *** specific contribution of the microbial community to changes in the composition of dissolved organic matter(DOM)within different biological treatment units remains unclear,as does the reciprocal influence of DOM composition on microbial *** this study,spectroscopy((Excitationemission matrix)EEM-PARAFAC,Ultraviolet(UV)-spectrum,Fourier transform infrared spectrometer(FT-IR)),Liquid chromatograph mass spectrometer(LC–MS)and Fourier transform ion cyclotron resonance(FT-ICR)MS along with high-throughput sequencing technology were used to explore the relationship between chemodiversity and microbial succession in WWTPs concerning seasonal *** results showed that WWTPs with anaerobic/anoxic/oxic(A2O)processes can metabolize and transformmost of thewastewater DOM,and the anaerobic unit has the highest removal rate for fluorescence DOM(FDOM,1..07%-64.43%);the anaerobic unit increased aliphatic/proteins and lignin-like molecules but decreased relative intensity,while the anoxic unit removed unsaturated hydrocarbons,aromatic structures,and lignin-like *** impact of seasonal changes on the composition and removal of FDOM and DOM in wastewater treatment is significant,and the variations that occur during different seasons affect microbial activity,as well as the production,degradation,and transformation of organic compounds throughout thewastewater treatment *** analysis shows that Parcubacteria_genera_incertae_sedis plays a crucial role in DOM chemodiversity,highlighting the crucial contribution of microbial com-munities to both the structure and operation of the entire DOM *** results in this study could provide some theoretical and practical basis for guiding the process optimiza-tion of WWTPs.

关键词： Wastewater treatment plant Dissolved organic matter Fourier transform ion cyclotron resonance mass spectrometry Chemodiversity Microbial community

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Superhydrophobic ceramic membrane coupled with a biphasic solvent for efficient CO_(2)capture

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Green Energy & Environment 2025年第4期10卷 834-844页

作者： Kaili Xue Zhen Chen Xiaona Wu Heng Zhang Haiping Chen Junhua Li State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing100084China Beijing Key Laboratory of Pollutant Monitoring and Control in Thermoelectric Production Process School of EnergyPower and Mechanical EngineeringNorth China Electric Power UniversityBeijing102206China MOE Key Laboratory of Resources and Environmental Systems Optimization College of Environmental Science and EngineeringNorth China Electric Power UniversityBeijing102206China

An innovative strategy was proposed by integration of membrane contactor(MC)with biphasic solvent for efficient CO_(2) capture from flue *** accessible fly ash-based ceramic membrane(CM)underwent hydrophobic modification through silane grafting,followed by fluoroalkylsilane decoration,to prepare the superhydrophobic membrane(CSCM).The CSCM significantly improved resistance to wetting by the biphasic solvent,consisting of amine(DETA)and sulfolane(TMS).Morphological characterizations and chemical analysis revealed the notable enhancements in pore structure and hydrophobic chemical groups for the modified *** of wetting/bubbling behavior based on static wetting theory referred the liquid entry pressure(LEP)of CSCM increased by 20 kPa compared to pristine *** with traditional amine solvents,the biphasic solvent presented the expected phase *** experiments demonstrated that the CO_(2) capture efficiency of the biphasic solvent increased by 7%,and the electrical energy required for desorption decreased by 32%.The 60-h continuous testing and supplemental characterization of used membrane confirmed the excellent adaptability and durability of the *** study provides a potential approach for accessing hydrophobic ceramic membranes and biphasic solvents for industrial CO_(2) capture.

