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A bi-functional catalyst strategy to selectively regulate sulfur redox kinetics in lithium-sulfur batteries

Journal of Materials Science & technology 2024年第6期173卷 54-62页

作者： Yanan Liu Xiaoxiao Huang Honglei Zhang Guangyu Qin Xiaoshuang Wang Meixiu Song Hongbo Liang Jingzhe Hong Yudong Huang State Key Laboratory of Advanced Welding and Joining Harbin Institute of TechnologyHarbin 150001China MIIT Key Laboratory of Advanced Structural-Functional Integration Materials&Green Manufacturing Technology Harbin Institute of TechnologyHarbin 150001China School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001China School of Chemistry and Chemical Engineering Harbin Institute of TechnologyHarbin 150001China

Designing electrochemical catalysts has become a research hotspot due to their accelerating the polysulfide conversion of the sulfur cathode to inhibit the“shuttle effect”in lithium-sulfur ***,it is still a great challenge to design the heterogeneous selective electrochemical catalyst for inhibiting the“shuttle effect”.Herein,nickel cobalt phosphide and cobalt phosphide as the heterogeneous catalyst active sites embedded in the nitrogen-doped hollow carbon nanocages(NiCoP@CoP/NC)are reported,used for multi-step and multi-phase sulfur electrode reaction,and it is found that metal-sulfur d-p hybridization can effectively indicate the intrinsic catalytic activity of metal *** of labor and cooperation of the bi-active NiCoP@CoP as heterogeneous catalysts propel the stepwise polysulfide *** and CoP sites preferentially accelerate the long-chain polysulfide conversion reaction(S_(8)■LiPSs)and the short-chain polysulfide conversion reactions(LiPSs■Li_(2)S),***,the hollow and porous N-doped carbon structure can successfully suppress the volume effect and improve the conductivity of the sulfur *** unique design can obtain an effective inhibition of the shuttle effect and rapid electrode *** a result,Li-S batteries demonstrate a high initial capacity of 1063 mAh g^(-1) and a low-capacity decay of 0.04% per cycle within 1000 *** work provides a feasible idea for the design of host materials in Li-S batteries.

关键词： Shuttle effect d-p hybridization Heterogeneous catalysts Stepwise polysulfide conversion

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Electrochemical sensor for dopamine detection based on multiwalled carbon nanotube/molybdenum disulfide quantum dots with machine learning integration and anti-interference capability

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Tungsten 2025年第1期7卷 137-151页

作者： Geethukrishnan Onkar Apte Kiran Kumar Tadi Energy Electrodics and Electrocatalysis (EEE) Lab Department of Chemistry School of Advanced Sciences Vellore Institute of Technology School of Computer Science and Engineering Vellore Institute of Technology

The precise detection and measurement of dopamine（DA）,a crucial neurotransmitter in the human body,plays a significant role in diagnosing,preventing,and treating neurological diseases associated with its levels.A highly sensitive DA electrochemical sensor was constructed by combining molybdenum disulfide quantum dots（MSQDs） with multiwalled carbon nanotubes（MWCNTs）.The MSQDs were synthesized using the shear exfoliation *** sensors consist of MSQDs with Mo-S edge catalytic centers for the DA redox reaction,and MWCNTs amplify the sensor *** linearity of the sensor for the detection of DA was tested in the presence of ascorbic acid(AA,50 μmol·L-1) and uric acid(UA,200 μmol·L-1),and exhibited linearity from 2 to 966 μmol·L-1of DA with 0.097 μA(mol·L-1)-1sensitivity and a low limit of detection of0.6 μmol·L-1（the ratio between signal and noise,S/N=3）.Moreover,the sensitivity and selectivity of the sensor were also studied using *** is no increase in amperometric current after adding the most potentially interfering *** sensor was successfully applied to recover DA in human blood sera ***,machine learning algorithms were operated to aid in the near-precise detection of DA in the heterogeneous mixture containing AA and *** algorithms facilitate the identification and quantification of DA amidst coexisting interferents,including AA,that are commonly present in biological matrices.

