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Ultrafast Laser Irradiation Induced Oxidation of Dopant-Free Spiro-OMeTAD for Improving the Perovskite Solar Cells Performance

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Energy & Environmental materials 2025年第2期8卷 284-290页

作者： Jiaqi Meng Xiangyu Chen Weihan Li Nianyao Chai Zhongle Zeng Yunfan Yue Fengyi Zhao Xuewen Wang Center of Femtosecond Laser Manufacturing for Advanced Materials and Devices State Key Laboratory of Advanced Technology for Materials Synthesis and ProcessingWuhan University of TechnologyWuhan 430070China School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China International School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China National Energy Key Laboratory for New Hydrogen-Ammonia Energy Technologies Foshan Xianhu LaboratoryFoshan 528000China

The exceptional photoelectric performance and high compatibility of perovskite materials render perovskite solar cells highly promising for extensive development,thus garnering significant *** perovskite solar cells,the hole transport layer plays a crucial *** the commonly employed organic small molecule hole transport material Spiro-OMeTAD,a certain period of oxidation treatment is required to achieve complete transport ***,this posttreatment oxidation processes typically rely on ambient oxidation,which poses challenges in terms of precise control and leads to degradation of the perovskite light absorption *** approach fails to meet the demands for high efficiency and stability in practical ***,the mechanism of ultrafast laser on Spiro-OMeTAD and the reaction process for laser-induced oxidation of it are ***2 at Perovskite/Spiro-OMeTAD interface breaks down to produce I2 upon ultrafast laser irradiation and I2 promote the oxidation *** the laser irradiation oxidation processing,a higher stability of perovskite solar cells is *** work establishes a new approach toward oxidation treatment of Spiro-OMeTAD.

关键词： hole transport layer perovskite solar cells ultrafast laser irradiation undoped Spiro-OMeTAD

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Ionic liquids-assisted in-situ targeted defect-healing strategy for high-performance sprayed perovskite modules

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Journal of Energy Chemistry 2025年第5期104卷 756-764页

作者： Jize Wang Xinxin Yu Cong Geng Wangnan Li Ying Liang Bin Li Yong Peng Yi-Bing Cheng State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070HubeiChina Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang 441053HubeiChina Hubei Longzhong Laboratory Wuhan University of Technology(Xiangyang Demonstration Zone)Xiangyang 441000HubeiChina

In the process of spraying coating perovskite films,the"coffee ring"effect(CRE)leads to the problem of excessive organic ammonium salt accumulation in local areas that cannot be completely *** introduce an in-situ targeted defect-healing strategy by incorporating butylamine formate(BAFa)ionic liquid into the spray *** liquids,due to their long carbon chain structure,tend to target flow towards the CRE region during the droplet evaporation *** coordination between the lone pair electrons in the C=O group of BAFa and Pb^(2+)effectively reduces defects in perovskite and suppresses non-radiative recombination ***,amine ligands,which are repelled to the film surface and grain boundaries,form a thin insulating monolayer in the CRE areas,forcing charge carriers to transport through areas of the perovskite with fewer *** approach enables the crystallization control and defect-heal over the Cs_(0.19)FA_(0.81)PbI_(3-x-y)Br_(x)Cl_(y)perovskite ***,the champion perovskite solar cell achieved a power conversion efficiency of 22.04%,while mini-modules with an effective area of 64.8 cm^(2)reached a peak power conversion efficiency of 18.35%,demonstrating the significant potential for commercializing large-area perovskite solar cells.

关键词： Ion liquid Spray-coating Perovskite solar cell "Coffee-ring"effect Targeted defect-healing

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An artificial interphase enables stable PVDF-based solid-state Li metal batteries

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Nano Research 2024年第3期17卷 1482-1490页

作者： Mengjun Wu Jiangping Song Jiaheng Lei Haolin Tang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Department of Chemistry School of ChemistryChemical Engineering and Life SciencesWuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan 528200China

