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Electronic structure engineering of transition metal dichalcogenides for boosting hydrogen energy conversion electrocatalysts

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Chinese Physics B 2024年第9期33卷 13-28页

作者： Bing Hao Jingjing Guo Peizhi Liu Junjie Guo Key Laboratory of Interface Science and Engineering in Advanced Materials Ministry of EducationTaiyuan University of TechnologyTaiyuan 030024China

Electrocatalytic water splitting for hydrogen production is an appealing strategy to reduce carbon emissions and generate renewable *** promising process,however,is limited by its sluggish reaction kinetics and high-cost *** two-dimensional(2D)transition metal dichalcogenides(TMDCs)have presented great potential as electrocatalytic materials due to their tunable bandgaps,abundant defective active sites,and good chemical ***,phase engineering,defect engineering and interface engineering have been adopted to manipulate the electronic structure of TMDCs for boosting their exceptional catalytic ***,it is essential to clarify the local structure of catalytically active sites of TMDCs and their structural evolution in catalytic reactions using atomic resolution electron microscopy and the booming in situ technologies,which is beneficial for exploring the underlying reaction *** this review,the growth regulation,characterization,particularly atomic configurations of active sites in TMDCs are *** significant role of electron microscopy in the understanding of the growth mechanism,the controlled synthesis and functional optimization of 2D TMDCs are *** review will shed light on the design and synthesis of novel electrocatalysts with high performance,as well as prompt the application of advanced electron microscopy in the research of materials science.

关键词： TMDCs STEM hydrogen energy conversion active site identification

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Effect of post rolling stress on phase transformation behavior of microalloyed dual phase steel

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Journal of Iron and Steel Research International 2024年第3期31卷 688-699页

作者： Wen-quan Sun Sheng-yi Yong Tie-heng Yuan Ting-song Yang An-rui He Chao Liu Rui-chun Guo National Engineering Research Center for Advanced Rolling and Intelligent Manufacturing University of Science and Technology BeijingBeijing 100083China

The slow phase transformation of microalloyed dual phase steel makes the nonuniform stress and temperature fields during the post rolling cooling process have a significant impact on the phase transformation *** the relatively slow phase transformation of DP780 steel within the microalloyed dual phase steel series,the influence of stress on the phase transformation behavior of DP780 steel was *** quantify the nonuniform thermal and stress conditions in the steel coil,a thermo-mechanical coupled finite element model of the hot-rolled strip cooling process was *** on the simulation data,DP780 steel was chosen as the research material,and Gleeble 3500 thermal simulation equipment was used for experimental *** thermal expansion curves were analyzed through regression to establish the dynamic model of DP780 steel phase transformation under ***,metallographic analysis was conducted to determine phase transformation type and grain size of DP780 *** results confirmed that the stress promotes the occurrence of semi-diffusion-type bainite ***,an appropriate level of stress facilitates the growth of bainitic grains,while the increased stress inhibits the growth of ferritic grains.

关键词： Microalloyed dual phase steel Stress Bainitic transformation Grain Finite element method

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Cubic hollow porous carbon with defective-edge Fe-N_(4) single-atom sites for high-performance Zn-air batteries

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Journal of Materials Science & technology 2024年第14期181卷 82-90页

作者： Shilong Zhou Chao Chen Jiawei Xia Le Li Xingyue Qian Fengxiang Yin Guohong Dai Guangyu He Qun Chen Haiqun Chen Key Laboratory of Advanced Catalytic Materials and Technology Advanced Catalysis and Green Manufacturing Collaborative Innovation CenterChangzhou UniversityChangzhou 213164China Department of Chemistry and Chemical Engineering Jiangsu University of TechnologyChangzhou 213001China

Regulating the local coordination of Fe active center can further improve the oxygen reduction reaction(ORR)performance of Fe-N-C catalyst to meet the practical application requirements of zinc-air batteries(ZABs).Herein,carbon vacancies modified hollow porous catalysts(C-FeZ8@PDA-950)are constructed by microenvironment modulation,achieving the efficient utilization of active sites and optimization of elec-tronic *** functional theory(DFT)calculations confirm that the defective-edge Fe-N_(4) sites can weaken the adsorption free energy of OH^(∗),and hinder the dissolution of Fe center,significantly accel-erating the ORR process for *** rechargeable liquid ZABs equipped with C-FeZ8@PDA-950 display high specific capacity(819.95 mAh g Zn^(−1))and excellent long-cycling life(over 500 h).Furthermore,the relevant flexible all-solid-state ZABs also display outstanding folding performance under various bending *** work will provide insights into optimizing the electronic structure to improve electrocatalytic performance in the energy conversion and storage area.