关键词： Dopamine MoS_2 Biosensor Multiwalled carbon nanotubes Machine learning Complex mixture

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BPFGuard: Multi-Granularity Container Runtime Mandatory Access Control

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IEEE Transactions on Cloud Computing 2025年第2期13卷 629-640页

作者： Lu, Hui Du, Xiaojiang Hu, Dawei Su, Shen Tian, Zhihong Guangzhou University Cyberspace Institute of Advanced Technology China Stevens Institute of Technology Electrical and Computer Engineering China Guangzhou University China

The adoption of container-based cloud computing services has been prevalent, especially with the introduction of Kubernetes, which enables the automated deployment, scaling, and administration of applications in containers, hence boosting the popularity of containers. As a result, researchers have placed greater emphasis on container runtime security, notably investigating the efficacy of traditional techniques such as Capabilities, Seccomp, and Linux security modules in guaranteeing container security. However, due to the limitations imposed by the container environment, the results have been unsatisfactory. In addition, eBPF-based solutions face the problem of being unable to quickly load policies and affect real-time operations when faced with newer kernel vulnerabilities. This paper investigates the limitations of existing container security mechanisms. Additionally, it examines the specific constraints of these mechanisms in Kubernetes environments. The paper classifies container monitoring and obligatory access control into three distinct categories: system call access control, LSM hook access control, and kernel function access control. Therefore, we propose a technique for regulating container access with a variety of granularity levels. This technique is executed using eBPF and is tightly integrated with Kubernetes to collect relevant meta-information. In addition, we suggest implementing a consolidated routing method and employing function tail call chaining to overcome the limitation of eBPF in enforcing mandatory access control for containers. Lastly, we conducted a series of experiment to verify the effectiveness of the system's security using CVE-2022-0492 and to benchmark the system that had BPFGuard enabled. The results indicate that the average performance loss increased merely by 2.16%, demonstrating that there are no adverse effects on the container services. This suggests that greater security can be achieved at a minimal cost. © 2013 IEEE.

关键词： Real time control

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High performance of Mg_(3)Bi_(1.5)Sb_(0.5) based materials for power generation:Revealing the counter-intuitive effect of tuning Bi content on the thermoelectric properties

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Journal of Magnesium and Alloys 2024年第11期12卷 4538-4546页

作者： Nuo Qu Yuke Zhu Jianbo Zhu Kuai Yu Fengkai Guo Zihang Liu Qian Zhang Wei Cai Jiehe Sui State Key Laboratory of Advanced Welding and Joining Harbin Institute of TechnologyHarbin 150001China School of Materials Science and Engineering Harbin Institute of TechnologyHarbin150001China Department of Materials Science and Engineering Harbin Institute of TechnologyShenzhen 518055China

Recently,Mg_(3)Sb_(2)-xBixalloys have attracted intensive attention,with the aim of maximizing the electrical transport performance via donor element doping,increasing the grain size,as well as electronic band structure ***,less attention has been paid to other significant factors,like how these intrinsic point defects and accompanied secondary phases influence thermoelectric *** this study,the microstructure and thermoelectric transport properties of Mg_(3.2)Sb_(0.5)Bi_(1.495-x)Te_(0.005)(x=0~0.2)compounds were systematically investigated,where tuning the Bi content shows the counter-intuitive impact on the thermoelectric *** was found that the Bipoor environment associated with Bi impurities facilitated the increment of cation vacancy formation energy and then increased the carrier concentration,leading to the enhancement of power ***,the reduction of Bi-rich second phase content weakened the carrier scattering by grain boundaries whereas high carrier mobility was ***,the bipolar thermal conductivity decreased obviously due to the increased majority carrier concentration to suppress the intrinsic *** synergistic optimization pushes the average ZT value(300-573 K)up to 0.95 in the Mg_(3.2)Sb_(0.5)Bi_(1.295)Te_(0.005)***,the calculated single-leg conversion efficiency is increased up to 9.7%with the hot-side temperature of 573 K,as the record-high value in this system.

关键词： Mg_(3)Sb_(2)-xBix alloys Nanoscale Bi-rich phase Bipolar thermal conductivity Thermoelectric performance

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Radiationless optical modes in metasurfaces:recent progress and applications

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Light(Science & Applications) 2024年第9期13卷 1720-1740页

作者： Naseer Muhammad Zhaoxian Su Qiang Jiang Yongtian Wang Lingling Huang School of Optics and Photonics Beijing Engineering Research Center of Mixed Reality and Advanced DisplayBeijing Institute of TechnologyBeijing 100081ChinaBeijing 100081China Beijing Engineering Research Center of Mixed Reality and Advanced Display Beijing Institute of TechnologyBeijing 100081China

Non-radiative optical modes attracted enormous attention in optics due to strong light confinement and giant Q-factor at its spectral *** destructive interference of multipoles leads to zero net-radiation and strong field *** radiationless states disappear in the far-field,localize enhanced near-field and can be excited in *** the other hand,the optical modes turn out to be completely confined due to no losses at discrete point in the radiation continuum,such states result in infinite Q-factor and *** radiationless states provide a suitable platform for enhanced light matter interaction,lasing,and boost nonlinear processes at the state *** modes are widely investigated in different material configurations for various applications in both linear and nonlinear metasurfaces which are briefly discussed in this review.