Composite polymer electrolytes(CPEs)have attracted much attention for high energy density solid-state lithium-metal batteries owing to their flexibility,low cost,and easy ***,the unstable Li/CPE interface is always challengeable for the practical utilization of ***,a polymer interlayer containing K+prepared by ultraviolet(UV)-curing precursor solution is coated on Li surface to stabilize the interface between poly(vinylidene difluoride)(PVDF)composite electrolytes and Li *** from the physical barrier of the interlayer,the continuous decomposition of PVDF is restrained and the intimate contact between electrode and electrolyte is also achieved to reduce the interface ***,the added K+is utilized to further regulate smooth Li *** a consequence,the symmetric Li|Li cell with coated Li demonstrates steady cycling at 0.4 mAh·cm^(-2) and a high critical current density of 1 mA·cm^(-2).The assembled Li|LiFePO_(4) cell presents outstanding cycling stability(capacity retention of 90%after 400 cycles at 1 C)and good rate *** associated pouch cell performs impressive flexibility and *** work provides a convenient strategy to achieve stable Li/PVDF interface for high-performance PVDF-based solid state Li metal batteries.

关键词： interfacial modification solid-state batteries composite polymer electrolytes interfacial compatibility lithium dendrite

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Preparation of Co/CoOx Derived from a Lowtemperature Etching of ZIF-67 for Oxygen Reduction and Oxygen Evolution Catalytic Reaction

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Journal of Wuhan University of technology(materials Science) 2023年第6期38卷 1255-1261页

作者： TAN Shifeng TU Wenmao PAN Hongfei ZHANG Haining State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Key Laboratory of Fuel Cells Wuhan University of TechnologyWuhan 430070China Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Foshan 528200China

Catalysts consisting of Zeolite imidazolyl ester skeleton-67(ZIF-67)and graphene oxide(GO)were fabricated through a solvothermal method,followed by etching ZIF-67 with oxygen-rich functional groups on GO in a reduction atmosphere at 400℃.During this process,an open type of cobalt metal center was formed by the partial vaporization and oxidation of ZIF-67,further reducing to Co and partially combining with oxygen species to amorphous *** from the rich functional N,and metal/oxides active centers derived from the calcination process,the synthesized Co/CoOx@NSG-400 showed a low OER overpotential of 10 mA·cm^(-2) at 298 mV,and an ORR half-wave potential of 0.8 V,which demonstrated its excellent bifunctional catalytic *** a controllable calcination strategy with high yields could be expected to pave the way for synthesizing low-cost and efficient bifunctional electrocatalysts.

关键词： oxygen evolution reaction oxygen reduction reaction bifunctional electrocatalyst ZIF-67

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A double-network porous hydrogel based on high internal phase emulsions as a vehicle for potassium sucrose octasulfate delivery accelerates diabetic wound healing

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Regenerative Biomaterials 2024年第4期3卷 82-97页

作者： Zhiwei Wang Lingshun Sun Weixing Wang Zheng Wang Ge Shi Honglian Dai Aixi Yu Department of Orthopedics Trauma and Microsurgery Zhongnan Hospital of Wuhan UniversityWuhan 430070China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Biomedical Materials and Engineering Research Center of Hubei ProvinceWuhan University of TechnologyWuhan 430070China

Diabetic wounds are a difficult medical *** secretion of matrix metalloproteinase-9(MMP-9)in diabetic wounds further degrades the extracellular matrix and growth factors and causes severe vascular damage,which seriously hinders diabetic wound *** solve these issues,a double-network porous hydrogel composed of poly(methyl methacrylate-co-acrylamide)(p(MMA-co-AM))and polyvinyl alcohol(PVA)was constructed by the high internal phase emulsion(HIPE)technique for the delivery of potassium sucrose octasulfate(PSO),a drug that can inhibit MMPs,increase angiogenesis and improve *** hydrogel possessed a typical polyHIPE hierarchical microstructure with interconnected porous morphologies,high porosity,high specific surface area,excellent mechanical properties and suitable swelling ***,the p(MMA-co-AM)/PVA@PSO hydrogel showed high drug-loading performance and effective PSO *** addition,both in vitro and in vivo studies showed that the p(MMA-co-AM)/PVA@PSO hydrogel had good biocompatibility and significantly accelerated diabetic wound healing by inhibiting excessive MMP-9 in diabetic wounds,increasing growth factor secretion,improving vascularization,increasing collagen deposition and promoting ***,this study provided a reliable therapeutic strategy for diabetic wound healing,some theoretical basis and new insights for the rational design and preparation of wound hydrogel dressings with high porosity,high drug-loading performance and excellent mechanical properties.

