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Recent progress in C-N coupling for electrochemical CO_(2) reduction with inorganic nitrogenous species in aqueous solution

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materials Reports(Energy) 2023年第1期3卷 65-77,I0003页

作者： Shuxia Liu Tanyuan Wang Lior Elbaz Qing Li State Key Laboratory of Material Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhanHubei430074China Department of Chemistry and the Institute of Nanotechnology and Advanced Materials Bar-Ilan UniversityRamat-Gan5290002Israel

The electrocatalytic CO_(2) reduction in aqueous solution mainly involves bond cleavage and formation between C,H and O,and it is highly desirable to expand the bond formation reaction of C with other atoms to obtain novel and valuable *** electrochemical synthesis of N-containing organic chemicals in electrocatalytic CO_(2) reduction via introducing N sources is an effective strategy to expand the product scope,since chemicals con-taining C–N bonds(*** and amines)are important reactants/products for medicine,agriculture and *** article focuses on the research progress of C–N coupling from CO_(2) and inorganic nitrogenous species in aqueous ***,the reaction pathways related to the reaction intermediates for urea,formamide,acetamide,methylamine and ethylamine are ***,the electrocatalytic performance of different catalysts for these several N-containing products are summarized and ***,the challenges and op-portunities are analyzed,aiming to provide general insights into future research directions for electrocatalytic C–N coupling.

关键词： CO_(2) reduction C-N coupling Heterogeneous electrocatalysis Amide Amine

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Excellent Compatibilization Effect of a Dual Reactive Compatibilizer on the Immiscible MVQ/PP Blends

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Chinese Journal of Polymer Science 2023年第7期41卷 1133-1141页

作者： Han-Bin Wang Hong-Chi Tian Shi-Jia Zhang Bing Yu Nan-Ying Ning Ming Tian Li-Qun Zhang Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials Beijing University of Chemical TechnologyBeijing100029China Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical TechnologyBeijing100029China Shandong Dawn Polymer Material Co. Ltd.Longkou265700China

Methyl vinyl silicone rubber (MVQ)/polypropylene (PP) thermoplastic vulcanizate (TPV) combines the good melt processability, recyclability and sealing performance as well as biosafety, stain and fluid resistance, and thus it is especially suitable in bio-safety areas and wearable electronic devices, etc. Nevertheless, the compatibility between MVQ and PP phases is poor. A big challenge on the compatibilization of MVQ/PP blends is that neither MVQ nor PP contains any reactive groups. In this study, a dual reactive compatibilizer composed of ethylenemethyl acrylate-glycidyl methacrylate terpolymer (EMA-co-GMA) and maleic anhydride grafted polypropylene (PP-g-MAH) was designed for the compatibilization of MVQ/PP blends. During melt blending, a copolymer compatibilizer at the MVQ/PP interface can be formed because of the in situ reaction between EMA-co-GMA and PP-g-MAH. The thermodynamic predict of its compatibilization effect through calculating the spreading coefficient of the in situ formed copolymer indicates that it can well compatibilize MVQ/PP blends. The experimental results show that under the GMA/MAH molar ratio of 0.5/1, the interface thickness largely increase from 102 nm for non-compatibilized blend to 406 nm, and the average size of MVQ dispersed phase largely decreases from 2.3 µm to 0.36 µm, the Tg of the two phases shifts toward each other, the mixing torque and mechanical properties of the blend are increased, all indicating its good compatibilization effect. This study provides a good compatibilizing method for immiscible MVQ/PP blends with no reactive groups in both components for the preparation of high performance MVQ/PP TPVs.