关键词： Hollow porous catalyst ORR Defective-edge Fe-N_(4) sites Zn-air battery DFT calculations

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Heterobimetallic[NiCo]integration in a hydrogenase mimic for boosting light-driven hydrogen evolution in CaTiO_(3)

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Nano Research 2024年第8期17卷 6888-6894页

作者： Kang Li Juanji Hong Ningning Song Zhanjun Guo Minmin Liang Experimental Center of Advanced Materials School of Materials Science&EngineeringBeijing Institute of TechnologyBeijing 10081China

Light-drive hydrogen production using titanium-based perovskite is one sustainable way to reduce current reliance on fossil fuels,but its wide applications are still limited by high electron−hole recombination and sluggish surface ***,the developments for low-cost and highly efficient co-catalysts remain *** by natural[NiFe]-hydrogenase active center structure,a hydrogenase-mimic,NiCo_(2)S_(4) nanozyme was synthesized,and subsequently decorated onto the CaTiO_(3) to catalyze the hydrogen evolution reaction(HER).Among the following test,CaTiO_(3)with a 15%loading of NiCo_(2)S_(4) nanozyme exhibited the highest HER rate of 307.76μmol·g^(–1)·h^(–1),which is 60 times higher than that of the CaTiO_(3) *** results reveal that NiCo_(2)S_(4) not only significantly increased the charge separation efficiency of the photogenerated carriers,but also substantively lowered the HER activation *** studies show that NiCo_(2)S_(4) readily splits H_(2)O by forming the Ni(OH)-Co intermediate and only Ni in the bimetallic center alters the oxidation state during the HER process in a manner analogous to the[NiFe]-*** contrast to the often-expensive synthetic catalysts that rely on rare elements such as ruthenium and platinum,this study shows a promising way to develop the nature-inspired cocatalysts to enhance the photocatalysts’HER performance.

关键词： hydrogen evolution reaction hydrogenase-mimic nanozyme photocatalyst water-splitting

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One-pot synthesis of Cu:InP multishell quantum dots for nearinfrared light-emitting devices

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Nano Research 2024年第12期17卷 10655-10660页

作者： Pan Huang Xiaonan Liu Xiao Liu Jing Wei Fangze Liu Hongbo Li Advanced Research Institute of Multidisciplinary Sciences Beijing Institute of TechnologyZhuhai 519088China Advanced Research Institute of Multidisciplinary Sciences Beijing Institute of TechnologyBeijing 100081China Beijing Key Laboratory of Construction-Tailorable Advanced Functional Materials and Green Applications Experimental Center of Advanced MaterialsSchool of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China

InP quantum dots(QDs)are promising heavy-metal-free materials for next-generation solid-state lighting,covering from visible to near-infrared(NIR)*** with the rapid development of visible InP QDs,the synthesis of high-performance NIR InP QDs remains to be *** this work,we report a simple one-pot synthesis of NIR InP QDs by controlling the Cu doping and designing a multishell *** replacing the conventional highly reactive phosphorus precursor with a slightly less reactive and low-cost ammonia phosphorus precursor,the nucleation process is effectively regulated for efficient Cu *** addition,the epitaxial growth of the ZnSe/ZnS shell further improves the stability and optical properties of InP ***,the synthesized Cu:InP/ZnSe/ZnS QDs have a photoluminescence quantum yield of 70%centered at 833 *** NIR InP lightemitting diodes exhibit a maximum radiance of 3.1 W·sr^(-1)·m^(-2)and a peak external quantum efficiency of 2.71%centered at 864 nm.