关键词： high internal phase emulsions double-network porous hydrogel drug delivery diabetic wound healing sucrose octasulfate

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Titanium nitrides as novel reactants for in-situ synthesis of TiB_(2)-based composites with improved properties

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Journal of materials Science & technology 2023年第14期145卷 48-55页

作者： Ji Zou Huayue Liang Jingjing Liu Weimin Wang Fan Zhang Wei Ji Zhengyi Fu State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China Hubei Longzhong Laboratory Xiangyang 441000China School of Materials Science and Engineering Wuhan University of TechnologyWuhan 430070China

A novel in-situ reactive approach based on the reactions among TiN,aluminum and boron has been developed to synthesize TiB_(2)-based composites including TiB_(2)-h BN(TB)and TiB_(2)-h BN-AlN(TBA).Fully dense ceramics with fine-grained microstructure were successfully obtained via spark plasma sintering at 1850℃/60 MPa/5 *** analysis suggests h BN flakes were homogenously distributed in the TiB_(2)*** AlN,however,they were elongated into plate-like grains during sintering,in which lots of defects in terms of stacking faults and twinning structures were *** mechanical and thermophysical properties of as-sintered ceramics were comprehensively investigated and ***-corporating AlN significantly improved the flexure strength,hardness,fracture toughness and thermal conductivity of TiB_(2)-h BN *** electrical conductivity of TB(3.06×10^(6)S/m)is larger than that of TBA(2.35×10^(6)S/m)at room temperature,but the value(6×10^(5)S/m)was lower than that of TBA(6.9×10^(5)S/m)at 1173 *** on the measurement of electrical and thermal conductivity,electron and phonon contributions to thermal conductivities of TB and TBA were calculated and their temperature dependences were illustrated.

关键词： Borides Microstructure Spark plasma sintering Mechanical property Thermo-physics property

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Enhanced thermoelectric and mechanical properties of Bi_(0.5)Sb_(1.5)Te_(3) alloy with dispersed yttrium oxide ceramic nanoparticles

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Rare Metals 2024年第4期43卷 1758-1768页

作者： Cun-Cheng Li Ming-Wei Zhang Ji-Wu Xin Lei Wei Wen-Yu Zhao School of Materials Science and Engineering Shandong University of TechnologyZibo255000China School of Electrical and Electronic Engineering Nanyang Technological UniversitySingapore639798Singapore State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan430070China

Reducing thermal conductivity while avoiding adverse interfacial reactions during sintering is crucial for improving the thermoelectric performance of Bi_(2)Te_(3)based *** ceramic nanoparticles are good candidates for achieving this *** this study,we designed and prepared a series of p-type Bi_(0.5)Sb_(1.5)Te_(3)nanocomposites decorated with Y_(2)O_(3)ceramic nanoparticles via ball-milling dispersion and spark-plasma *** to the chemical stability of the ceramics,no traces of atomic doping or interfacial reactions were *** measurements revealed that the Y_(2)O_(3)nanoparticles distributed along the grain boundaries acted as energy-dependent carrier-filtering centers to improve the scattering parameter and Seebeck coefficient,contributing to the elevated power factor even with a decreased electrical ***,the incorporated Y_(2)O_(3)nanoparticles and various defect structures they induced effectively strengthened the phonon scattering and suppressed the lattice thermal ***,a peak figure of merit(ZT)of 1.23 at 313 K was achieved for 0.4%Y_(2)O_(3)/Bi_(0.5)Sb_(1.5)Te_(3),which is 13%higher than that of the *** addition,the Vickers hardness of the composite material was 35%higher than that of the *** study demonstrates the effectiveness of ceramic nanoparticles in synergistic ally improving the thermoelectric and mechanical properties,which may be further extended to other thermoelectric systems.