关键词： Methyl vinyl silicone rubber(MVQ) Polypropylene(PP) Immiscible polymer blends Reactive compatibilization

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Sodium vanadium oxides:From nanostructured design to high-performance energy storage materials

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Journal of materials Science & Technology 2022年第26期121卷 80-92页

作者： Yifan Dong Shuolei Deng Ziting Ma Ge Yin Changgang Li Xunlong Yuan Huiyun Tan Jing Pan Liqiang Mai Fan Xia Engineering Research Center of Nano-Geomaterials of Ministry of Education Faculty of Material Science and ChemistryChina University of GeosciencesWuhan 430074China State Key Laboratory of Advanced Technology for Materials Synthesis and Processing International School of Materials Science and EngineeringWuhan University of TechnologyWuhan 430070China

Developing high-capacity and low-cost cathode materials for metal-ion rechargeable batteries is the mainstream trend and is also the key to providing breakthroughs in making high-energy rechargeable *** has a variety of valence states and can form a variety of vanadate *** a typical positive electrode material,vanadate has abundant ion adsorption sites,a unique“pillar”framework,and a typical layered ***,it has the advantages of high specific capacity and excellent rate performance,possessing the prospect of being a large-capacity energy storage *** this review,we focus on applications of sodium vanadium oxides(NVO)in electrical energy storage(EES)devices and summarize sodium vanadate materials from three aspects,including crystal structure,electrochemical performance,and energy storage *** recent progress of NVO-based highperformance energy storage materials along with nanostructured design strategies was provided and discussed as *** review is intended to serve as general guidance for researchers to develop desirable sodium vanadate materials.

关键词： Sodium vanadate Nanostructured materials Rechargeable metal-ion batteries Energy storage mechanism

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In situ formed cross-linked polymer networks as dual-functional layers for high-stable lithium metal batteries

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Journal of Energy Chemistry 2023年第4期79卷 253-262页

作者： Lei Shi Wanhui Wang Chunjuan Wang Yang Zhou Yuezhan Feng Tiekun Jia Fang Wang Zhiyu Min Ji Hu Zhigang Xue School of Materials Science and Engineering School of Environmental Engineering and ChemistryLuoyang Institute of Science and TechnologyLuoyang 471023HenanChina Key Laboratory for Material Chemistry of Energy Conversion and Storage Ministry of EducationSchool of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074HubeiChina Key Laboratory of Advanced Materials Processing&Mold(Ministry of Education) National Engineering Research Center for Advanced Polymer Processing TechnologyZhengzhou UniversityZhengzhou 450002HenanChina Henan Intelligent Manufacturing Engineering Technology Research Center for Building Profile Luoyang Institute of Science and TechnologyLuoyang 471023HenanChina Henan Province International Joint Laboratory of Materials for Solar Energy Conversion and Lithium Sodium based Battery Luoyang Institute of Science and TechnologyLuoyang 471023HenanChina

Lithium-metal anodes(LMAs)have been recognized as the ultimate anodes for next-generation batteries with high energy density,but stringent assembly-environment conditions derived from the poor moisture stability dramatically hinder the transformation of LMAs from laboratory to ***,an in situ formed cross-linked polymer layer on LMAs is designed and constructed by a facile thiol-acrylate click chemistry reaction between poly(ethylene glycol)diacrylate(PEGDA)and the crosslinker containing multi thiol groups under UV *** to the hydrophobic nature of the layer,the treated LMAs demonstrate remarkable humid stability for more than 3 h in ambient air(70%relative humidity).The coating humid-resistant protective layer also possesses a dual-functional characterization as solid polymer electrolytes by introducing lithium bis(trifluoromethanesulfonyl)imide in the system in *** intimate contact between the polymer layer and LMAs reduces interfacial resistance in the assembled Li/LiFePO_(4)or Li/LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)full cell effectively,and endows the cell with an outstanding cycle performance.