关键词： Carbon capture Membrane contactor Hydrophobic modification Membrane wetting Biphasic solvent

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Effects of impregnation sequence on the NH_(3)-SCR activity and hydrothermal stability of a Ce-Nb/SnO_(2) catalyst

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Journal of environmental Sciences 2024年第4期138卷 450-457页

作者： Ying Zhu Wenpo Shan Zhihua Lian Jingjing Liu Yan Zhang Hong He Center for Excellence in Regional Atmospheric Environment and Key Laboratory of Urban Pollutant Conversion Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Zhejiang Key Laboratory of Urban Environmental Processes and Pollution Control Ningbo Urban Environment Observation and Research StationInstitute of Urban EnvironmentChinese Academy of SciencesNingbo 315800China State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China

Hydrothermal stability is crucial for the practical application of deNO_(x)catalyst on diesel vehicles,for the selective catalytic reduction of NO_(x)with NH_(3)(NH_(3)-SCR).SnO_(2)-based materials possess superior hydrothermal stability,which is attractive for the development of NH_(3)-SCR *** this work,a series of Ce-Nb/SnO_(2)catalysts,with Ce and Nb loading on SnO_(2)support,were prepared by impregnation *** was found that,the NH_(3)-SCR activities and hydrothermal stabilities of the Ce-Nb/SnO_(2)catalysts significantly varied with the impregnation sequences,and the Ce-Nb(f)/SnO_(2) catalyst that firstly impregnated Nb and then impregnated Ce exhibited the best *** characterization results revealed that CeNb(f)/SnO_(2)possessed appropriate acidity and redox ***,the strong synergistic effect between Nb and Sn species stabilized the structure and maintained the dispersion of acid *** study may provide a new understanding for the effect of impregnation sequence on activity and hydrothermal stability and a new environmental-friendly NH_(3)-SCR catalyst with potential applications for NO_(x)removal from diesel and hydrogenfueled engines.

关键词： NO_(x)emission control NH_(3)-SCR Hydrothermal stability Ce-Nb/SnO_(2)catalyst Impregnation sequence

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Enhancing oxidation reaction over Pt-MnO_(2) catalyst by activation of surface oxygen

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Journal of environmental Sciences 2023年第12期134卷 117-125页

作者： Ruoting Shan Zhenteng Sheng Shuo Hu Hongfei Xiao Yuhua Zhang Jianghao Zhang Li Wang Changbin Zhang Jinlin Li Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education&Hubei Key Laboratory of Catalysis and Materials Science South-Central Minzu UniversityWuhan 430074China State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-environmental SciencesChinese Academy of SciencesBeijing 100085China

Formaldehyde(HCHO) and carbon monoxide(CO) are both common air pollutants and hazardous to human body. It is imperative to develop the catalyst that is able to efficiently remove these pollutants. In this work, we activated Pt-MnO_(2)under different conditions for highly active oxidation of HCHO and CO, and the catalyst activated under CO displayed superior performance. A suite of complementary characterizations revealed that the catalyst activated with CO created the highly dispersed Pt nanoparticles to maintain a more positively charged state of Pt, which appropriately weakens the Mn-O bonding strength in the adjacent region of Pt for efficient supply of active oxygen during the reaction. Compared with other catalysts activated under different conditions, the CO-activated Pt-MnO_(2)displays much higher activity for oxidation of HCHO and CO. This research contributes to elucidating the mechanism for regulating the oxidation activity of Pt-based catalyst.

关键词： Pt/MnO_(2)catalysts HCHO abatement CO abatement Catalytic oxidation Activation of surface oxygen

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Occurrence and Decay of SARS-CoV-2 in Community Sewage Drainage Systems

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Engineering 2023年第7期26卷 214-219,I0008,I0009页

作者： Qian Dong 蔡俊雄刘艳臣凌海波 Qi Wang Luo-Jing Xiang Shao-Lin Yang Zheng-Sheng Lu Yi Liu Xia Huang 曲久辉 State Key Joint Laboratory of Environment Simulation and Pollution Control School of EnvironmentTsinghua UniversityBeijing 100084China Hubei Provincial Academy of Eco-Environmental Sciences Wuhan 430072China Key Laboratory of Drinking Water Science and Technology Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China