关键词： optical lasing optics

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ZIF-8 modified by isocyanate as a photocatalytic antibacterial agent

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Rare Metals 2024年第6期43卷 2708-2718页

作者： Yi-Ning Zhang Zhen Pei Zi-Hao Wang Chong-En Wang Fen-Fen Liang Li-Qiao Wei College of Architecture Taiyuan University of TechnologyTaiyuan 030024China Key Laboratory of Interface Science and Engineering in Advanced Materials of Taiyuan University of Technology Ministry of EducationTaiyuan 030024China Department of Materials Science and Engineering Shanxi Institute of TechnologyYangquan 045000China Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Taiyuan 030000China

Zeolite imidazole skeleton(ZIF-8)is a promising option for self-cleaning of building exterior walls due to its large specific surface area,high antibacterial activity and low ***,it suffers from low antibacterial efficiency and yield under visible light *** address the issues,we developed the photocatalytic materials T-ZIF-8-TDI(thermally treated-ZIF-8-toluene 2,4-diisocyanate)by modifying ZIF-8 with thermal oxygen sensitization and chemical *** results show that the yield of T-ZIF-8-TDI photocatalytic antibacterial agent is increased to 11.5 times of that of T-ZIF-8,while maintaining the crystal structure of T-ZIF-8 and thermal stability up to 60℃.Furthermore,T-ZIF-8-TDI exhibits extended optical response range to the nearinfrared region,significantly narrowed band gap,improved photogenerated elec tron-hole separation efficiency,reduced recombination rate,and excellent photocatalytic *** the concentration of antibacterial agent is 600 mg·L^(-1),the antibacterial rate of Escherichia coli(***)reaches 99.99%irradiated by visible light for30 min,and when the concentration of antibacterial agent is 200 mg·L^(-1),the antibacterial rate of Staphylococcus aureus(***)reaches 99.99%irradiated by visible light for 25 *** also analyzed the reasons in detail from the aspects of bacterial species and antibacterial mechanism,and proposed the antibacterial mechanism of·O_(2)^(-)and h^(+)as the main active *** findings suggest that T-ZIF-8-TDI photocatalytic antibacterial agent has potential for use in self-cleaning of building exterior walls.

关键词： ZIF-8 Hot oxygen sensitization Modified by isocyanate Antimicrobial performance Photocatalytic antibacterial mechanism

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High-entropy sulfides enhancing adsorption and catalytic conversion of lithium polysulfides for lithium-sulfur batteries

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Journal of Energy Chemistry 2025年第3期102卷 263-270页

作者： Yating Huang Jiajun Wang Wei Zhao Lujun Huang Jinpeng Song Yajie Song Shaoshuai Liu Bo Lu School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001HeilongjiangChina School of Chemistry and Chemical Engineering Harbin Institute of TechnologyHarbin 150001HeilongjiangChina Stake Key Laboratory of Advanced Welding and Joining Harbin Institute of TechnologyHarbin 150001HeilongjiangChina

Lithium-sulfur(Li-S)batteries with high energy density suffer from the soluble lithium polysulfide species,Traditional metal sulfides containing a single metal element used as electrocatalysts for Li-S batteries commonly have limited catalytic abilities to improve battery ***,based on the Hume-Rothery rule and solvothermal method,the high-entropy sulfide NiCoCuTiVS_(x)derived from Co_(9)S_(8)was designed and synthesized,to realize the combination of small local strain and excellent catalytic *** all five metal elements(Ni,Co,Cu,Ti,and V)capable of chemical interactions with soluble polysulfides,NiCoCuTiVS_(x)exhibited strong chemical confinement of polysulfides and promoted fast kinetics for polysulfides ***,the S/NiCoCuTiVS_(x)cathode can maintain a high discharge capacity of 968.9 mA h g^(-1)after 200 cycles at 0.5 C and its capacity retention is 1.3 times higher than that of S/Co_(9)S_(8).The improved cycle stability can be attributed to the synergistic effect originating from the multiple metal elements,coupled with the reduced nucleation and activation barriers of Li_(2)*** present work opens a path to explore novel electrocatalyst materials based on high entropy materials for the achievement of advanced Li-S batteries.