关键词： Lithium-metal anode Humid-resistant protective film Solid-state polymer electrolytes Cross-linked polymers

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Advancements in heterojunction,cocatalyst,defect and morphology engineering of semiconductor oxide photocatalysts

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Journal of Materiomics 2024年第2期10卷 315-338页

作者： Guojing Wang Shasha Lv Yuanhua Shen Wei Li Linhan Lin Zhengcao Li State Key Laboratory of New Ceramics and Fine Processing Key Laboratory of Advanced Materials(MOE)School of Materials Science and EngineeringTsinghua UniversityBeijing100084China Key Laboratory of Beam Technology and Material Modification Ministry of EducationCollege of Nuclear Science and TechnologyBeijing Normal UniversityBeijing100875China School of Physical Science and Technology Lanzhou UniversityLanzhou730000China Department of Engineering Physics Tsinghua UniversityBeijing100084China State Key Laboratory of Precision Measurement Technology and Instruments Department of Precision InstrumentTsinghua UniversityBeijing100084China

Photocatalytic technology has emerged as a crucial avenue for harnessing solar energy,presenting itself as a viable solution to address the current energy crisis and environmental *** past 50 years have witnessed significant progress and breakthroughs in scientific research on photocatalytic *** paper provides a comprehensive review of the mechanism of photocatalytic technology and methods to improve the photocatalytic efficiency of semiconductor photocatalysts,such as TiO_(2) and *** this paper,common modification methods are divided into four categories:heterojunction con-struction,cocatalysts,defects,and morphological *** origin and development of photo-catalysts in each category are briefly summarized;moreover,the latest progress in each type of modification is discussed.S-scheme heterojunctions retain the high reduction and oxidation capacity of photogenerated electrons and holes by sacrificing half of the photogenerated carriers,showing excellent performance in photocatalysis and great application *** challenges associated with current modification schemes are *** is growing interest in quantitative and atomic-level modu-lation as attractive approaches to tackling these *** the electronic spin state and internal field is important for minimizing photogenerated carrier recombination in *** review will inspire researchers and promote the application of photocatalytic technology.

关键词： Photocatalytic activity Modification Heterostructure Thermal annealing Ion irradiation

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Structure, magnetism and magnetocaloric effects in Er_(5)Si_(3)B_(x)(x=0.3,0.6) compounds

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Chinese Physics B 2023年第11期32卷 575-579页

作者：郝志红刘辉张聚国 School of Rare Earth and New Materials Engineering Gannan University of Science and TechnologyGanzhou 341000China School of Intelligent Manufacturing and Automotive Engineering Gannan University of Science and TechnologyGanzhou Innovation Center of Rare earth Permanent Magnet Material Advanced Manufacturing and Intelligent Equipment TechnologyGanzhou 341000China School of Rare Earth and New Materials Engineering Gannan University of Science and TechnologyGanzhou Key Laboratory of Advanced Processing and Technology Optimization of High Performance Tungsten Base MaterialsGanzhou 341000China

We investigate the structure, magnetic properties, magnetic phase transitions and magnetocaloric effects(MCEs) of Er5Si3Bx(x=0.3,0.6) compounds. The Er5Si3Bx(x = 0.3, 0.6) compounds crystalize in a Mn5Si3type hexagonal structure(space group: P63/cm) and exhibit a successive complicated magnetic phase transition. The extensive magnetic phase transitions contribute to the broad temperature range of MCEs exhibiting in Er_(5)Si_(3)B_(x)(x=0.3,0.6) compounds, with maximum magnetic entropy change(-ΔSM_(max)) and refrigeration capacity of 10.2 J·kg^(-1)·K^(-1), 356.3 J/kg and 11.5 J·kg^(-1)·K^(-1),393.3 J/kg under varying magnetic fields 0–5 T, respectively. Remarkably, the δTFWHMvalues(the temperature range corresponding to 1/2×|-ΔSM_(max)|) of Er5Si3Bx(x=0.3,0.6) compounds were up to 41.8 K and 39.6 K, respectively. Thus, the present work provides a potential magnetic refrigeration material with a broad temperature range MCEs for applications in cryogenic magnetic refrigerators.

