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Regulation of solvation structure and electrochemical performance optimization in Zn（NH2SO3）2-based electrolytes

Journal of Energy Chemistry 2025年第5期104卷 644-654页

作者： Lei Liu Ruxue Yan Songyan Jiang Xiao Liu Zhonghua Zhang Xiaosong Guo Xingguang Liu Jun Zheng Guicun Li College of Materials Science and Engineering Qingdao University of Science and Technology Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials Anhui University of Technology

Monovalent anions,with relatively low charge density,exhibit weak bond energy with Zn2+ions,which facilitates the solubility of Zn salts and the regulation of solvation *** this study,zinc bis（aminosulfate）(Zn（NH2SO3）2) with a monovalent anion,NH2SO3-,was synthesized and dissolved in different ratios of dimethyl sulfoxide （DMSO） and H2O as electrolytes for Zn-ion batteries （ZIBs）.From the perspective of game theory,the influences of DMSO and H2O on the solvation structure and electrochemical performance of the Zn（NH2SO3）2based electrolytes has been meticulously *** and spectra analysis indicate that DMSO molecules are reluctant to penetrate the primary solvation structure of Zn2+***,increasing DMSO in electrolytes can induce a transition from solvent-separated ion pairs （SSIP） to contact ion pairs （CIP）,resulting in an enrichment of anions in the primary solvation *** alteration can significantly suppress parasitic reactions,enhance nucleation density,and refine the deposition morphology during the Zn plating process,leading to superior cyclic stability and high coulombic efficiency （CE） of Zn//Cu and Zn//Zn ***,the enrichment of anions in the primary solvation structure also inhibits the activity of Zn2+ions,amplifies the polarization effect,and engenders a sluggish ionization dynamics,resulting in the low energy conversion efficiency of the *** findings underscore the influence of the anion ratio within the primary solvation structure on electrochemical properties of electrolytes for ZIBs,which may be a pivotal determinant in the Zn deposition process.

关键词： CIP Game theory Impressed current cathodic protection Monovalent anion Primary solvation structure

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Fast deposition of Ni doped YSZ coatings by cathode plasma electrolysis for solid oxide fuel cell applications

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Ceramics International 2025年第13期51卷 17268-17277页

作者： Liu, Chenxu Du, Ke Song, Chen Song, Yang Zhou, Chenchen Zhang, Jin Liu, Min Tian, Yu Meng, Yonggang State Key Laboratory of Tribology in Advanced Equipment Tsinghua University Beijing100084 China Institute of New Materials Guangdong Academy of Sciences National Engineering Laboratory of Modern Materials Surface Engineering Technology Guangdong Provincial Key Laboratory of Modern Surface Engineering Technology Guangdong-Hong Kong Joint Laboratory of Modern Surface Engineering Technology Guangzhou510650 China School of Materials Science and Engineering Nanyang Technological University 639798 Singapore Beijing Key Laboratory for Corrosion Erosion and Surface Technology Institute of Advanced Materials and Technology University of Science and Technology Beijing Beijing100083 China

The fast fabrication of high-quality anode layers of solid oxide fuel cells (SOFCs) is a key factor for their efficient applications. In this work, a one-step method of cathode plasma electrolytic deposition (CPED) is developed to prepare Ni doped YSZ coatings with a thickness of 35–55 μm on porous stainless steel. Compared to the several hours required by traditional methods, a faster coating deposition that only takes 60 s is achieved owing to the effect of enormous energy of plasma arc at the solid-liquid interface in the CPED method. The preparation process is analyzed by recording the variation of current with voltage. The unique micro-structure of the coatings is observed, and the formation mechanism of the Ni doped YSZ coating during the CPED process is proposed. The deposited coatings show an excellent performance as the anode layers for SOFCs, with Sc2O3 stabilized ZrO2 coating prepared by atmospheric plasma spraying as electrolyte and La0.6Sr0.4Co0.2Fe0.8O3-δ as the cathode. The open circuit voltage of the cells reaches 1.000 V and the maximum power density reaches 817.4 mW cm−2 at 800 °C. The finding opens a novel pathway for the efficient preparation of anode materials for SOFCs. © 2025