关键词： Bi_(0.5)Sb_(1.5)Te_3 alloy Y_(2)O_(3) ceramic nanoparticles Microstructures Thermoelectric performance Mechanical properties

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Molecular Engineering of g-C_(3)N_(4)with Dibenzothiophene Groups as Electron Donor for Enhanced Photocatalytic H_(2)-Production

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Chinese Journal of Structural Chemistry 2022年第6期41卷 48-54页

作者： Shanren Tao Sijie Wan Qinyang Huang Chengming Li Jiaguo Yu Shaowen Cao State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The construction of donor-acceptor(D-A)molecular structure is an attractive strategy to enhance the photocatalytic performance of polymeric ***,dibenzothiophene(DBT)-4-carbaldehyde as the precursor is introduced into g-C_(3)N_(4)(TCN)prepared by two-step thermal polymerization to construct an intramolecular D-A type copolymer(TCN-DBT_(x)).DFT calculation and experimental results reveal that DBT plays the role of electron donor unit to modify g-C_(3)N_(4).The incorporation of DBT not only adjusts the band gap to improve reduction ability,but also induces an internal electric field with extendingπ-conjugated system for effective charge *** a result,TCN-DBT_(x)exhibits much better photocatalytic performance with an optimal hydrogen production rate of 3334μmol h^(-1)g^(-1),which is 2.5 times that of *** work provides a protocol for preparing high-performance g-C_(3)N_(4)-based photocatalysts toward various applications.

关键词： carbon nitride donor-acceptor photocatalysis charge transfer

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Eu3+ doped hydroxyapatite nanowires enabling solid-state electrolytes with enhanced ion transport

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Journal of materials Science & technology 2024年第19期186卷 104-109页

作者： Xiaoyue Wang Hong Zhang Lin Xu Liqiang Mai State Key Laboratory of Advanced Technology for Materials Synthesis and Processing School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China Hubei Longzhong Laboratory Wuhan University of Technology(Xiangyang Demonstration Zone)Xiangyang 441000China Hainan Institute Wuhan University of TechnologySanya 572000China

The polymer-based solid-state electrolytes (PSEs) are promising for solid-state batteries but they have deficiencies such as low ionic conductivity, low lithium-ion transference number, and unstable electrode/electrolyte interface. Herein, we designed a hydroxyapatite nanowire doped with high-valence cations in anticipation of the formation of positively charged active sites on the nanowire surface. The higher surface activity can reduce the reaction activation energy on the nanowire surface and adsorb the anions in the PSEs as a way to improve the ionic conductivity and Li+ transference number of the PSEs. The active sites on the surface of the nanowires anchor the anions, thus increasing the Li+ transference number to 0.38, which effectively improves the ionic conductivity of the PSE to 1.58 × 10-4 S cm-1 at room temperature. At the same time, the composite polymer electrolyte has a wide electrochemical window. The lithium symmetric cell stably cycles for 800 h at a current density of 0.1 mA cm-2, and the LiFePO4||Li full cell steadily cycles for 180 cycles at a rate of 0.5 C with a capacity retention of 94.2 %. The ion doping strategy to change the surface electrical behavior of nanowires provides an idea to improve the ionic conductivity of solid-state electrolytes.

关键词： Nanowires Ion doping Active site Polymer-based solid-state electrolyte

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Microstructure and Mechanical Property of (TiNbTaZrHf)C Synthesized by In-situ Reaction

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Journal of Wuhan University of technology(materials Science) 2022年第2期37卷 177-183页

作者： ZHOU Qing ZHANG Jinyong FU Zhengyi WANG Dangqiang State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070China

The(TiNbTaZrHf)C high entropy carbide(HEC)was successfully synthesized by complete commercial transition metal powders,obtained fine sintered bulks without additives by in-situ reaction element synthesis method.(TiNbTaZrHf)C bulk shows a face centered cubic rock salt structure with homogeneous single-phase FCC structure in composition and *** optimum sintering temperature is about 1900℃at which the best mechanical properties are *** mechanical properties of(TiNbTaZrHf)C ceramic block are better than those of binary transition metal carbides,and it has obvious high entropy *** a small amount of Al as sintering additive,the mechanical properties of(TiNbTaZrHf)C ceramics continue to improve,the bending strength of the samples at each temperature is increased by at least 38%,and the highest is 486 *** elastic modulus and hardness of the sample at 1900℃are also slightly increased by 4%and 14%,*** above conclusions illustrate that the properties of high entropy ceramics are greatly improved by in-situ reaction sintering.

关键词： high entropy carbide in-situ reaction microstructure mechanical property sintering additive

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