检索结果-内蒙古大学图书馆

Hydrogen production by catalytic gasification of cellulose in supercritical water

Frontiers of Chemical Science and engineering 2008年第2期2卷 176-180页

作者： Yu GUAN Aixia PEI Liejin GUO State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China

Cellulose,one of the important components of biomass,was gasified in supercritical water to produce hydrogen-rich gas in an autoclave which was operated batch-wise under high-pressure.K_(2)CO_(3) and Ca(OH)2 were selected as the catalysts(or promoters).The temperature was kept between 450uC and 500uC while pressure was maintained at 24–26 *** reaction time was 20 *** results showed that the two catalysts had good catalytic effect and optimum amounts were observed for each *** 0.2 g K_(2)CO_(3) was added,the hydrogen yield could reach 9.456 mol?kg21.which was two times of the H2 amount produced without *** 1.6 g Ca(OH)2 was added,the H2 yield was 8.265 mol?kg21.which is lower than that obtained using K_(2)CO_(3) as catalyst but is still 1.7 times that achieved without *** with the results obtained using K_(2)CO_(3) or Ca(OH)2 alone,the use of a combination of K_(2)CO_(3) and Ca(OH)2 could increase the H2 yield by up to 2.5 times that without catalyst and 25%and 45%more than that obtained using K_(2)CO_(3) and Ca(OH)2 alone,*** was found that methane was the dominant product at relatively low *** the temperature was increased,the methane reacts with water and is converted to hydrogen and carbon dioxide.

关键词： biomass hydrogen production supercritical water gasification hydrogen

来源：评论

学校读者我要写书评

暂无评论

Chlorine anchored pyrrole-based conjugated porous polymers for ultrahigh capacity and selective Hg(II) capture

引用

Separation and Purification Technology 2025年 374卷

作者： Bianyan He Jiarui Zhang Yubing Wang Mingtao Li Wei Yan Department of Environmental Science and Engineering Xi’an Key Laboratory of Solid Waste Recycling and Resource Recovery Xi’an Jiaotong University Xi’an 710049 PR China State Key Laboratory of Multiphase Flow in Power Engineering School of Energy and Power Engineering Xi’an Jiaotong University Xi’an 710049 PR China

In this study, chlorine anchored pyrrole-based conjugated porous polymers (CPPs) with distinct pore properties were synthesized using the Knoevenagel reaction and the double chain condensation method. The partially crosslinked and partially oxidized structures of the materials exhibit a unique microstructure integrating interconnected nets and molecular hooks. This architecture utilizes pore channels for physical interception of Hg(II), while synergistic chemical immobilization at N, O, and Cl active sites enables multifunctional enhancement of Hg(II) capture efficiency. Among these materials, the maximum adsorption capacity reached 1.83 mg·g −1., demonstrating ultrahigh selectivity. Moreover, the adsorbents maintained > 90 % removal efficiency over 1. adsorption–desorption cycles, confirming excellent reusability. Mechanistic studies revealed that Hg(II) adsorption primarily whin material pores through hydrogen bonding and coordination interactions, and their synergistic interactions. This work highlights the efficiency of the double chain condensation design strategy in advancing conjugated porous polymers for the removal of heavy metals, particularly Hg(II), from wastewater.

关键词：

来源：评论

学校读者我要写书评

暂无评论

Proposal and thermodynamic analysis of a steam methane reforming system integrated with thermochemical energy storage and a SCO₂ brayton cycle

引用

Journal of Energy Storage 2025年 127卷

作者： Fu, Yu Liu, Ming Wang, Zhu Xie, Tao Yan, Junjie State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China Institute of Industrial Catalysis School of Chemical Engineering and Technology Xi'an Jiaotong University Xi'an 710049 China

Solar energy is a promising alternative to fossil fuels for providing heat in steam methane reforming (SMR) hydrogen production. However, the variability of solar energy requires effective storage solutions. This study presents a new SMR hydrogen production system that integrates thermochemical energy storage (TCES) utilizing a CaO/CaCO₃ cycle with a SCO₂ Brayton cycle. The system converts fluctuating solar energy into the stable chemical energy of CaO by calcinating CaCO₃ in the solar calciner, with the SMR reaction mainly heated by the exothermic reaction of CaO and CO₂. The SCO₂ Brayton cycle efficiently recovers heat from the high-temperature SMR products. Comprehensive thermodynamic analysis and evaluation models are developed. Results show that the proposed system performs well, achieving energy and exergy efficiencies of 73.49 % and 78.46 %, respectively, under benchmark conditions. The energy storage efficiency of TCES is 81.55 %, and the solar-to-chemical energy efficiency is 48.21.%. Integrating TCES significantly enhances the system's steady operation under fluctuating solar energy conditions. The calciner accounts for the largest share of exergy destruction at 31.63 %, followed by the carbonator at 1..50 %. Sensitive analyses of key operating parameters indicate that higher CaO conversion rate and storage temperature enhance energy storage, energy, and exergy efficiencies. Besides, the energy and exergy efficiencies decrease with the increasing SMR reaction pressure but increase with rising reaction temperature. When the S/C is 2.0, these efficiencies reach their maximum values of 75.42 % and 78.63 %, respectively. © 2025 Elsevier Ltd