The rapid spread of the coronavirus disease(COVID-1.)pandemic in over 200 countries poses a substantial threat to human *** acute respiratory syndrome coronavirus 2(SARS-CoV-2),which causes COVID-1.,can be discharged with feces into the drainage ***,a comprehensive understanding of the occurrence,presence,and potential transmission of SARS-CoV-2 in sewers,especially in community sewers,is still *** study investigated the virus occurrence by viral nucleic acid testing in vent stacks,septic tanks,and the main sewer outlets of community where confirmed patients had lived during the early days of the epidemic in Wuhan,*** results indicated that the risk of long-term emission of SARS-CoV-2 to the environment via vent stacks of buildings was low after confirmed patients were ***-CoV-2 were mainly detected in the liquid phase,as opposed to being detected in aerosols,and its RNA in the sewage of septic tanks could be detected for only four days after confirmed patients were *** surveillance of SARS-CoV-2 in sewage could be a sensitive indicator for the possible presence of asymptomatic patients in the community,though the viral concentration could be diluted more than ten times,depending on the sampling site,as indicated by the Escherichia coli *** comprehensive investigation of the community sewage drainage system is helpful to understand the occurrence characteristics of SARS-CoV-2 in sewage after excretion with feces and the feasibility of sewage surveillance for COVID-1. pandemic monitoring.

关键词： SARS-CoV-2 Transmission risk Drainage system Sewage Community

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Assessing the effectiveness and mechanisms of Fe/PS,Fe/H2O2,and O3 treatment for water disinfection:Spotlight on VBNC bacteria

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环境科学学报（英文版） 2025年第6期152卷 389-400页

作者： Zheng Qi Zaihui Huang Chunguang Liu School of Environmental Science and Engineering Laboratory of Marine Ecological Environment in Universities of ShandongShandong UniversityQingdao 266237China Environmental Simulation and Pollution Control State Key Joint Laboratory School of EnvironmentTsinghua UniversityBeijing 100084China School of Environmental Science and Engineering Laboratory of Marine Ecological Environment in Universities of ShandongShandong UniversityQingdao 266237China School of Environmental Science and Engineering Laboratory of Marine Ecological Environment in Universities of ShandongShandong UniversityQingdao 266237China Qingdao Key Laboratory of Marine Pollutant Prevention Shandong Key Laboratory of Environmental Processes and HealthShandong UniversityQingdao 266237China

Advanced oxidation processes(AOPs)exhibit significant potential for water disinfection due to their generation of large quantities of highly oxidizing free ***,the neglect of viable but nonculturable(VBNC)cells obscures their true disinfection efficacy and poten-tial environmental health ***,the study evaluated the disinfection effective-ness and mechanisms of typical AOPs,including Fe/H2O2,Fe/persulfate(PS),and O3,from the perspective of the production of VBNC *** results indicate that Fe/PS exhibits the strongest bacterial inactivation rate(99.94％),and the cells lose their ability to ***/H2O2 and O3 induce more cells to enter the VBNC {1. compared to Fe/***-over,different AOPs result in varying levels of free radical production and utilization effi-ciency,with SO4·-and O3 exhibiting greater selectivity in deactivating bacteria compared to HO·.The inhibition of VBNC bacteria production by Fe/PS treatment may be attributed to the combined action of HO·and SO4·-on microorganisms,leading to oxidative stress and metabolic disruption in bacteria through the inhibition of biofilm formation and aminoacyl-tRNA biosynthesis(p＜0.05),thereby causing direct bacterial death rather than entry into the VBNC *** contrast,Fe/H2O2 and O3 result in the upregulation of the metabolism of alanine,aspartate,and glutamate,as well as styrene degradation capacity by the bacte-ria,leading to the production of more VBNC ***,the study offers insights into mitigating potential biological risks in water disinfection and developing environmentally friendly and efficient disinfection technologies.

关键词： Advanced oxidation processes Disinfection Oxidative stress Reactive oxygen species Viable but nonculturable cells

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