Spark plasma sintering (SPS) and Self-propagating High-temperature synthesis/ quick pressing (SHS/QP) methods were used to fabricate nanotubes reinforced alumina. The difference in microstructure was discussed. In the...
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Spark plasma sintering (SPS) and Self-propagating High-temperature synthesis/ quick pressing (SHS/QP) methods were used to fabricate nanotubes reinforced alumina. The difference in microstructure was discussed. In the SHS/QP process, the maximum densification temperature is 1660°C and the heating rate is about 1600°C /min. The whole densification process in SHS/QP is very short, which is much beneficial to protect the nanotubes and restrain the growing of grains. The fracture toughness of the sample prepared by SHS/QP is up to 4.9MPam1/2 for 1mass% CNTs/Al2O3 composites, which shows excellent toughening effects of nanotubes.
Superparamagnetic FePt nanoparticles (NPs) have attracted considerable attention due to their extremely promising potentials as the diagnostic and therapeutic reagent in biomedical *** the present study,water-soluble ...
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Superparamagnetic FePt nanoparticles (NPs) have attracted considerable attention due to their extremely promising potentials as the diagnostic and therapeutic reagent in biomedical *** the present study,water-soluble FePt NPs about 4 nm in diameter and oil-soluble FePt NPs about 6 nm in diameter were successfully synthesized using amino acids and oleic acid/oleylamine as the capping reagent,*** component,size and magnetic property of FePt NPs were tuned through adjusting the reactant molar ***,the anticancer activities of FePt NPs with different capping reagents were evaluated using different brain tumor cell lines (such as U251,U87,H4) as the *** growth prohibition of tumor cells by NPs was measured through MTT assay,while the interaction of NPs and tumor cells was observed through transmission electron microscopy (TEM).The results show that FePt NPs capped with oleic acid/oleylamine displayed better cytotoxic effects toward brain tumor cells than L-cysteine-capped FePt *** is interesting that the cellular uptake of FePt NPs seem to be similar in three cell *** conclusions,we synthesized successfully superparamagnetic FePt NPs with the different component using different capping reagents,which displayed different anticancer activities on Human brain tumor *** results also provide a promising potential of superparamagnetic FePt NPs as the multifunctional diagnostic and therapeutic reagent in biomedical fields.
Highly oriented titanate nanotube (TNT) film was successfully synthesized by a simple electrophoretic deposition (EPD) method without any hard templates and surfactants. This oriented films adequately utilized the exc...
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Highly oriented titanate nanotube (TNT) film was successfully synthesized by a simple electrophoretic deposition (EPD) method without any hard templates and surfactants. This oriented films adequately utilized the excellent properties of ID nanomaterials such as single crystal semiconductor architectures, large surface area, and superior charge transport, which lead to higher photocatalytic activity. We believe that this versatile method can be extent to fabricate other ordered ID nanomaterials films. [ABSTRACT FROM AUTHOR]
The ability to fabricate high precision micro- to nanoscale structure in a wide variety of materials is of crucial importance for the advancement of microtechnology, nanotechnology and nanoscience. Also, the ability t...
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The ability to fabricate high precision micro- to nanoscale structure in a wide variety of materials is of crucial importance for the advancement of microtechnology, nanotechnology and nanoscience. Also, the ability to create micrometer and sub-micrometer architecture for functional ceramics is a prerequisite of exploring the rich field of ceramic nanotechnology. In this work we fabricated three-dimensional oxide ceramic materials with fine-structure over multiple length scales by combining replication patterning technique, polyvinyl alcohol (PVA), oxide ceramic material (TiO2) nano-sized particles. Our study is based on the idea that PVA can be easily detached from a mold by peeling. We confirmed that micron and sub-micron-sized fine-structured oxide ceramic patterns containing nano-sized pores could be fabricated using this procedure. The results presented demonstrate the compositional and structural diversities that are possible with a facile approach and simple method.
In present paper a new niobate materials Ba5LixTixNb10-xO30 were synthesized by doping Li+ in the system BaO- TiO2- Nb2O5 in millimeter wave field. X-ray diffraction (XRD) quantitative and scanning transition spectros...