关键词： near-Infrared InP quantum dots core-shell light-emitting diodes

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Deciphering and overcoming the high-voltage limitations of halide and sulfide-based all-solid-state lithium batteries

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Journal of Energy Chemistry 2025年第4期103卷 926-935页

作者： Xiang Qi Gang Wu Meng Wu Dabing Li Chao Wang Lei Gao Shichao Zhang Li-Zhen Fan Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory for Advanced Energy Materials and TechnologiesUniversity of Science and Technology BeijingBeijing 100083China School of Materials Science and Engineering Beihang UniversityBeijing 100191China

Adopting high-voltage Ni-rich cathodes in halide and sulfide-based all-solid-state lithium batteries(ASSLBs)holds great promise for breaking through the 400 Wh kg^(-1)***,both cell configurations are confronted with intricate interfacial challenges in high-voltage regines(>4.5 V),resulting in inadequate cathode utilization and premature cell ***,contrary to previous studies,coupled with LiNi_(0.85)Co_(0.1)Mn_(0.05)O_(2)cathodes,typical halide(Li_(2)ZrCl_(6))-based cells at 4.5 V feature unlimited interfacial degradation and poor long cycle stability,while typical sulfide(Li_(6)PS_(5)Cl)-based cells feature self-limited interfacial degradation and poor initial cycle ***,this work addresses the high-voltage limitations of Li_(2)ZrCl_(6)and Li_(6)PS_(5)Cl catholyte-based cells by manipulating electrode mass fraction and tailoring interfacial composition,thereby effectively improving interfacial charge-transfer kinetics and(electro)chemical stability within *** appropriate interface design,both optimized cells at 4.5 V demonstrate remarkably increased initial discharge capacities(>195 mA h g^(-1)at0.1 C),improved cycle stabilities(>80%after 600 cycles at 0.5 C),and enhanced rate performances(>115 mA h g^(-1)at 1.0 C).This work deepens our understanding of high-voltage applications for halide/sulfide electrolytes and provides generalized interfacial design strategies for advancing high-voltage ASSLBs.

关键词： All-solid-state lithium batteries Halide solid electrolytes Sulfide solid electrolytes High voltage Interface design

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Pure-quartic soliton molecules in normal fourth-order dispersion regimes based on spectral filtering effect

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Chinese Physics B 2025年第3期34卷 400-406页

作者： Han-Yang Shen Rui-Bo Lan Hong-Bin Hu Yang Li Rui Zhou Zu-Xing Zhang Advanced Photonic Technology Laboratory College of Electronic and Optical Engineering&College of Flexible Electronics(Future Technology)Nanjing University of Posts and TelecommunicationsNanjing 210023China

Recent theoretical verification of self-similar and dissipative pure-quartic solitons(PQSs)emphasized the similarity between PQS lasers and conventional fiber lasers,but the unique equilibrium mechanism hinders the formation of PQS molecules in normal fourth-order dispersion(FOD)*** this paper,we investigated the effect of filters on shaping PQSs in normal FOD based on a passively mode-locked fiber laser model.A bandpass filter eliminates the time pedestal of dissipative PQSs,thus realizing a multi-pulsing *** the filter bandwidth is appropriate,the effective spectral filtering effect can lower the pulse splitting threshold and enable the coherent restoration from chaotic PQSs to PQS ***,changing the central wavelength of the filter can generate PQSs and PQS molecules with asymmetric intensity *** results are important guides for the manipulation of PQSs and the construction of high repetition-frequency fiber lasers.

关键词： pure-quartic soliton soliton molecule spectral filtering effect mode-locked fiber laser

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Innovative Application of Project Integration technology in the Teaching Mode of engineering Drawing Course 24

Innovative Application of Project Integration Technology in ...

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7th International Conference on Educational technology Management, ICETM 2024

作者： Zhang, Runfeng Ming, Yankun Zhang, Guobin Liu, Zhenzhong Wu, Jianguo Tang, Yuxin National Demonstration Center for Exerimenta Mechanica and Electrica Engineering Education Lianin Key Laboratory for Advanced Mechatronic System Design and Intelligent Control School of Mechanical Engineering Tianjin University of Technology Tianjin Tianjin China Tianjin Hanhailanfan Marine Technology Co. Ltd. Tianjin University of Technology Tianjin Tianjin China

ISBN: (纸本)9798400717468

Taking underwater robots project as an example, this paper discusses the innovation of the teaching mode of engineering drawing courses under the guidance of a project. The traditional engineering drawing course often lacks the link of practice and project application, which leads to the lack of students’ understanding and application ability of the course content. Therefore, this study proposes a teaching mode based on project guidance. By using underwater robots as teaching cases, theoretical knowledge and practical application are combined to promote the cultivation of students’ comprehensive abilities. This paper first reviews the research progress in related fields, then introduces the design and implementation methods of the teaching mode in detail, and analyzes the actual effect of the model through the underwater robot case. The results show that the teaching mode of engineering drawing courses under the guidance of the project has a positive impact on students’ learning interest, practical ability and teamwork ability. The results of this study will provide practical and feasible solutions for the innovation of the teaching mode of engineering drawing courses, and also provide a reference for the reform of undergraduate teaching mode in the construction of "New engineering Education". © 2024 Copyright held by the owner/author(s).

