Ions at the oil-water interface is a ubiquitous phenomenon which plays a important role in many industrial processes,such as extraction separation,nanoparticle assembly,enhanced oil recovery,*** the petroleum industry...
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Ions at the oil-water interface is a ubiquitous phenomenon which plays a important role in many industrial processes,such as extraction separation,nanoparticle assembly,enhanced oil recovery,*** the petroleum industry,due to the long-term interaction with solids and crude oil,the water including formation water,injection water and aqueous solution dissolves lots of ions,such as Na,K,Ca,Mg Cl,SO,*** migration of charged ions in the bulk phase or interface between oil and water has a significant influence on the molecular packing of active species at the interface,zeta potential of oil droplets and microstructure and strength of interfacial film by changing the interfacial tension,interface viscosity and electrical repulsion of charged ganglia,thus affecting the stability of crude oil emulsions and the oil displacement in porous ***,more detailed knowledge of how ions affect the properties of oil-water interface is ***,we perform a molecular dynamics(MD) study on the effects of ions on the oil-water interface using the LAMMPS package in the NVT *** temperature of the system is kept at 300 K via Nose-Hoover *** simulation box,whose volume equals to4×4×1..4 nm,is divided into two layers of oil and water *** boundary conditions are applied in x-,y-and *** is adopted as the oil phase according to "equivalent alkane carbon number"(EACN) value of crude *** are arranged uniformly in the water *** and Clions are involved,because they are basic components of brine and quite common in the *** atomic interactions between decane molecules are described by the OPLS-AA potential while the TIP3 P model of water is adopted to consider both dispersive and electrostatic *** cut-off distance of all potentials is 1. *** results demonstrate that the structures and dynamics of the oil-water interface is significantly affected by Na and *** kosmotropes,Na ions remain strongly h
A new absorption refrigeration system, which is driven by solar energy, biomass energy and geothermal energy simultaneously, was designed with capillaries as its radiation surface. Likewise, variations of water temper...
A new absorption refrigeration system, which is driven by solar energy, biomass energy and geothermal energy simultaneously, was designed with capillaries as its radiation surface. Likewise, variations of water temperature in the capillaries with the change in both time and its flow rate were experimentally researched as well as how COP of the system varies with the surrounding temperature. The following conclusions have been obtained: Common refrigeration demand can be met by the system after its operation in 1.hour; with the increase in water flow rate in the capillaries, its temperature, which drops down after an increase, gets its peak value at the flow rate of 4.5-5.5 L/min; COP of the system decreases with the rise of surrounding temperature, thus it’s better to keep it from direct sunlight. With the utilization of natural energy and the structure of capillaries, the system’s advantages in simple structure, low cost, environment-friendly working process and nice performance lead to promising application prospects, especially in residence refrigeration in countryside.
Two-phase cryogenic flow are involved in many cooling systems. In order to study the mechanism of cryogenic two phase flow. Two-phase pressure drop of liquid nitrogen (LN2) in a circular horizontal channels was experi...
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The integration of flue gas fan mill dryer with an open pulverizing system significantly improves the plant thermal efficiency of the Flue Gas Pre-dried Lignite-fired power Systems (FPLPS). The aim of this article is ...
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Recently,plasma-assisted combustion has become a potentially applicable technology in many combustion *** this paper,a dielectric barrier discharge(DBD) plasma generator is designed to explore the effect of plasma o...
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Recently,plasma-assisted combustion has become a potentially applicable technology in many combustion *** this paper,a dielectric barrier discharge(DBD) plasma generator is designed to explore the effect of plasma on the CH4 oxidation process,and several properties of combustion are ***,in the presence or absence of plasma discharge,physical appearance of the flame is examined and ***,the flame propagation velocity is calculated by the flame front extracted from the imaging data with the Bunsen burner ***,the main molecular components and their intensity variation in the flame and the plasma zones are identified with an emission spectrograph to analyze the effect of active species on the combustion *** also discuss the possible kinetic regime of plasma-assisted *** results imply that plasma discharge applied to the premixed CH_4/O_2/He mixture significantly raises the flame speed with equivalence ratios ranging from 0.85 to 1.1.,with the flame speed improved by 1.%to 35%.It can be seen that plasma can improve methane oxidation efficiency in the premixed fuel/oxidizer,especially at a low equivalence ratio.
Red phosphorus is a promising photocatalyst with wide visible‐light absorption up to 700 nm, but the fast charge recombination limits its photocatalytic hydrogen evolution reaction (HER) activity. Now, [001.‐oriente...
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Red phosphorus is a promising photocatalyst with wide visible‐light absorption up to 700 nm, but the fast charge recombination limits its photocatalytic hydrogen evolution reaction (HER) activity. Now, [001.‐oriented Hittorf's phosphorus (HP) nanorods were successfully grown on polymeric carbon nitride (PCN) by a chemical vapor deposition strategy. Compared with the bare PCN and HP, the optimized PCN@HP hybrid exhibited a significantly enhanced photocatalytic activity, with HER rates reaching 33.2 and 1..5 μmol h −1.from pure water under simulated solar light and visible light irradiation, respectively. It was theoretically and experimentally indicated that the strong electronic coupling between PCN and [001.‐oriented HP nanorods gave rise to the enhanced visible light absorption and the greatly accelerated photoinduced electron–hole separation and transfer, which benefited the photocatalytic HER performance.
To understand droplet motion on solid surfaces is very important for many applications such as enhanced oil recovery (Freitas et al.201.), droplet spreading, manipulation and fabrication of droplets in microfluidic de...
To understand droplet motion on solid surfaces is very important for many applications such as enhanced oil recovery (Freitas et al.201.), droplet spreading, manipulation and fabrication of droplets in microfluidic devices (Worner et al.201.).Solid surface wettability affects significantly the movement of the contact line and hence dominants the motion of droplets on solid surfaces, especially when the flow is confined to microscale.
Compound solution of N-methyl-diethanolamine and dimethyl sulfoxide were selected to remove CO2, SO2 and NOx simultaneously in an experimental systems of micro bubbling bed. With suitable absorbent formula, the influe...
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Ions at the oil-water interface is a ubiquitous phenomenon which plays a important role in many industrial processes, such as extraction separation, nanoparticle assembly, enhanced oil recovery, *** the petroleum indu...
Ions at the oil-water interface is a ubiquitous phenomenon which plays a important role in many industrial processes, such as extraction separation, nanoparticle assembly, enhanced oil recovery, *** the petroleum industry, due to the long-term interaction with solids and crude oil, the water including formation water, injection water and aqueous solution dissolves lots of ions, such as Na+, K+, Ca2+, Mg2+, Cl-, SO42-, *** migration of charged ions in the bulk phase or interface between oil and water has a significant influence on the molecudar packing of active species at the interface, zeta potential of oil droplets and microstructure and strength of interfacial film by changing the interfacial tension, interface viscosity and electrical repulsion of charged ganglia, thus affecting the stability of crude oil emulsions and the oil displacement in porous ***, more detailed knowledge of how ions affect the properties of oil-water interface is required.
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