关键词： magnetic materials cryogenic magnetic refrigeration magnetic phase transition magnetocaloric effects

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Ultrasensitive conductive hydrogels conferred by nanoscale synergistic effect

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Science China materials 2025年第1期68卷 226-235页

作者： Gangrong Wang Xin Jing Binghan Niu Liya Lin Yaoxun Zhang Jiazhou Zeng Peiyong Feng Yuejun Liu Hao-Yang Mi Key Laboratory of Advanced Packaging Materials and Technology of Hunan Province Hunan University of TechnologyZhuzhou 412007China National&Local Joint Engineering Research Center for Advanced Packaging Material and Technology Hunan University of TechnologyZhuzhou 412007China National Engineering Research Center for Advanced Polymer Processing Technology Zhengzhou UniversityZhengzhou 450000China

The inherent limitations of hydrogels,such as low electrical conductivity and inadequate sensitivity,present considerable challenges in flexible electronic *** address these issues,we proposed an innovative synthesis technique that synergistically leveraged the nanoscale properties of the conductive fillers including one-dimensional polyaniline and two-dimensional reduced graphene oxide to fabricate hydrogels with exceptional *** advanced hydrogel exhibited an extraordinary sensitivity with a gauge factor of 27.55,impressive electrical conductivity(7.2 mS/cm),and outstanding ***,the hydrogel demonstrated excellent self-adhesion and robust selfhealing properties,attributed to its abundant catechol functionalities,hydrogen bonding interactions,andπ-π***,the flexible,strain-sensitive,self-powered sensors derived from these hydrogels displayed unparalleled sensing performance,positioning them as highly promising candidates for advanced human-computer interaction systems and sophisticated information transmission applications.

关键词： conductive hydrogels sodium alginate polyaniline sensitivity reduced graphene oxide

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Pushing the high-k scalability limit with a superparaelectric gate layer

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Journal of advanced Ceramics 2024年第4期13卷 539-547页

作者： Kun Wang Chao Liu Yuan Zhang Fuyu Lv Jun Ouyang Houbing Huang Rui-Long Yang Yu-Yao Zhao Hongbo Cheng Hanfei Zhu Xiaoming Shi Yun Tian Institute of Advanced Energy Materials and Chemistry Jinan Engineering Laboratory for Multi-scale Functional MaterialsSchool of Chemistry and Chemical EngineeringQilu University of Technology(Shandong Academy of Sciences)Jinan 250353China Key Laboratory for Liquid-Solid Structure Evolution and Processing of Materials(Ministry of Education) School of Materials Science and EngineeringShandong UniversityJinan 250061China China Tobacco Shandong Industrial Co. Ltd.Jinan 250104China Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhen 518055China Key Laboratory of Key Film Materials&Application for Equipments(Hunan Province) School of Material Sciences and EngineeringXiangtan UniversityXiangtan 411105China Advanced Research Institute of Multidisciplinary Science and School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Key Laboratory of Magnetic Molecules and Magnetic Information Materials of Ministry of Education School of Chemistry and Materials ScienceShanxi Normal UniversityTaiyuan 030032China

To meet the expectation set by Moore’s law on transistors,the search for thickness-scalable high dielectric constant(k)gate layers has become an emergent research *** investigations have failed to solve the“polarizability–scalability–insulation robustness”*** this work,we show that this trilemma can be solved by using a gate layer of a high k ferroelectric oxide in its superparaelectric(SPE)*** the SPE,its polar order becomes local and is dispersed in an amorphous matrix with a crystalline size down to a few nanometers,leading to an excellent dimensional scalability and a good field-stability of the k *** an example,a stable high k value(37±3)is shown in ultrathin SPE films of(Ba_(0.95),Sr_(0.05))(Zr_(0.2),Ti_(0.8))O_(3)deposited on LaNiO_(3)-buffered Pt/Ti/SiO_(2)/(100)Si down to a 4 nm thickness,leading to a small equivalent oxide thickness of~0.46 *** aforementioned characteristic microstructure endows the SPE film a high breakdown strength(~10.5 MV·cm^(−1)for the 4 nm film),and hence ensures a low leakage current for the operation of the complementary metal oxide semiconductor(CMOS)***,a high electrical fatigue resistance is displayed by the SPE *** results reveal a great potential of superparaelectric materials as gate dielectrics in the next-generation microelectronics.

