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Achieving asymmetric redox chemistry for oxygen evolution reaction through strong metal-support interactions

Journal of Energy Chemistry 2024年第9期96卷 526-535页

作者： Shihao Wang Meiling Fan Hongfei Pan Jiahui Lyu Jinsong Wu Haolin Tang Haining Zhang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina National Energy Key Laboratory for New Hydrogen-Ammonia Energy Technologies Foshan Xianhu LaboratoryFoshan 528200GuangdongChina International School of Materials Science and Engineering(School of Materials and Microelectronics) Wuhan University of TechnologyWuhan 430070HubeiChina Nanostructure Research Centre Wuhan University of TechnologyWuhan 430070HubeiChina Hubei Key Laboratory of Fuel Cell Wuhan University of TechnologyWuhan 430070HubeiChina

Water electrolysis poses a significant challenge for balancing catalytic activity and stability of oxygen evolution reaction(OER)*** this study,we address this challenge by constructing asymmetric redox chemistry through elaborate surface OO–Ru–OH and bulk Ru–O–Ni/Fe coordination moieties within single-atom Ru-decorated defective NiFe LDH nanosheets(Ru@d-NiFe LDH)in conjunction with strong metal-support interactions(SMSI).Rigorous spectroscopic characterization and theoretical calculations indicate that single-atom Ru can delocalize the O 2p electrons on the surface and optimize d-electron configurations of metal atoms in bulk through ***^(18)O isotope labeling experiment based on operando differential electrochemical mass spectrometry(DEMS),chemical probe experiments,and theoretical calculations confirm the encouraged surface lattice oxygen,stabilized bulk lattice oxygen,and enhanced adsorption of oxygen-containing intermediates for bulk metals in Ru@d-NiFe LDH,leading to asymmetric redox chemistry for *** Ru@d-NiFe LDH electrocatalyst exhibits exceptional performance with an overpotential of 230 mV to achieve 10 mA cm^(−2)and maintains high robustness under industrial current *** approach for achieving asymmetric redox chemistry through SMSI presents a new avenue for developing high-performance electrocatalysts and instills confidence in its industrial applicability.

关键词： Reaction redox chemistry Strong metal-support interactions Layered double hydroxides Electrocatalysts Water electrolysis

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AI-driven material discovery for energy, catalysis and sustainability

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National Science Review 2025年第5期 77-78页

作者： Ning Han Bao-Lian Su Department of Electrical and Computer Engineering University of Toronto Laboratory of Inorganic Materials Chemistry(CMI) University of Namur State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology

Artificial intelligence (AI) is revolutionizing various sectors, including science,technology, industry and daily life [1,2].One key area where AI can make a significant impact is in material design, crucial for advan...

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Modification of sulfonated poly(arylene ether nitrile) proton exchange membranes by poly(ethylene-co-vinyl alcohol)

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RSC Advances 2023年第16期13卷 11062-11068页

作者： Liu, Hao Dong, Tiandu Zhou, Mingzheng Zhang, Zetian Li, Yunxi Lu, Chuanrui Liu, Yichen Zhao, Shengqiu Zheng, Shuhong Meng, Zihan Tang, Haolin State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology Wuhan430070 China State Power Investment Corporation Hydrogen Energy Company Ltd. Co. Beijing China

The modification of the physicochemical properties of sulfonated poly(arylene ether nitrile) (SPAEN) proton exchange membranes was demonstrated by poly(ethylene-co-vinyl alcohol) (EVOH) doping (named SPAEN-x%). By controlling the temperature during membrane preparation, the side reactions of the sulfonic acid groups to form sulfonic acid esters were effectively prevented, greatly reducing the proton conductivity of the membranes. Due to the flexible chain of EVOH, SPAEN-8% showed a relatively high elongation of 30.2%, which enhanced the aromatic polymers' flexibility. The SPAEN-2% membrane exhibited proton conductivity of 166, 55, and 9.6 mS cm−1 at 95%, 70%, and 50% relative humidity, respectively, higher than those of the other SPAEN-x% membranes and even comparable to that of Nafion 212. The water uptake, morphological study, and through-plane proton conductivity of the membranes were studied and discussed. The results suggest that EVOH doping can be used as an effective strategy to improve SPAEN-based proton exchange membranes' performance. © 2023 The Royal Society of Chemistry.