关键词： Plasma spraying

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Activating lithium storage in 2D CaSi_(2) anode via enhancing pseudocapacitive properties with oxygen modification engineering

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Nano Research 2025年第4期18卷 199-206页

作者： Yongzheng Zhang Lu Sun Kailin Yang Youwang Ye Liang Zhan Qi Wei Jianan Gu Institute of Energy Power Innovation North China Electric Power UniversityBeijing 100096China State Key Laboratory of Chemical Engineering East China University of Science and TechnologyShanghai 200237China State Key Laboratory of Mesoscience and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China Aviation Key Laboratory of Science and Technology on Advanced Surface Engineering AVIC Manufacturing Technology InstituteBeijing 100024China

Silicon(Si)has emerged as a promising anode material for lithium-ion batteries(LIBs)due to its extremely high theoretical capacity of 4200 mAh·g^(-1).However,its practical application is limited by several critical challenges,including severe volume expansion and poor electrical ***,we employ a two-dimensional(2D)oxygen modification engineering approach to fabricate 2D oxygen-functionalized CaSi_(2)(CaSi_(2)O_(x))*** the preparation of 2D CaSi_(2) layers,O atoms are gradually incorporated onto their *** resulting 2D CaSi_(2)O_(x) layers have a thickness of 3-5 nm,closely matching the theoretical thickness of 6-10 *** used as lithium anodes,the 2D CaSi_(2)O_(x) layers exhibit exceptional electrochemical performance,maintaining stability over 3000 cycles at an ultrahigh current density of 30 A·g^(-1).By tailoring the surface properties,their pseudocapacitive charge storage mechanism is significantly enhanced,effectively overcoming the intrinsic limitations of traditional Si *** study highlights the promise of 2D surface engineering in the development of advanced materials for next-generation LIBs.

关键词： two-dimensional(2D)CaSi_(2)O_(x) Si anode volume change pseudocapacitive surface modification lithium storage

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Boosting charge extraction and efficiency of inverted perovskite solar cells through coordinating group modification at the buffer layer/cathode interface

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Nano Research 2025年第1期18卷 415-423页

作者： Zhiqing Liang Ziqiu Ren Ziyu Wang Nan Yan Ling Li Bo Zhang Yanlin Song College of Chemistry Zhengzhou UniversityZhengzhou 450052China Key Laboratory of Applied Surface and Colloid Chemistry Ministry of Education Shaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy Technology School of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119China Key Laboratory of Green Printing Institute of ChemistryChinese Academy of Sciences(ICCAS)Beijing Engineering Research Center of Nanomaterials for Green Printing TechnologyNational Laboratory for Molecular Sciences(BNLMS)Beijing 100190China

In inverted perovskite solar cells (PSCs),effective modification of the interface between the metalcathode and electron transport layer (ETL) is crucial forachieving high performance and stability. Herein, sulfonatedbathocuproine, commonly known as disodium bathocuproinedisulfonate (BCDS), was employed as a cathode buffer layerto address the interfacial issues at the [6,6]-phenyl-C61-butyricacid methyl ester (PCBM)/Ag interface. BCDS possesses theability to form coordinate bonds with Ag electrodes. Theutilization of the BCDS buffer layer enhanced the chargeextraction capability at the cathode interface whilesimultaneously achieving interfacial defect passivation,improving interfacial contact and increasing the built-in electricfield. Consequently, a power conversion efficiency (PCE) of25.06% was achieved. Furthermore, owing to the excellent filmforminguniformity of BCDS on PCBM, the stability of thedevice was also improved. After storage in dry air for morethan 2000 h, the device maintained 96% of its initial efficiency. This work underscores the remarkable potential of tailoringcoordination groups to enhance charge extraction efficiency at the ETL-cathode interface, unveiling a promising newfrontier in buffer layer development and performance optimization strategies for PSCs.

