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Crystalline carbon nitride with in-plane built-in electric field accelerates carrier separation for excellent photocatalytic hydrogen evolution

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Chinese Chemical Letters 2024年第4期35卷 160-165页

作者： Wengao Zeng Yuchen Dong Xiaoyuan Ye Ziying Zhang Tuo Zhang Xiangjiu Guan Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong UniversityXi'an 710049China

Achieving a high carrier migration efficiency by constructing built-in electric field is one of the promising approaches for promoting photocatalytic activity. Herein, we have designed a donor-acceptor(D-A) crystalline carbon nitride(APMCN) with 4-amino-2,6-dihydroxypyrimidine(AP) as electron donor, in which the pyrimidine ring was well embedded in the heptazine ring via hydrogen-bonding effect during hydrothermal process. The APMCN shows superior charge-transfer due to giant built-in electric field(5.94times higher than pristine carbon nitride), thereby exhibiting excellent photocatalytic H_(2) evolution rate(1.50 μmol/h) with a high AQY(62.8%) at 400 nm. Mechanistic analysis based on detailed experimental investigation together with theoretical analysis reveals that the excellent photocatalytic activity is attributed to the promoted charge separation by the giant internal electric field originated from the D–A structure.

关键词： Crystalline carbon nitride Built-in electric field Donor-acceptor structure Photocatalysis Hydrogen production

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Theoretical investigation on water/metal fuel ramjet motor-thermodynamic cycle and thermodynamic calculation

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航空动力学报 2010年第5期25卷 1129-1138页

作者： YANG Ya-jing HE Mao-gang School of Aerospace Xi'an Jiaotong UniversityXi'an 710049China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power EngineeringXi'an Jiaotong UniversityXi'an 710049China

For achieving high-speed requirement of underwater vehicle,a conceptual engine,which utilizes the hydroreactive characteristic of several metals under supercavitation environment,has been put forward. Especially,in order to obtain specific impulse as great as possible,a dual water injection system is taken into account. Then thermodynamic cycle model,which lead the improvement of power plant and energy system,is introduced in detail,and thermal efficiency is also analyzed. Furthermore,for investigating the performance of this kind of engine system,detailed thermodynamic calculation and analysis are achieved. Especially,regarding hydroreactive metal fuel Mg/AP/HTPB as our target fuel-rich propellant,considering its obvious deficient oxygen property and the energy property of magnesium/water reaction,theoretical calculation method is established by integrating chemical non-equilibrium with chemical equilibrium. Accordingly,low limit of primary water/fuel ratio is determined. In addition,the qualitative and quantitative relationship of performance parameters,such as theoretical specific impulse,nozzle exit temperature,characteristic velocity,etc.,versus water/fuel ratio is investigated respectively.

关键词： hydroreactive metal fuel water ramjet thermodynamic cycle thermal efficiency specific impulse

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Progress in hydrogen enriched hydrocarbons combustion and engine applications

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Frontiers in Energy 2014年第1期8卷 73-80页

作者： Zuohua HUANG Jinhua WANG Erjiang HU Chenglong TANG Yingjia ZHANG State Key Laboratory of Multiphase Flow in Power Engineering Xi'anJiaotong University Xi'an 710049 China

The paper summarized the work on hydrogen enriched hydrocarbons combustion and its application in engines. The progress and understanding on laminar burning velocity, flame instability, flame structure flame and chemical kinetics were presented. Based on funda- mental combustion, both homogeneous spark-ignition engine and direct-injection spark-ignition engine fueled with natural gas-hydrogen blends were conducted and the technical route of natural gas-hydrogen combined with exhaust gas recirculation was proposed which experimen- tally demonstrated benefits on both thermal efficiency improvement and emissions reduction.

关键词： hydrogen enriched hydrocarbon combustion,fundamental study engine application

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Experimental investigations on combustion characteristics of syngas composed of CH_(4),CO,and H_(2)

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Frontiers of Chemical Science and engineering 2010年第4期4卷 404-410页

作者： Qingwei FAN Shien HUI Qulan ZHOU Qinxin ZHAO Tongmo XU State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China

The residual gas and remained raw gas in dual gas resources polygeneration system are quite complex in components(mainly CH_(4),CO,and H_(2)),and these results to the distinguished differences in combustion *** investigations on basic combustion characteristics of syngas referred above are conducted on a laboratory-scale combustor with flame temperature and flue gas composition measured and *** air coefficient(PA),total air coefficient(TA),and components of the syngas(CS)are selected as {1. factors,and it is found that PA dominates mostly the ignition of syngas and NOx formation,while TA affects the flue gas temperature after high temperature region and NOx formation trend to be positive as H_(2)/CO components *** results provide references for industrial utilization.

