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Experimental study on CCl_4/CH)4/O_2/N_2 oxidation

Science China(Technological Sciences) 2010年第4期53卷 1016-1022页

作者： WANG Bo1.2,CHI Yong2,YAN JianHua2 & NI MingJiang2 1.College of Energy and power {1.,University of Shanghai for Science and Technology,Shanghai 200093,China 2 state key laboratory of Clean Energy Utilization,Zhejiang University,Hangzhou 31.027,China 1. College of Energy and Power Engineering University of Shanghai for Science and Technology Shanghai 200093 China2. State Key Laboratory of Clean Energy Utilization Zhejiang University Hangzhou 310027 China

Oxidation within the system CCl4/CH4/O2/N2 is studied at atmospheric pressure in a tubular flow reactor to investigate the influence of reaction temperature and chlorine content on chlorinated waste combustion and find incineration process optimization methods for pollution *** reaction temperature varies from 700℃ to 1.00℃ and the CCl4/CH4(or Cl/H) mole ratio of the inlet mixture varies from 0.21.to *** profiles are measured with *** is shown that at the same initial CCl4 concentration and reaction temperature adding CH4 favors CCl4 destruction and CO2 *** the destruction and removal efficiency(DRE) of CH4 decreases with lower Cl/H and higher concentrations of toxic products of incomplete combustion such as COCl2 and CH3Cl are formed at the same *** chlorine in the system favors CH4 decomposition,but it also inhibits further oxidation of *** temperature assists in both CCl4 destruction and CH4 conversion,and the concentration of toxic combustion intermediates is *** the temperature is the most effective way to enhance CCl4 *** CO2 concentration increases with temperature.A CO concentration peak is observed around 800℃:with a certain Cl/H,the CO concentration first increases with temperature and then *** effect of increasing CH4 concentration on CCl4 destruction becomes mild above 900℃.Rather,it enhances the interaction between chlorine and carbonaceous radicals,which leads to higher concentration of toxic products.

关键词： hazardous waste destruction and removal efficiency(DRE) oxidation carbon tetrachloride chlorinated compounds methane

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A model for calculating heat transfer coefficient concerning ethanol‐water mixtures condensation

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AIP Conference Proceedings 2010年第1期1207卷 367-373页

作者： J. S. Wang J. J. Yan S. H. Hu Y. S. Yang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an China

The attempt of the author in this research is made to calculate a heat transfer coefficient (HTC) by combining the filmwise theory with the dropwise notion for ethanol‐water mixtures condensation. A new model, including ethanol concentration, vapor pressure and velocity, is developed by introducing a characteristic coefficient to combine the two mentioned‐above theories. Under different concentration, pressure and velocity, the calculation is in comparison with experiment. It turns out that the calculation value is in good agreement with the experimental result; the maximal error is within ±30.1.. In addition, the model is applied to calculate related experiment in other literature and the values obtained agree well with results in reference.

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Experimental and numerical study on flow separation control in rectangle diffuser

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Zhongguo Dianji Gongcheng Xuebao/Proceedings of the Chinese Society of Electrical engineering 2010年第5期30卷 92-99页

作者： Xie, Yong-Hui Fan, Tao Zhang, Di Ye, Dong-Ting Wang, Shun-Sen State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 Shaanxi Province China

To investigate the mechanism of active control for flow separation in rectangle diffuser by vortex generator jets (VGJs) method, numerical analysis with large-eddy simulation and experimental measurement by particle image velocimetry (PIV) were carried out for the flow field. The numerical results show good agreement with experimental data. The two dimensional vortical structure was discussed in detail via the analysis of their velocity and vorticity distribution. Based on the three dimensional identification of vortex, several vortical structure, with emphasis on the dynamic process of its generation and development, was also discussed. The results show that the jet shear-layer vortices evolved from vortex loops to vortex rings as time go on. Horseshoe vortices wrap around the jet nozzle have the strong stability. The counter-rotating vortex pair has mean-flow definition although they may also have unsteady components. Moreover, to investigate the effect of VGJs on separation control, the surface pressure coefficient, the length of separation zone, the flow characteristics in diffuser and pressure power spectra were compared with and without VGJs. It revealed the longitudinal vortices generate at the downstream of jet increase cross-stream mixing of streamwise momentum and then suppress or delay the separation in diffuser. © 201. *** ***.