关键词： perovskite solar cells buffer layer bathocuproine disulfonate coordination group modification electron transport layer(ETL)-cathode interface

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Microstructure and mechanical properties of high-pressure sintered B6O-SiC nanocomposites

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材料科学技术（英文版） 2025年第1期204卷 238-244页

作者： Bin Zhang Rongxin Sun Pan Ying Song Zhao Yitong Zou Lei Sun Zihe Li Yufei Gao Mengdong Ma Lingyu Liu Chao Liu Bo Xu Center for High Pressure Science(CHiPS) State Key Laboratory of Metastable Materials Science and TechnologyYanshan UniversityQinhuangdao 066004China National Key Laboratory of Advanced Casting Technologies MIIT Key Laboratory of Advanced Metallic and Intermetallic Materials TechnologyEngineering Research Center of Materials Behavior and DesignMinistry of Education Nanjing University of Science and TechnologyNanjing 210094China Key Laboratory of Materials and Surface Technology(Ministry of Education) School of Materials Science and EngineeringXihua UniversityChengdu 610039China School of Materials Science and Engineering Faculty of Materials Metallurgy and ChemistryJiangxi University of Science and TechnologyGanzhou 341000China

Boron suboxide(B6O)is recognized as a superhard material with a low mass density,high resistance to chemical wear,and excellent wear *** its desirable properties,the limited fracture tough-ness of B6O restricts its application in industrial *** study presents the structural and me-chanical characterization of B6O-SiC nanocomposites,which were synthesized via a high-pressure high-temperature sintering process of B6O powders and SiC *** sintering process induced fragmen-tation of SiC whiskers,resulting in the homogenous distribution of SiC fragments within the B6O *** increase in SiC content was observed to decrease the composite's hardness,while initially reducing then enhancing its *** nanocomposites containing 20 wt％and 30 wt％SiC whiskers exhibited significant improvements in fracture toughness,averaging 6.5 MPa m1/2 and 7.0 MPa m1/2,respectively-approximately threefold the toughness of polycrystalline B6O-while sustaining high hardness values of 36.3 GPa and 35.6 GPa on *** analyses revealed that the composites'superior me-chanical performance is due to the presence of strong grain boundaries,as well as a high density of nan-otwins and stacking *** findings demonstrate a viable method for producing B6O-based nanocom-posites with enhanced hardness and toughness,potentially expanding their industrial applicability.

关键词： B6O Ceramic nanocomposite Mechanical properties Microstructure

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DNA-based recyclable moist-electric generator

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Friction 2025年第2期13卷 57-62页

作者： Tianlei Guang Yaxing Huang Haiyan Wang Tiancheng He Kaixuan Zhu Yujuan Zhang Hongfei Shang Jian Li Huhu Cheng Liangti Qu Laboratory of Flexible Electronics Technology Key Laboratory of Organic Optoelectronics&Molecular EngineeringMinistry of EducationDepartment of ChemistryTsinghua UniversityBeijing 100084China State Key Laboratory of Tribology in Advanced Equipment Tsinghua UniversityBeijing 100084China School of Chemical Engineering and Technology North University of ChinaTaiyuan 030051China State Key Laboratory of Special Surface Protection Materials and Application Technology Wuhan Research Institute of Materials ProtectionWuhan 430000China

Recently developed moist-electric generator(MEG)can spontaneously produce electricity after absorbing water from the air,delivering an interesting and novel power harvesting *** employment of environment-friendly biological substrates in MEGs has demonstrated the favorable electricity generation capacity,however,which always requires a careful cultivation process or gentle storage *** this regard,the extremely abundant DNA formed porous membrance is fabricated to construct a novel recyclable DNA based MEG(DNA-MEG)which produces a stable voltage of ca.0.3 V with a current density of ca.1.2μA·cm−2,as well as a maximum power density of 0.36μW·cm−2 at~90%relative humidity ***,benefited from excellent water-solubility,this freeze-drying DNA membrance can be easily recycled after DNA-MEG damaged and the reborned device still shows favorable electricity generation *** addition,several DNA-MEGs in parallel or series can power up light-emitting diodes and so on for *** stable and recyclable DNA-MEG will provide new insights for moisture power generation device design and enlarge the practical regions greatly.