关键词： dual gas resources polygeneration lean premixed combustion residual gas remained raw gas NOx emission

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Experimental research on catalysts and their catalytic mechanism for hydrogen production by gasification of peanut shell in supercritical water

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中国高等学校学术文摘·能源与动力工程 2007年第4期1卷 451-456页

作者： PEI Aixia GUO Liejin JIN Hui State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China

Peanut shell,mixed with sodium carboxymethylcellulose,was gasified at a temperature of 450℃ and a pressure range from 24 to 27 MPa with the presence of different catalysts,including K2CO3,ZnCl2 and *** experimental results show that different catalysts have greatly different effects on the *** efficiency (GE),hydrogen gasification efficiency (GHE),carbon gasification efficiency (GCE),yield of hydrogen production (YH2) and potential yield of hydrogen production (YPH2) are applied to describe the catalytic *** the result of gaseous components,ZnCl2 has the highest hydrogen selectivity,K2CO3 is lower,and Raney-Ni is the lowest,but Raney-Ni is the most favorable to gasify biomass among the three catalysts,and its GE,GHE,GcE reach 1.6.84%,1.5.71.,94.24%,*** expected,hydrogen selectivity increased and CH4 reduced rapidly when the mixture of ZnCl2 and Raney-Ni is used under the same *** optimization mixture appeared when 0.2 g of ZnCl2 was added to 1.g of Raney-Ni,43.56 g·kg-1.of hydrogen production was *** addition,the catalytic mechanisms of different catalysts were analyzed,and the possible reaction pathway was brought forward,which helped to explain the experiment phenomena and results correctly.

关键词： biomass supercritical water gasification,hydrogen production

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Combustion and emission characteristics of a turbo-charged common rail diesel engine fuelled with diesel-biodiesel-DEE blends

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能源前沿 2011年第1期5卷 104-114页

作者： Ni ZHANG Zuohua HUANG Xiangang WANG Bin ZHENG State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049China

The combustion and emission characteristics of a turbo-charged, common rail diesel engine fuelled with diesel-biodiesel-DEE blends were investigated. The study repons that the brake-specific fuel consumption of dieselbiodiesel-DEE blends increases with increase of oxygenated fuel fractions in the blends. Brake thermal efficiency shows little variation when operating on different dieselbiodiesel-DEE blends. At a low load, the NOx emission of the diesel-biodiesel-DEE blends exhibits little variation in comparison with the biodiesel fraction. The NOx emission slightly increases with increase in the biodiesel fraction in diesel-biodiesel-DEE blends at medium load. However,the NOx emission increases remarkably with increase of the biodiesel fraction at high load. Particle mass concentration decreases significantly with increase of the oxygenated-fuels fraction at all engine speeds and loads;particle number concentration decreases remarkably with increase of the oxygenated-fuels fraction. HC and CO emissions decrease with increasing oxygenated-fuels fraction in these blends.

关键词： Combustion particulate emissions dieselbiodiesel-DEE blend diesel engine

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Experimental study on premixed combustion of spherically propagating methanol-air-nitrogen flames

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中国高等学校学术文摘·能源与动力工程 2010年第2期4卷 223-233页

作者： Xiangang WANG Zhiyuan ZHANG Zuobua HUANG Xibin WANG Haiyan MIAO State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China

The outward propagation and development of surface instability of the spark-ignited spherical premixed flames for methanol-air-nitrogen mixtures were experimentally studied by using a constant volume combustion chamber and a high-speed schlieren photography system. The laminar burning velocities, the mass burning fluxes, and the Markstein lengths were obtained at different equivalence ratios, dilution ratios, initial temperatures, and pressures. The laminar burning velocities and the mass burning fluxes give a similar curve versus the equivalence ratios. They increase with the increase of initial temperature and decrease with the increase of dilution ratio. The laminar burning velocity decreases with elevating the initial pressure, while the mass burning flux increases with the increase of the initial pressure. Markstein length decreases slightly with the increase of initial temperature for the rich mixtures. High initial pressure corresponds to low Markstein length. Markstein length increases with the increase of dilution ratio, which is more obvious when the mixture becomes leaner. Equivalence ratio has a slight impact on the development of the diffusive-thermal cellular structure at elevated initial pressures. The initial pressure has a significant influence on the occurrence of the flame front cellular structure. At the elevated pressures, the cracks on the flame surface branch and develop into the cell structure. These cells are bounded by cracks emitting a bright light, which may indicate soot formation. For very lean mixture combustion, the buoyancy effect and cooling effect from the spark electrodes have a significant impact on the flame propagation. The hydrodynamic instability, inhibited with the increase of initial temperature around the stoichiometric equivalence ratio, is enhanced with the increase of initial pressure and suppressed by mixture dilution.