In present paper a new niobate materials Ba5LixTixNb10-xO30 were synthesized by doping Li+ in the system BaO- TiO2- Nb2O5 in millimeter wave field. X-ray diffraction (XRD) quantitative and scanning transition spectroscopy (SEM) analysis were employed to study crystal structure and microstructure of reaction products. It was found that pure products could be obtained at temperature 900°, 8 min which is lower comparing with that by conventional method. The XRD data shown the crystal belongs to tetragonal tungsten bronze structure with space group P4bm. The grain size synthesized in millimeter wave field had smaller size, narrower distribution, better sinter-ability, and without hard agglomeration comparing whit that obtaining from conventional synthesis. At lower temperature Ba5LiTiNb9O30 is a tetragonal ferroelectric phase.
A high performance thermosetting epoxy resin crosslinkable at room temperature was obtained via directly moulding diglycidyl ether of bisphenol A(DGEBA) and flexibleα,ω-bisamino(n-alkylene)phenyl terminated poly...
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A high performance thermosetting epoxy resin crosslinkable at room temperature was obtained via directly moulding diglycidyl ether of bisphenol A(DGEBA) and flexibleα,ω-bisamino(n-alkylene)phenyl terminated poly(ethylene glycol).The influences of the n-alkylene inserted in aminophenyl of flexible amino-terminated polythers(ATPE) on the mechanical properties,fractographs and curing kinetics of the ATPE-DGEBA cured products were *** results show that the insertion of n-alkylene group into the aminophenyl group of the ATPE,on one hand,can significantly increase the strain relaxation rate and decrease glass transition temperature of the ATPE-DGEBA cured products,resulting in slight decrease of the Young’s modulus and tensile strength,and significant increase of the toughness and elongation of the ATPE-DGEBA cured *** the other hand,it can remarkably enhance the reactivity of amine with epoxy,much accelerating the curing rate of the ATPE-DGEBA *** activation energy of DGEBA cured by BAPTPE,BAMPTPE and BAEPTPE was 53.1,28.5 and 25.4 kJ·mol;,*** as-obtained ATPE-DGEBA cured products are homogeneous, transparent,and show excellent mechanical properties including tensile strength and *** they are promising to have important applications in structure adhesives,casting bulk materials,functional coatings,cryogenic engineering, damping and sound absorbing materials.
作者:
Pan YongJun潘勇军Xie HongQuan陈勇Chen Yong崔丽College of Material Science and Engineering
Wuhan Textile University Wuhan 430074 China 武汉纺织大学材料科学与工程学院 武汉 430073 Department of Chemistry Huazhong University of Science and Technology Wuhan 430074China 武汉理工大学复合材料国家重点实验室 武汉 430070 State key laboratory of advanced technology for materials synthesis and processingWuhan University of Technology Wuhan 430070 China
ZnO sub-millimeter crystals were synthesized by microwave heating from ZnO powders without any catalyst or transport agent. Zinc oxide raw materials were evaporated from the high-temperature zone in an enclosure and c...
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ZnO sub-millimeter crystals were synthesized by microwave heating from ZnO powders without any catalyst or transport agent. Zinc oxide raw materials were evaporated from the high-temperature zone in an enclosure and crystals were grown on the self-source substrate. The thermodynamics analysis method was used to estimate the partial pressure of gases in the chamber, which shows that the pressure of ZnO could be neglected entirely in the range of experiment temperature. The kinetics analysis was employed to estimate the growth rate in different conditions, which shows a remarkable temperature gradient and a high system temperature would enhance the growth rate. Optics photos reveal that these products are hexagon crystals with 0.2-0.3 mm in diameter and 0.5-1 mm in length. A vapor-solid mechanism is proposed to explain the growth process of ZnO crystals. The temperature distribution in microwave oven is mainly determined by properties of electric field and it is different from that of a conventional method.
Cr(N,O) thin films were deposited by radio frequency reactive unbalanced magnetron sputtering on Si(100) or glassy carbon substrates. In this paper, the influence of oxygen content on hardness of Cr(N,O) thin films wa...
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Cr(N,O) thin films were deposited by radio frequency reactive unbalanced magnetron sputtering on Si(100) or glassy carbon substrates. In this paper, the influence of oxygen content on hardness of Cr(N,O) thin films was investigated. The compositional analysis was carried out by Rutherford backscattering spectroscopy. It was found that these thin films contained up to 44at.% of oxygen. Phases in the samples were determined by X-ray diffraction. Cr(N,O) thin films show only peaks based on CrN. The microstructure was observed by utilizing a transmission electron microscope. At
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