关键词： Membranes

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Mixed ion-electron conducting Li_(3)P for efficient cathode prelithiation of all-solid-state Li-ion batteries

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SmartMat 2023年第5期4卷 119-130页

作者： Jing Li Dan Liu Han Sun Deyu Qu Zhizhong Xie Haolin Tang Jinping Liu Department of Chemistry School of ChemistryChemical Engineering and Life ScienceWuhan University of TechnologyWuhanChina Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory FoshanChina State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhanChina

All-solid-state batteries(ASSBs)using sulfide electrolytes hold promise for next-generation battery *** using a pure Li metal anode is believed to maximize battery energy density,numerous recent studies have implicated that Li-ion anodes(e.g.,graphite and Si)are more realistic candidates due to their interfacial compatibility with sulfide ***,those Li-ion ASSBs suffer from an issue similar to liquid Li-ion batteries,which is a loss of active Li inventory owing to interfacial side reactions between electrode components,resulting in reduced available capacities and shortened cycle ***,for the first time,we explore the potential of Li_(3)P for cathode prelithiation of Li-ion *** identify that the crystallized Li_(3)P(c-Li_(3)P)has room-temperature ionic and electronic conductivities of both over 1o-4 s/*** a mixed ion-electron conduct-ing feature ensures that the neat c-LisP affords a high Li+-releasing capacity of 983 mAh/g in ASSBs during the first ***,the electro-chemical delithiation of c-LisP takes place below 2 V versus Li+/Li,while its lithiation dominates below 1 V versus Lit/*** used as a cathode prelithiation regent for ASSBs,c-Li_(3)P only functions as a Li+donor without lithiation activity and can adequately compensate for the Li loss with minimal dosage *** mitigating first-cycle Li loss,c-LisP prelithiation can also improve the battery cyclability by sustained release of low-dosage Li+ions in subsequent cycles,which have been embodied in several full ASSBs by coupling a LiCoO2 cathode with various types of anodes(including graphite,in foil,Sb,and Si anode).Our work provides a universal cathode prelithiation strategy for high-efficiency Li-ion AsSBs.

关键词： all-solid-state batteries cathode prelithiation Li_(3)P lithium-ion batteries mixed ion-electron conductor

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Size effect enabling additive-free MXene ink with ultrahigh conductivity for screen printing of wireless electronics

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Nano Research 2023年第8期16卷 11012-11017页

作者： Shuaishuai Chen Huaqiang Fu Yunfa Si Xueyu Liu Zhe Wang Yixue Duan Zixin Zhang Hao Feng Xin Zhao Daping He State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Engineering Research Center of RF-Microwave Technology and Application Wuhan University of TechnologyWuhan 430070China School of Science Wuhan University of TechnologyWuhan 430070China

Facile preparation of additive-free inks with both high viscosity and high conductivity is critical for scalable screen printing of wireless electronics,yet very *** materials exhibit excellent conductivity and hydrophilicity,showing great potential in the field of additive-free inks for screen ***,we demonstrate the synthesis of additive-free two-dimensional(2D)titanium carbide MXene inks,and realize screen-printed MXene wireless electronics for the first *** viscosity of MXene ink is solely regulated by tuning the size of MXene nanosheet without any additives,hence rendering the printed MXene film extremely high conductivity of 1.67×10^(5) S/m and fine printing resolution down to 0.05 mm on various flexible ***,radio frequency identification(RFID)tags fabricated using the additive-free MXene ink via screen printing exhibit stable antenna reading performance and superb *** article,thus offers a new route for the efficient,low-cost and pollution-free manufacture of printable electronics based on additive-free MXene inks.