关键词： moist-electric generator(MEG) DNA biological substrates electricity generation

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Improved surface hydrophobicity of self-assembled transport layers enables perovskite/silicon tandem solar cells with efficiency approaching 31%

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Journal of Energy Chemistry 2025年第5期104卷 749-755页

作者： Jing Yang Jin Wang Biao Shi Yixin Dong Dongxue Liu Shenhzhi Xu Qian Huang Xiaona Du Fu Zhang Miao Yang Yongcai He Bo He Xiaoning Ru Shengzhong Liu Xixiang Xu Pengyang Wang Ying Zhao Xiaodan Zhang Three Gorges Corporation Science and Technology Research Institute Institute of Photoelectronic Thin Film Devices and Technology Renewable Energy Conversion and Storage Center State Key Laboratory of Photovoltaic Materials and CellsNankai University Tianjin Key Laboratory of Efficient Utilization of Solar Energy Haihe Laboratory of Sustainable Chemical Transformations Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) Key Laboratory of Applied Surface and Colloid Chemistry Ministry of Education Shaanxi Key Laboratory for Advanced Energy Devices Shaanxi Engineering Lab for Advanced Energy Technology School of Materials Science and Engineering Shaanxi Normal University LONGi Central R&D Institute LONGi Green Energy Technology Co. Ltd.

[4-（3,6-dimethyl-9H-carbazol-9-yl）butyl]phosphonic acid （Me-4PACz） self-assembled monolayer （SAM）as the hole transport materials have been demonstrated remarkable potential in perovskite solar cells（PSCs）.However,the hydrophobicity of Me-4PACz presents a critical challenge for the fabrication of high-quality perovskite films due to its poor ***,a doped Al2O3with Me-4PACz to modify the Me-4PACz surface was *** one hand,this approach improved the wettability of the Me-4PACz film,enhancing the coverage,uniformity,and buried interface properties of the perovskite *** the other hand,compared to Al2O3modification alone,doping Al2O3with Me-4PACz allowed direct contact between the perovskite and Me-4PACz,resulting in better buried interface *** a result,we achieved an efficiency of 22.71% for single-junction wide-bandgap perovskite solar cells（1.68 eV）.Additionally,the efficiency of perovskite/silicon tandem solar cells was improved from 28.68%to 30.92%,with a significant reduction in ***,the tandem cells demonstrated no degradation after 4200 s of operation at the maximum power point.

关键词： Hydrophic Me-4PACz Perovskite/silicon Tandem solar cell

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Evidence of microstructural evolution linked to non-monotonic distribution of micromechanical properties induced by shot peening

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材料科学技术（英文版） 2025年第4期207卷 238-245页

作者： Guoxin Lu Qiang Wang Bonnie Attard Huhu Su Shijian Zheng Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of EducationSchool of Materials Science and EngineeringShandong UniversityJinan250061China Aviation Key Laboratory of Science and Technology on Advanced Corrosion and Protection for Aviation Material AECC Beijing Institute of Aeronautical MaterialsBeijing100095China Department of Metallurgy and Materials Engineering University of MaltaMSD2080Malta Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology School of Materials Science and EngineeringHebei University of TechnologyTianjin300130China

The residual stress field induced by surface strengthening processes such as mechanical shot peening and other forms of plastic deformation does not generally exhibit a simple"monotonic"distribution *** researchers have analyzed this fact from a mechanical perspective based on Hertz ***,the micro/nano-scale microstructural changes corresponding to the distribution of residual stress fields still appear to be *** this study,we focused on a widely used material in aviation manufacturing,namely nickel-based superalloy GH4169,as our experimental *** subjected GH4169 alloy to me-chanical strengthening treatment using a shot peening intensity of 0.25 mmA,followed by quantitative testing of micromechanical performance indicators such as microhardness and residual *** thor-oughly investigate the relationship between micromechanical properties and microstructure changes,we utilized transmission electron microscopy(TEM)to observe and analyze shot-peened materials at differ-ent *** findings revealed that the most severe microstructural distortion induced by mechanical shot peening in GH4169 alloy was likely to occur within a depth range of 25 to 75 *** observation aligns with the actual phenomenon that the maximum microhardness and maximum residual compres-sive stress did not manifest on the outermost surface of the *** presenting a detailed analysis of deformation defects such as dislocations,stacking faults,and twinning in different depths of mechan-ically strengthened layers,our study contributes to a deeper understanding and practical application of post-processing technologies based on plastic deformation.