关键词： Hydrogen production SCO2 Brayton cycle Solar energy Steam methane reforming Thermochemical energy storage

来源：评论

学校读者我要写书评

暂无评论

High tension cyclic hydrocarbons synthesized from biomass-derived platform molecules for aviation fuels in two steps

引用

Green Energy & Environment 2023年第1期8卷 331-337页

作者： Zhanchao Li Yizhuo Wang Qing Li Liqing Xu Hong Wang Frontier Institute of Science and Technology Xi'an Jiaotong UniversityXi'an710054China State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong UniversityXi'an710054China

Synthesizing ring structure aviation fuels from biomass-derived platform molecules is challenging,especially for bridged ring structure aviation fuels which are typically achieved from fossil-derived ***,we report the synthesis of a series of ring structure biofuels in two steps by a combination of a solvent-free Michael-cyclization reaction and a hydrodeoxygenation(HDO)reaction from lignocellulosederived 5,5-dimethyl-1.*** biofuels are obtained with high overall yields up to 90%,which exhibit high densities of 0.81.g cm^(-3)-0.88 g cm^(-3)and high volumetric neat heat of combustion(VNHOC)values of 36.0 MJ L^(-1.-38.6 MJ L^(-1..More importantly,bridged-ring structure hydrocarbons can also be achieved in two steps by a combination of a Robinson annulation reaction and an HDO reaction to afford the final products at high overall yields up to 90%.The bridged-ring structure products have comparable high densities and high VNHOC values to the best artificial fuel JP-1.(0.94 g cm^(-3)and 39.6 MJ L^(-1.).The results demonstrate a promising way for the synthesis of high-density aviation fuels with different fuel properties at high yields.

关键词： Biofuels 5,5-Dimethyl-1.3-cyclohexanedione Solvent-free Michael-cyclization Robinson annulation Green reaction

来源：评论

学校读者我要写书评

暂无评论

Experimental Study of Drop Deformation and Breakup in Simple Shear flows

引用

Chinese Journal of Chemical engineering 2007年第1期15卷 1-5页

作者：林长志郭烈锦 State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University

The experimental results of the deformation and breakup of a single drop immersed in a Newtonian liq-uid and subjected to a constant shear rate which generated by counter rotating Couette apparatus were presented in this paper. From experimental observations, the breakup occurred by three mechanisms, namely, necking, end pinching, and capillary instability. Quantitative results for the deformation and breakup of drop are presented. The maximum diameter and Sauter mean diameter of daughter drops and capillary thread radius are linearly related to the inverse shear rate and independent of the initial drop size, the dimensionless wavelength which is the wave-length divided by the thread width at breakup is independent of the shear rate and initial drop size, and the deforma-tion of threads follows a pseudo-affine deformation for Cai/Cac larger than 2.

关键词： drop deformation breakup Couette shear flow

来源：评论

学校读者我要写书评

暂无评论

Gas flow in a Stratified Porous Medium with Crossflow

引用

Journal of Thermal Science 2002年第1期11卷 35-40页

作者： Sun Hedong Gao Chengtai Qian Huanqun Zhou Fangde State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong University Xi’an 710049China Department of Petroleum Engineering Xi’an Petroleum InstituteXi’an 710065China

A new model called semi-permeable wall model is presented for multilayer gas reservoir. The model is used to study the influence of crossflow on pressure transient well tests and other single-phase flow problems. It is suggested here to use this model to approximate the actual multilayer gas reservoir, so that the problem is greatly simplified mathematically. Its differential equation is established here for multilayer gas reservoirs, and is linearized by normalized pseudo pressure and pseudo time. Simulation program is developed by finite-difference method when all layers are perforated. The feature of wellbore pressure and rate is clarified by analyzing the results of numerical simulation.

关键词： multi-layer gas reservoir semi-permeable wall model numerical simulation transient well-test wellbore storage skin factor.

来源：评论

学校读者我要写书评

暂无评论

Evaluation of frictional pressure drop correlations for air-water and air-oil two-phase flow in pipeline-riser system

引用

Petroleum Science 2024年第2期21卷 1305-1319页

作者： Nai-Liang Li Bin Chen School of Low-carbon Energy and Power Engineering China University of Mining and TechnologyXuzhou221116JiangsuChina State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an710049ShaanxiChina

Accurate prediction of the frictional pressure drop is important for the design and operation of subsea oil and gas transporting system considering the length of the pipeline. The applicability of the correlations to pipeline-riser flow needs evaluation since the flow condition in pipeline-riser is quite different from the original data where they were derived from. In the present study, a comprehensive evaluation of 24prevailing correlation in predicting frictional pressure drop is carried out based on experimentally measured data of air-water and air-oil two-phase flows in pipeline-riser. Experiments are performed in a system having different configuration of pipeline-riser with the inclination of the downcomer varied from-2°to-5°to investigated the effect of the elbow on the frictional pressure drop in the riser. The inlet gas velocity ranges from 0.03 to 6.2 m/s, and liquid velocity varies from 0.02 to 1.3 m/s. A total of885 experimental data points including 782 on air-water flows and 1.3 on air-oil flows are obtained and used to access the prediction ability of the correlations. Comparison of the predicted results with the measured data indicate that a majority of the investigated correlations under-predict the pressure drop on severe slugging. The result of this study highlights the requirement of new method considering the effect of pipe layout on the frictional pressure drop.