关键词： Large eddy simulation

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First passage failure of dynamical power systems under random perturbations

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Science China(Technological Sciences) 2010年第9期53卷 2495-2500页

作者： CHEN LinCong1.& ZHU WeiQiu2 1.College of Civil engineering,Huaqiao University,Xiamen 361.21.China 2 Department of Mechanics,{1. key laboratory of Fluid power Transmission and Control,Zhejiang University,Hangzhou 31.027,China 1. College of Civil Engineering Huaqiao University Xiamen 361021 China2. Department of Mechanics State Key Laboratory of Fluid Power Transmission and Control Zhejiang University Hangzhou 310027 China

The first-passage problem of dynamical power system of a single-machine-infinite-bus (SMIB) system under random perturbations is ***,the stochastic averaging method for quasi non-integrable generalized Hamiltonian systems is applied to reduce the equations of the SMIB system under random perturbations to a set of averaged It ***,the backward Kolmogorov equation governing the conditional reliability function and the Pontryagin equation governing the conditional mean of first passage time are established and solved numerically,***,the proposed method is verified by using the Monte Carlo simulation of the original system.

关键词： dynamical power system random perturbation stochastic averaging first passage failure

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Research on the Preparation of (CuAg)xIn2xZn2(1.2x)S2 Solid Solution Photocatalysts

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AIP Conference Proceedings 2010年第1期1207卷 1066-1069页

作者： K. Zhang D. W. Jing C. J. Xing L. J. Guo State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University China

ZnS‐CuInS2‐AgInS2 solid solution photocatalysts were successfully prepared by co‐precipitation method with heat treatment under different atmosphere ( N2 and H2S). XRD, XRF, UV‐vis, and SEM were used to characterize the prepared photocatalysts, indicated that the composition of result photocatalysts were different from each other and also the rate of charge, though they possessed a wurtzite‐type phase structure. The photocatalysts all showed photocatalytic activities for H2 evolution from aqueous solutions containing SO32− and S2− as sacrificial reagents under visible light irradiation with Ru loading, but sample treated under H2S atmosphere performed better, the possible reason was proposed.

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Effects of radiation heat transfer space non-uniformity of combustion chamber components on in-cylinder soot emission formation in diesel engine

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Science China(Technological Sciences) 2010年第7期53卷 1824-1832页

作者： Lü JiZu1. BAI MinLi2 & LI XiaoJie1.1.state {1. laboratory of Structural Analysis for Industrial Equipment, Dalian University of Technology, Dalian 1.6023, China 2 School of Energy and power engineering, Dalian University of Technology, Dalian 1.6023, China 1. State Key Laboratory of Structural Analysis for Industrial Equipment Dalian University of Technology Dalian 116023 China2. School of Energy and Power Engineering Dalian University of Technology Dalian 116023 China

Combustion chamber components (cylinder head-cylinder liner-piston assembly-fuel film) were treated as a coupled body. Based on the three-dimensional numerical simulation of heat transfer of the coupled body, the multi-dimensional simulation computation coupling flow and solid on working process and combustion chamber components of internal combustion engine was performed using Discrete Transfer Radiation Model (DTRM) radiation heat transfer model, zoning solution method and boundary coupling method. The simulation was applied to the influence investigation of the space non-uniformity in radiation heat transfer among combustion chamber components on the generation of in-cylinder soot emissions. The results show that the space non-uniformity in heat transfer among the combustion chamber components has great influence on the generation of in-cylinder NOx emissions. The difference value of total soot in cylinder when exhaust valves are opened is 1.3% (no radiation), 0.8% (radiation). So the effect of radiation heat transfer space non-uniformity of combustion chamber components on total soot production can be ignored. While in local area radiation heat transfer space non-uniformity has certain effect on soot production inside whole combustion chamber space, and has less effect on soot production in the area near the wall of combustion chamber components.

关键词： radiation heat transfer space non-uniformity in-cylinder diesel engine

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Emission Characteristics and Axial Flame Temperature Distribution of a Circumferential Reverse flow Combustor

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Journal of Energy and power {1. 2010年第7期4卷 9-14页

作者： C. Dong Q.L. Zhou X.G. Zhang P. Sun T.M. Xu S.E. Hui Q.X. Zhao State Key Laboratory of Multiphase Flow in Power Engineering Xi ＇an Jiaotong University Xi ＇an 710049 China

In partially premixed combustion of gas turbine, the combustion temperature should be lowed in order to reduce NOx. One solution is lean premixed combustion. However, the problem is that large excess air ratio may make the combustion unstable. A novel combustor with circumferential reverse flow of fuel gas is proposed for settling this problem. A 1. kw furnace is established to test performance of this combustor. Three factors such as primary air ratio, position of secondary air, total excess air ratio are studied. The emission characteristics and axial flame temperature distribution are studied. Basing on experimental results, the axial flame temperature and NOr emission increase with primary air ratio and axial length of second stream, and decrease with total excess air ratio. When the total excess air ratio is larger than 1.05, the combustor presents a lower temperature field and much lower NOx emission （less than 1. ppm）.