关键词： High-entropy sulfides Hume-Rothery rule Polysulfides adsorption Cycle stability Lithium-sulfur batteries

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Taming of trinitromethyl-oxadiazole to access high density and high oxygen balance via a dual modulation strategy

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Defence technology(防务技术) 2025年第1期43卷 142-149页

作者： Jinya Zhang Teng Fei Jingwei Meng Jinxiong Cai Lei Zhang Siping Pang Chunlin He School of Materials Science&Engineering Beijing Institute of TechnologyBeijing 100081China Experimental Center of Advanced Materials School of Materials Science&EngineeringBeijing Institute of TechnologyBeijing 100081China hongqing Innovation Center Beijing Institute of TechnologyChongqing 401120China

Energetic compounds bearing the trinitromethyl group are garnering broad attraction as potential candidates for a new generation of high energy dense *** this work,an effective dual modulation strategy involving both molecular isomerization and crystal morphology control was employed to design and optimize trinitromethyl-oxadiazole with improved comprehensive *** this dual strategy,3,5-bis(trinitromethyl)-1,2,4-oxadiazole(3)was synthesized,resulting in the formation of two distinct crystal morphologies(needle and sheet)corresponding to two crystal forms(3-a and3-b).Encouragingly,while maintaining ultra-high oxygen balance(21.73%),3 achieves impressive densities(1.97-1.98 g/cm^(3)).To our knowledge,the density of 1.98 g/cm^(3)for 3-a sets a new record among that of nitrogen-rich monocyclic ***,practical crystal morphology prediction was creatively introduced to guide the experimental crystallization conditions of 3,increasing the impact sensitivity and friction sensitivity from 1 J to 80 N(3-a)to 10 J and 240 N(3-b),***,the crystal structural analyses and theoretical calculations were conducted to elucidate the reasons of differences between 3-a and 3-b in density and *** work provides an efficient strategy to enhance performance of trinitromethyl derivatives,broadening the path and expanding the toolbox for energetic materials.

关键词： Energetic materials High oxygen balance High density Dual modulation Trinitromethyl group

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Synergistic improvement of strength and ductility via doping cerium into PH13-8Mo stainless steel by laser powder bed fusion

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Journal of Materials Science & technology 2024年第7期174卷 106-119页

作者： Chang Liu Jianxiong Liang Changjun Wang Gang Chen Xuanhui Qu Yu Liu Zhenbao Liu Mengxing Zhang Central Iron&Steel Research Institute Company Limited Beijing 100081China Beijing Advanced Innovation Center for Materials Genome Engineering Institute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China

In this study,the PH13-8Mo stainless steel parts doped without and with cerium(Ce)were fabricated via laser powder bed fusion followed by post-heat treatment,and systematically compared in terms of microstructure,phase constituent,and tensile *** comparative results show that doping Ce-modified grains with the equiaxed morphology and finer size,increased the mechanical stability of austenite,and enhanced the sphericity of oxide inclusion in the resultant ***,the coherency between the newly-formed CeAlO 3 inclusion and matrix was effectively im proved after doping Ce,as compared to the original aluminum oxide inclusion without doping *** resultant PH13-8Mo parts doped with Ce yielded an ultimate tensile strength of 1446±20 MPa with a fracture elongation of 16.0%±1.5%,for the first time meeting the AMS 5629E H1000 standard for the PH13-8Mo made by additive manufacturing(AM).The enhanced strength results from the strengthening effects of nanoscale precipitation(inclusion)and grain ***,the ductilizing mechanism can be attributed to the enhanced inclusion sphericity and ameliorative coherency between the inclusion and matrix,and improved misorientation angle of grain boundary owing to the modification by Ce,which efficiently re-duced the stress concentration and enhanced cracking resistance during ***,doping rare earth elements presents a promising pathway to synergistically improve the strength and ductility of stainless steels by AM.

关键词： Stainless steel Additive manufacturing Rare earth Precipitation Tensile properties

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The Emergence of Functional Ultrasound for Noninvasive Brain-Computer Interface

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Research 2024年第2期6卷 301-317页

作者： Hairong Zheng Lili Niu Weibao Qiu Dong Liang Xiaojing Long Guanglin Li Zhiyuan Liu Long Meng Institute of Biomedical and Health Engineering Shenzhen Institutes of Advanced TechnologyChinese Academy of SciencesShenzhen518055China Shenzhen Institute of Advanced Integration Technology Chinese Academy of Sciences and The Chinese University of Hong KongShenzhen518055China

A noninvasive brain-computer interface is a central task in the comprehensive analysis and understanding of the brain and is an important challenge in international brain-science *** implanted brain-computer interfaces are cranial and invasive,which considerably limits their *** development of new noninvasive reading and writing technologies will advance substantial innovations and breakthroughs in the field of brain-computer ***,we review the theory and development of the ultrasound brain functional imaging and its ***,we introduce latest advancements in ultrasound brain modulation and its applications in rodents,primates,and human;its mechanism and closed-loop ultrasound neuromodulation based on electroencephalograph are also ***,high-frequency acoustic noninvasive brain-computer interface is prospected based on ultrasound super-resolution imaging and acoustic tweezers.

关键词： breakthrough computer Computer

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