关键词： methanol spherical flame propagation characteristics flame instabilities

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Influence of cetane number improver on performance and emissions of a common-rail diesel engine fueled with biodiesel-methanol blend

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能源前沿 2011年第4期5卷 412-418页

作者： Wu YU Gen CHEN Zuohua HUANG State Key Laboratory of Multiphase Flow in Power Engineering Xi'anJiaotong University Xi'an 710049 China

In this paper,the effect ofcetane number (CN)improver on performance and emissions,including particulate number concentration and size distribution,of a turbocharged,common-rail diesel engine fueled with biodiesel-methanol were *** volume fractions (0.3％ and 0.6％) of CN improver were added to BM30 (30％ of methanol in the biodiesel-methanol blend) in the *** results show that,compared with those of biodiesel-methanol blend,the peak value of cylinder pressure increases,the second peak of heat release rate decreases,the start of second heat release are advanced,and the fuel economy and thermal efficiency are improved when CN improver is added to biodiesel-methanol ***,CO and HC emissions decrease,NOx emission varies little and smoke emissions increase ***,exhaust particles of BM30 mainly distribute in nanosize ***,particle number concentration decreases and peak of size distribution profile shifts toward large size direction.

关键词： biodiesel methanol common-rail (CR) dieselengine cetane number (CN) improver

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Numerical simulation of the heat flux distribution in a solar cavity receiver

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能源前沿 2011年第1期5卷 98-103页

作者： Yueshe WANG Xunwei DONG Jinjia WEI Hui JIN State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an 710049China

In the solar tower power plant, the receiver is one of the main components of efficient concentrating solar collector systems. In the design of the receiver, the heat flux distribution in the cavity should be considered first. In this study, a numerical simulation using the Monte Carlo Method has been conducted on the heat flux distribution in the cavity receiver, which consists of six lateral faces and floor and roof planes, with an aperture of 2.0m×2.0m on the front face. The mathematics and physical models of a single solar ray's launching,reflection, and absorption were proposed. By tracing every solar ray, the distribution of heat flux density in the cavity receiver was obtained. The numerical results show that the solar flux distribution on the absorbing panels is similar to that of CESA-I's. When the reradiation from walls was considered, the detailed heat flux distributions were issued, in which 49.1.% of the total incident energy was absorbed by the central panels,47.02% by the side panels, and 3.88% was over{1.ed from the aperture. Regarding the peak heat flux, the value of up to 1.96.406 kW/m2 was obtained in the center of absorbing panels. These results provide necessary data for the structure design of cavity receiver and the local thermal stress analysis for boiling and superheated panels.

关键词： solar cavity receiver Monte Carlo method heat flux distribution

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Convective heat transfer in helical coils for constant-property and variable-property flows with high Reynolds numbers

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中国能源与动力工程前沿 2010年第4期4卷 546-552页

作者： Yufei MAO Liejin GUO Bofeng BAI Ximin ZHANG State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

Forced convection heat transfer of single-phase water in helical coils was experimentally studied. The testing section was constructed from a stainless steel round tube with an inner diameter of 1.?mm, coil diameter of 300?mm, and pitch of 50?mm. The experiments were conducted over a wide Reynolds number range of 40000 to 500000. Both constant-property flows at normal pressure and variable-property flows at supercritical pressure were investigated. The contribution of secondary flow in the helical coil to heat transfer was gradually suppressed with increasing Reynolds number. Hence, heat transfer coefficients of the helical tube were close to those of the straight tube under the same flow conditions when the Reynolds number is large enough. Based on the experimental data, heat transfer correlations for both incompressible flows and supercritical fluid flows through helical coils were proposed.

关键词： convective heat transfer helical coils high Reynolds number supercritical pressure variable property

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