关键词： Partially premixed combustor secondary air distributor NOx emission axial flame temperature experimentalinvestigation.

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Experimental Study of Falling Film on the Outside of Horizontal Tube

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AIP Conference Proceedings 2010年第1期1207卷 238-243页

作者： L. B. Yan H. X. Li B. Guo Y. Q. Zhang Z. Zhang Y. F. Zhang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049 China

Evaporating falling film on horizontal tubes has been widely used in desalinization, refrigeration, chemical process industries, and so on. In this paper, the flow characteristics of falling film outside horizontal tubes in horizontal air flows was studied theoretically and experimentally. Two low patterns of the falling film, i.e., droplet flow pattern and columnar flow pattern, were considered. Effects of the velocity of airflow, the flux of falling film flow, the external diameter of tube and the surface property of tube on the falling film flowing characters were investigated. Experimental study indicated that, in a definite flow scale, as the flow increased, the diameters of falling droplets and falling columns of the liquid enlarged, and the liquid film became thick and the area covered by the liquid film increased. As the air velocity increased, the offset of the droplet and the column to the top of the tube enlarged, and the rate of increase come down until it complete depart from the the top of the horizontal tube. Besides, a theoretical model was established about the offset of the droplet and liquid column from the top of the tube under the force of the horizontal air flows, and the model was validated by a comparison between the numerical predictions and experimental data.A further analysis about the excursion law of falling film flow outside horizontal tube was also made at the last paprt of the paper.

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Experimental Research on the Performance of Exhaust Steam Reclaim Device With a Swirling flow Vane

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AIP Conference Proceedings 2010年第1期1207卷 374-379页

作者： X. L. Li J. J. Yan P. F. Zhang J. J. Yang J. P. Liu State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University P.R. China

This paper experimentally studied the performance of exhaust steam reclaim device with a swirling flow vane at different inlet water pressures, temperatures, different inlet steam pressures and different distances between the throat and spout. The results indicated that the injection coefficient decreased as the inlet water pressure and temperature increased, respectively. There is a best distance between the throat and spout which makes the injection coefficient reached to its maximal value at the same experimental pressure and temperature, and the value equals to 1.0 mm in our experimental system. The resistance coefficient has a minimum value which makes the device have the highest outlet water pressure. Compared with the device without a swirling flow vane, it improves the heating performance for higher injection coefficient and exergy efficiency.

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Slagging characteristics on the superheaters of a 1. MW biomass-fired boiler

Slagging characteristics on the superheaters of a 12 MW biom...

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作者： Niu, Yanqing Tan, Hongzhang Ma, Lin Pourkashanian, Mohamed Liu, Zhengning Liu, Yang Wang, Xuebin Liu, Haiyu Xu, Tongmo State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xian Jiaotong University Xian 710049 China School of Process Environmental and Materials Engineering University of Leeds Leeds LS2 9JT United Kingdom

In an attempt to understand the problem of severe slagging in biomass-fired boilers, slags formed on the fourth-, second-, and first-stage superheaters in a 1. MW biomass-fired grate furnace have been collected, sampled, and analyzed using X-ray fluorescence (XRF) and X-ray diffraction (XRD) techniques. The slag collected on each superheater has a unique morphology and structure. The slag on the fourth-stage superheater is loose and porous, while on the secondary and the primary superheaters, the slag shows a clear layered structure of different colors and levels of hardness. Aluminosilicate is the major component in the slag on the fourth-stage superheater, which is formed by Si, Al, and alkali species. On both the secondary and primary superheaters, the sticky sylvine, potassium calcium sulfate, and aphthitalite in the bottom layer trap coarse, large particles, resulting in further slagging. In the alternating layers, the particles containing high concentrations of K, Na, and Cl form the initial deposit layer, the yellow layer in the secondary superheater. Then, it traps the coarse, large particles containing high Si, Al, Ca, Mg, and Fe to form the brown layer. Similarly, the particles in the pale-yellow layer of the primary superheater containing high concentrations of K, Na, and Cl form the initial deposit layer, and then, it traps the coarse, large particles containing high Si, Al, Ca, Mg, and Fe to form the black layer. Accompanied by the periodic blowing, the alternating layer is formed and the slag gradually becomes thicker. © 201. American Chemical Society.

关键词： Iron

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