关键词： Students

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Structure characterization of the oxide film on FGH96 superalloy powders with various oxidation degrees

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International Journal of Minerals,Metallurgy and Materials 2024年第9期31卷 2037-2047页

作者： Yang Liu Yufeng Liu Sha Zhang Lin Zhang Peng Zhang Shaorong Zhang Na Liu Zhou Li Xuanhui Qu Beijing Advanced Innovation Center for Materials Genome Engineering Institute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China Institute of Materials Intelligent Technology Liaoning Academy of MaterialsShenyang 110004China Science and Technology on Advanced High Temperature Structural Materials Laboratory AECC Beijing Institute of Aeronautical MaterialsBeijing 100095China

The structure of the oxide film on FGH96 alloy powders significantly influences the mechanical properties of *** this study,FGH96 alloy powders with various oxygen contents were investigated using high-resolution transmission electron microscopy and atomic probe technology to elucidate the structure evolution of the oxide *** dispersive spectrometer analysis revealed the presence of two distinct components in the oxide film of the alloy powders:amorphous oxide layer covering the γ matrix and amorphous oxide particles above the *** alloying elements within the oxide layer showed a laminated distribution,with Ni,Co,Cr,and Al/Ti,which was attributed to the decreasing oxygen equilibrium pressure as oxygen diffused from the surface into the γ *** the other hand,Ti enrichment was observed in the oxide particles caused by the oxidation and decomposition of the carbide *** analysis of the oxide film with oxygen contents of 140,280,and 340 ppm showed similar element distributions,while the thickness of the oxide film varies approximately at 9,14,and 30 nm,*** findings provide valuable insights into the structural analysis of the oxide film on FGH96 alloy powders.

关键词： Ni-based superalloys surface structure oxide layer thickness oxidation behavior element distribution

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Multi-Scale Time Series Segmentation Network Based on Eddy Current Testing for Detecting Surface Metal Defects

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IEEE/CAA Journal of Automatica Sinica 2025年第3期12卷 528-538页

作者： Xiaorui Li Xiaojuan Ban Haoran Qiao Zhaolin Yuan Hong-Ning Dai Chao Yao Yu Guo Mohammad S.Obaidat George Q.Huang the School of Intelligence Science and Technology University of Science and Technology Beijing the Beijing Advanced Innovation Center for Materials Genome Engineering the Key Laboratory of Intelligent Bionic Unmanned Systems and the Institute of Materials Intelligent Technology Liaoning Academy of Materials IEEE the Department of Computer Science Hong Kong Baptist University the School of Computer and Communication Engineering Key Laboratory of Advanced Materials and Devices for Post-Moore Chips Ministry of Education University of Science and Technology Beijing the Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology Beijing the School of Computer and Communication Engineering University of Science and Technology Beijing the King Abdullah Ⅱ School of Information Technology The University of Jordan the Department of Computational Intelligence the School of Computing SRM University the School of Engineering The Amity University The Hong Kong Polytechnic University

In high-risk industrial environments like nuclear power plants, precise defect identification and localization are essential for maintaining production stability and safety. However, the complexity of such a harsh environment leads to significant variations in the shape and size of the defects. To address this challenge, we propose the multivariate time series segmentation network(MSSN), which adopts a multiscale convolutional network with multi-stage and depth-separable convolutions for efficient feature extraction through variable-length templates. To tackle the classification difficulty caused by structural signal variance, MSSN employs logarithmic normalization to adjust instance distributions. Furthermore, it integrates classification with smoothing loss functions to accurately identify defect segments amid similar structural and defect signal subsequences. Our algorithm evaluated on both the Mackey-Glass dataset and industrial dataset achieves over 95% localization and demonstrates the capture capability on the synthetic dataset. In a nuclear plant's heat transfer tube dataset, it captures 90% of defect instances with75% middle localization F1 score.

关键词： Eddy current testing nondestructive testing semantic segmentation time series analysis

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