关键词： size effect additive-free MXene ink screen printing wireless electronics radio frequency identification(RFID)

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Bioprocess-inspired Actin Biomineralized Hematite Mesocrystals for Energy Storage

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Journal of Wuhan University of technology(materials Science) 2023年第6期38卷 1299-1303页

作者： XU Wei ZHAO Chao XIE Jingjing WANG Rongjie Tianjin Institute of Power Sources Tianjin 300384China CETC LAN TIAN Technology Co. Ltd.Tianjin 300384China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

Biomineralization is a biological process of synthesizing inorganic minerals within *** has been found that intracellular proteins are involved in the room temperature synthesis process of anatase Ti O2in living ***,we used intracellular actin to synthesize hematite by *** hematite has a nano spindle structure with a particle size of approximately 150 *** microstructure indicates that the prepared hematite is a mesocrystals composed of ordered arrangement and assembly of primary *** addition,hematite mesocrystals exhibit good lithium storage performance as electrode materials for lithium *** discharge specific capacity of the battery remained at 560.7 m Ah·g^(-1)after 130 cycles at a current density of 200 m A·g^(-1).This work expands the synthesis methods of hematite by biomineralization,and provides a new strategy for preparing inorganic materials by intracellular proteins.

关键词： actin hematite biomineralization mesocrystals lithium battery

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Directly Unveiling the Photothermal Corrosion of BiVO4 via In-situ Transmission Electron Microscopy

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Chemical Research in Chinese Universities 2025年第2期41卷 351-357页

作者： WANG Lindong SUN Jingyi WANG Lang LI Yu HU Zhiyi SU Baolian State Key Laboratory of Advanced Technology for Materials Synthesis and Processing International School of Materials Science and Engineering(ISME)Wuhan University of TechnologyWuhan 430070P.R.China Nanostructure Research Centre(NRC) Wuhan University of TechnologyWuhan 430070P.R.China CMI(Laboratory of Inorganic Materials Chemistry) University of Namurrue deBruxelles 61B-5000NamurBelgium

BiVO4(BVO)is widely utilized in photothermal catalysis because of its favorable bandgap structure(2.4 eV),excellent photo response capabilities and high thermal ***,the mechanism of BVO photothermal corrosion still remains unclear due to the lack of visualized characterization on the degradation process in real ***,we directly unveil the photothermal-induced microstructural evolution of BVO through in-situ heating(scanning)transmission electron microscopy[(S)TEM].The results indicate that the electrons are the initiating condition(“switch”)for the photothermal corrosion of BVO,resulting in the precipitation of Bi and reduction of V5+to V3+in the substrate,while the thermal field facilitates the evaporation of Bi and the recrystallization of *** work sheds light on the mechanism of BVO photothermal corrosion in dynamics and provides significant insights into the photothermal synergistic effects.

关键词： BiVO4 Photothermal corrosion In-situ transmission electron microscopy(TEM) Photothermal catalysis Structural evolution

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Structural Evolution of Graphene Oxide and Its Thermal Stability During High Temperature Sintering

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Journal of Wuhan University of technology(materials Science) 2022年第3期37卷 342-349页

作者： HU Lanxin WANG Aiyang WANG Weimin School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The thermal reduction of graphene oxide(GO)was performed by a tube furnace at different temperatures,and its structure evolution was investigated in *** results showed that the oxygen-containing functional groups on the carbon plane surface of GO gradually decomposed as the temperature increase,and the reduced graphene oxide(rGO)powder was obtained at 800℃.Then,rGO powder was sintered under 30 MPa at 1800℃using spark plasma sintering(SPS)and hot-pressing(HP)to evaluate its structural stability at high *** defect densities of rGO were reduced after high-temperature *** edge flatness and sp^(2) hybrid carbon plane structure were reconstructed *** results demonstrate that the lamellar structure of rGO maintains the structural integrity during high-temperature sintering without obvious deterioration,which provides experimental and theoretical supports for GO reinforced ceramics.