关键词： Mechanical shot peening surface strengthening Residual stress Microstructure

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Enhanced room temperature CO2 photoreduction on gas-solid interfaces using nanocrystals integrated with ZIF-8 wrapping design

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材料科学技术（英文版） 2025年第6期209卷 55-63页

作者： Xiaoxiong Hou Zhuangzhuang Ma Zhilei Zhang Xiaotong Gao Hongqiang Wang Lichao Jia Key Laboratory of Applied Surface and Colloid Chemistry Shaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringNational Ministry of EducationShaanxi Normal UniversityXi'an 710119China Beijing National Laboratory for Molecular Sciences Key Laboratory of Organic SolidsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China University of the Chinese Academy of Sciences Beijing 100049China State Key Laboratory of Solidification Processing Center for Nano Energy MaterialsSchool of Materials Science and EngineeringNorthwestern Polytechnical University and Shaanxi Joint Laboratory of GrapheneXi'an 710072China

Composites derived from metal-organic frameworks(MOFs)show promise as catalysts for the photocat-alytic reduction of ***,their potential is hindered by constraints such as limited light absorp-tion and sluggish electron transfer and separation,impacting the overall efficiency of the photocatalytic *** this study,TiO2 nanocrystals,modified with Ptx+,underwent laser etching were encapsulated within the traditional MOF-ZIF-8 *** enhanced the adsorption capabilities for CO2 reactants and solar light,while also facilitating directed electron transfer and the separation of photogenerated *** finely-tuned catalyst demonstrates impressive CH4 selectivity at 9.5％,with yields of 250.24 μmol g-1 h-1 for CO and 25.43 μmol g-1 h-1 for CH4,utilizing water as a hole trap and H+*** study demonstrates the viability of achieving characteristics related to the separation of photogen-erated charges in TiO2 nanocrystals through laser etching and MOF composite *** offers novel perspectives for designing MOF-based catalysts with enhanced performance in artificial photosynthesis.

关键词： CO2 photoreduction Nanocrystals TiO2 ZIF-8 Wrapping structure

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Building Li-S batteries with enhanced temperature adaptability via a redox-active COF-based barrier-trapping electrocatalyst

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Journal of Energy Chemistry 2025年第2期101卷 702-712,I0015页

作者： Jie Xu Acheng Zhu Zhangyu Zheng Yiming Qi Yuwen Cheng Yongjie Cao Bo Peng Lianbo Ma Yonggang Wang School of Materials Science and Engineering Key Laboratory of Efficient Conversion and Solid-state Storage of Hydrogen&Electricity of Anhui ProvinceKey Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials of Ministry of EducationAnhui University of TechnologyMa'anshan 243002AnhuiChina Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Institute of New EnergyiChEM(Collaborative Innovation Center of Chemistry for Energy Materials)Fudan UniversityShanghai 200433China

Covalent organic frameworks(COFs)are promising materials for mitigating polysulfide shuttling in lithium-sulfur(Li-S)batteries,but enhancing their ability to convert polysulfides across a wide temperature range remains a challenge,Herein,we introduce a redox-active COF(RaCOF)that functions as both a physical barrier and a kinetic enhancer to improve the temperature adaptability of Li-S batteries,The RaCOF constructed from redox-active anthraquinone units accelerates polysulfide conversion kinetics through reversible C=O/C-OLi transformations within a voltage range of 1,7 to 2.8 V(***^(+)/Li),optimizing sulfur redox reactions in ether-based *** conventional COFs,RaCOF provides bidentate trapping of polysulfides,increasing binding energy and facilitating more effective polysulfide ***-situ XRD and ToF-SIMS analyses confirm that RaCOF enhances polysulfide adsorption and promotes the transformation of lithium sulfide(Li_(2)S),leading to better sulfur cathode ***,RaCOF-modified Li-S batteries demonstrate low self-discharge(4.0%decay over a 7-day rest),excellent wide-temperature performance(stable from-10 to+60℃),and high-rate cycling stability(94%capacity retention over 500 cycles at 5.0 C).This work offers valuable insights for designing COF structures aimed at achieving temperature-adaptive performance in rechargeable batteries.

关键词： Lithium-sulfur batteries Redox-active property Covalentorganic framework Wide-temperature adaptability

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