关键词： Frictional pressure drop Pipeline-riser Gas-liquid two-phase flow Severe slugging Correlation

来源：评论

学校读者我要写书评

暂无评论

Enhanced efficiency in Concentrated Parabolic Solar Collector(CPSC) with a porous absorber tube filled with metal nanoparticle suspension

引用

Green Energy & Environment 2018年第2期3卷 129-137页

作者： Mohammad Hatami Jiafeng Geng Dengwei Jing Mechanical Engineering Department Esfarayen University of Technology (EUT) International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi'an Jiaotong University

In this study, effects of different nanoparticles and porosity of absorber tube on the performance of a Concentrating Parabolic Solar Collector(CPSC) were investigated. A section of porous-filled absorber tube was modeled as a semi-circular cavity under the solar radiation which is filled by nanofluids and the governing equations were solved by FlexPDE numerical software. The effect of four physical parameters, nanoparticles type, nanoparticles volume fraction(φ), Darcy number(Da) and Rayleigh number(Ra), on the Nusselt number(Nu) was discussed. It turns out that Cu nanoparticle is the most suitable one for such solar collectors, compared to the commonly used Fe_3O_4, Al_2O_3, TiO_*** the increased addition of Cu nanoparticles all the parameters φ, Da and Ra shows a significant increase against the Nu, indicates the enhanced heat transfer in such cases. As a result, low concentration of Cu nanoparticle suspension combined with porous matrix was supposed to be beneficial for the performance enhancement of concentrating parabolic solar collector.

关键词： Concentrating parabolic solar collector Porous absorber tube Nanofluid Nusselt number Finite Element Method

来源：评论

学校读者我要写书评

暂无评论

Coupling Effect of Heat Transfer and flow Resistance in the Rifled Tube Water Wall of a Ultra-Supercritical CFB Boiler

引用

Journal of Thermal Science 2019年第5期28卷 1078-1088页

作者： LI Yaode YANG Dong OUYANG Shijie LIU Dan WANG Wenyu State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China North China Electric Power Test and Research Institute Co. Ltd Tianjing 300000 China

The coupling factor is used in this study to characterise the combined effect of the heat transfer and resistance characteristics of a rifled tube. Boundary layer theory is utilised to investigate the relationship between the comprehensive coefficient and Reynolds number in two regions, namely, higher and lower than pseudo-critical enthalpy. Results indicate that mass flux exerts a decisive negative influence on the coupling effect, and the impacts of pressure and heat flux are weak. The overall effect decreases rapidly as the mass flux increases, but it increases in the area behind the quasi-critical enthalpy. The coupling effect is also affected by specific heat ratio, thermal acceleration and buoyancy. The correlations of heat transfer and friction resistance are deduced with high precision according to experimental data.

关键词： supercritical pressure heat transfer frictional resistance coupling effect

来源：评论

学校读者我要写书评

暂无评论

Void fraction measurement and calculation model of vertical upward co-current air-water slug flow

引用

Chinese Journal of Chemical engineering 2022年第11期51卷 178-198页

作者： Teng Wang Miao Gui Jinle Zhao Qincheng Bi Tao Zhang State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China School of Nuclear Science and Technology Xi’an Jiaotong UniversityXi’an 710049China

The focus of this paper is on the measurement and calculation model of void fraction for the vertical upward co-current air-water slug flow in a circular tube of 1. mm inner diameter. High-speed photography and optical probes were utilized, with water superficial velocity ranging from 0.089 to 0.65 m·s^(-1.and gas superficial velocity ranging from 0.049 to 0.65 m·s^(-1.. A new void fraction model based on the local parameters was proposed, disposing the slug flow as a combination of Taylor bubbles and liquid slugs. In the Taylor bubble region, correction factors of liquid film thickness Cδand nose shape CZ*were proposed to calculate aTB. In the liquid slug region, the radial void fraction distribution profiles were obtained to calculate aLS, by employing the image processing technique based on supervised machine learning. Results showed that the void fraction proportion in Taylor bubbles occupied crucial contribution to the overall void fraction. Multiple types of void fraction predictive correlations were assessed using the present data. The performance of the Schmidt model was optimal, while some models for slug flow performed not outstanding. Additionally, a predictive correlation was correlated between the central local void fraction and the cross-sectional averaged void fraction, as a straightforward form of the void fraction calculation model. The predictive correlation showed a good agreement with the present experimental data, as well as the data of Olerni et al., indicating that the new model was effective and applicable under the slug flow conditions.

关键词： Slug flow Gas-liquid flow Void fraction Measurement Optical probe Model

来源：评论

学校读者我要写书评

暂无评论

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案：

请选择收藏分类：

通借通还

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：