关键词： graphene oxide ceramics structure evolution thermal stability sintering

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Nonflammable electrolyte with weak-solvation structure for stable NCM811 cathode under high temperature

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Journal of Energy Chemistry 2025年第5期104卷 111-117页

作者： Dawei Xu Chao Yang Ailing Yang Xiaowei Liu Meilong Wang Jin Han Tiefeng Liu Ya You State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina International School of Materials Science and Engineering School of Materials Science and MicroelectronicsWuhan University of TechnologyWuhan 430070HubeiChina College of Chemical and Biological Engineering Zhejiang UniversityHangzhou 310058ZhejiangChina Quzhou Institute of Power Battery and Grid Energy Storage Quzhou 324000ZhejiangChina

High-nickel cathode LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811)could enable lithium-ion batteries(LIBs)with high energy ***,excessive decomposition of the electrolyte would happen in the high operating voltage *** addition,the utilization of flammable organic solvents would increase safety risks in the high temperature ***,an electrolyte consisting of flame-retardant solvents with lower highest occupied molecular orbital(HOMO)level and LiDFOB salt is proposed to address above two *** a result,a thin and robust cathode-electrolyte interface containing rich LiF and Li-B-O compounds is formed on the cathode to effectively suppress electrolyte decomposition in the high operating *** NCM811||Li cell paired with this designed electrolyte possesses a capacity retention of 72%after 300 cycles at 55℃.This work provides insights into developing electrolyte for stable high-nickel cathode operated in the high temperature.

关键词： Electrolyte engineering Weak solvation High temperature Safety High-nickel cathode

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Surface repair of wide-bandgap perovskites for high-performance all-perovskite tandem solar cells

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Journal of Energy Chemistry 2024年第6期93卷 64-70,I0003页

作者： Xiaojing Lv Weisheng Li Jin Zhang Yujie Yang Xuefei Jia Yitong Ji Qianqian Lin Wenchao Huang Tongle Bu Zhiwei Ren Canglang Yao Fuzhi Huang Yi-Bing Cheng Jinhui Tong State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina Key Lab of Artificial Micro-and Nano-Structures of Ministry of Education of China School of Physics and TechnologyWuhan UniversityWuhan 430072HubeiChina Department of Electrical and Electronic Engineering Photonics Research Institute(PRI)Research Institute for Intelligent Wearable Systems(iWEAR)The Hong Kong Polytechnic University999077Hong KongChina Laboratory of Advanced Materials Fudan UniversityShanghai 200438China Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan 528200GuangdongChina

Wide-bandgap(WBG)perovskite solar cells(PSCs)play a fundamental role in perovskite-based tandem solar ***,the efficiency of WBG PSCs is limited by significant open-circuit voltage losses,which are primarily caused by surface *** this study,we present a novel method for modifying surfaces using the multifunctional S-ethylisothiourea hydrobromide(SEBr),which can passivate both Pb^(-1)and FA^(-1)terminated surfaces,Moreover,the SEBr upshifted the Fermi level at the perovskite interface,thereby promoting carrier *** proposed method was effective for both 1.67 and 1.77 eV WBG PSCs,achieving power conversion efficiencies(PCEs)of 22.47%and 19.90%,respectively,with V_(OC)values of 1.28 and 1.33 V,along with improved film and device *** this advancement,we were able to fabricate monolithic all-perovskite tandem solar cells with a champion PCE of 27.10%,This research offers valuable insights for passivating the surface trap states of WBG perovskite through rational multifunctional molecular engineering.

关键词： Wide-bandgap perovskite Surface defect Multifunctional molecule All-perovskite tandem solar cells

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