关键词： high-k transistors Moore's law superparaelectric insulation robustness

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微束等离子体重熔Mg-12Dy-1.1Ni合金的显微组织和腐蚀性能

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Journal of Central South University 2023年第1期30卷 20-34页

作者：姜静陈思琦顾家睿毕广利黄健康李元东陈体军马颖 State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals(Lanzhou University of Technology) Lanzhou 730050China School of Material Science and Engineering Lanzhou University of TechnologyLanzhou 730050China

本文研究了微束等离子体重熔(MPRMed)Mg-12Dy-1.1Ni (wt%)合金的显微组织和腐蚀性能。铸态合金主要由α-Mg相、具有18R-LPSO结构的片层状Mg12DyNi相和Mg24Dy5相组成。经微束等离子体重熔后,铸态合金的晶粒尺寸显著细化至11μm,18R-LPSO... 详细信息

本文研究了微束等离子体重熔(MPRMed)Mg-12Dy-1.1Ni (wt%)合金的显微组织和腐蚀性能。铸态合金主要由α-Mg相、具有18R-LPSO结构的片层状Mg12DyNi相和Mg24Dy5相组成。经微束等离子体重熔后,铸态合金的晶粒尺寸显著细化至11μm,18R-LPSO相体积分数由18.3%增加至26.0%,并呈连续网状分布。电化学和浸泡实验结果表明,在0.1 mol/L NaCl溶液中,MPRMed合金的失重速率(0.31 g/(cm2·d))和腐蚀电流密度(605.3μA/cm2)均低于铸态合金,其中腐蚀电流密度较铸态合金减少了38.5%。该MPRMed合金优异的耐腐蚀性能主要源自于其均匀的显微组织、致密的腐蚀产物和连续分布的18R-LPSO相。

关键词： Mg-Dy-Ni合金微束等离子重熔显微组织 LPSO相腐蚀性能

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Review on incorporation of alkali elements and their effects in Cu(In,Ga)Se_(2)solar cells

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Journal of materials Science & Technology 2022年第1期96卷 179-189页

作者： Yazi Wang Shasha Lv Zhengcao Li State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Key Laboratory of Radiation Beam Technology and Material Modification(MOE) College of Nuclear Science and TechnologyBeijing Normal UniversityBeijing 100875China Key Laboratory of Advanced Materials(MOE) School of Materials Science and EngineeringTsinghua UniversityBeijing 100084Chinaa

Cu(In,Ga)Se_(2)(CIGS)is a promising candidate to replace crystalline silicon solar cells and dominate the photovoltaic market in the *** elements such as sodium(Na),potassium(K),rubidium(Rb),and Cesium(Cs)are commonly accepted as indispensable parts to boost cell efficiencies of CIGS thin-film solar ***,a comprehensive understanding of alkali effects on the electronic and chemical properties of the CIGS layer as well as the underlying mechanisms is of paramount importance for achieving high-performance solar *** paper reviews the development process and incorporation pathways of alkalis and then overviews the roles of different alkali elements and their effects on CIGS cells in ***,the unsolved problems and future development prospects are also ***,the understanding and development of widely adopted alkali-fluoride post-deposition treatments(PDTs)are still underway,and together with newly updated research,it will likely enable the CIGS technology to make the conversion efficiency closer to its theoretical limit.

关键词： Cu(In,Ga)Se_(2)(CIGS) Solar cells Post-deposition treatment(PDT) Alkali effects

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