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16th International Conference on Quality in Research, QiR 2019

作者： Paduraksa, Jagad Luthfi, Muhammad Verdianto, Ariono Subhan, Achmad Widayatno, Wahyu Bambang Prihandoko, Bambang Kartini, Evvy Hudaya, Chairul Department of Electrical Engineering Faculty of Engineering Universitas Indonesia Depok16424 Indonesia Energy System Engineering Study Program Faculty of Engineering Universitas Indonesia Depok16424 Indonesia Research Center for Physics Indonesian Institute of Sciences PUSPIPTEK SerpongTangerang Selatan15314 Indonesia Center for Science and Technology of Advanced Materials BATAN Kawasan Puspiptek Tangerang15314 Indonesia

ISBN: (纸本)9783035715996

Lithium-Ion Capacitor (LIC) has shown promising performance to meet the needs of high energy and power-density-energy storage system in the era of electric vehicles nowadays. The development of electrode materials and electrolytes in recent years has improvised LIC performance significantly. One of the active materials of LIC electrodes, activated carbon (AC), can be synthesized from various biomass, one of which is the water hyacinth. Its abundant availability and low utilization make the water hyacinth as a promising activated carbon source. To observe the most optimal physical properties of AC, this study also compares various activation temperatures. In this study, full cell LIC was fabricated using LTO based anode, and water hyacinth derived AC as the cathode. The LIC full cell was further characterized to see the material properties and electrochemical performance. Water hyacinth derived LIC can achieve a specific capacitance of 32.11 F/g, the specific energy of 17.83 Wh/kg, and a specific power of 160.53 W/kg. © 2020 Trans Tech Publications Ltd, Switzerland.

关键词： Activated carbon

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Characteristic of beef tallow/rice husk charcoal/plaster composite phase change materials

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AIP Conference Proceedings 2023年第1期2568卷

作者： I. Made Astika I. Nyoman Suprapta Winaya I. Ketut Gede Wirawan Akhmad Herman Yuwono I. Dewa Gede Ary Subagia 1Doctoral Study Program of Engineering Science Faculty of Engineering Udayana University Kampus Sudirman Denpasar Bali 80234 Indonesia. 2Study Program of Mechanical Engineering Faculty of Engineering Udayana University Kampus Bukit Jimbaran Badung Bali 80361 Indonesia 3Department of Metallurgy and Materials Engineering Faculty of Engineering Universitas Indonesia Kampus Baru UI Depok Depok 16424 Indonesia

Composite materials are a combination of several materials to form a new material with specific properties. Chemical compatibility of the constituent materials is a factor that affects the characteristics of composite materials. Currently, composite phase change materials (PCM) are commonly applied as thermal energy storage systems. This study investigated the characteristics of beef tallow/rice husk charcoal/plaster PCM composite. The weight fraction of rice husk charcoal used was 10%. To prevent leakage of beef tallow from the composite structure, the researcher used polyvinyl acetate (PVAc) to cover the tallow/RHC composite before mixing it with plaster material. As much as 30% of the tallow/RHC/PVAc composite weight fraction is integrated into the plaster. PCM composite was made by using a direct incorporation method. The FTIR test results on the PCM composites produced showed good chemical compatibility among different components. The scanning electron microscope results showed the formation of microcapsules where the rice husk charcoal and polyvinyl acetate functions as a wrapper/capsule for beef tallow. This composite is suitable for application in building walls as thermal energy storage.

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Variational quantum circuit-based quantum machine learning approach for predicting corrosion inhibition efficiency of pyridine-quinoline compounds

Materials Today Quantum

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materials Today Quantum 2024年 2卷

作者： Muhamad Akrom Supriadi Rustad Hermawan Kresno Dipojono Study Program in Informatics Engineering Faculty of Computer Science Universitas Dian Nuswantoro Semarang 50131 Indonesia Research Center for Materials Informatics Faculty of Computer Science Universitas Dian Nuswantoro Semarang 50131 Indonesia Quantum and Nano Technologies Research Group Faculty of Industrial Technology Institut Teknologi Bandung Bandung 40132 Indonesia

This work used a variational quantum circuit (VQC) in conjunction with a quantitative structure-property relationship (QSPR) model to completely investigate the corrosion inhibition efficiency (CIE) displayed by pyridine-quinoline compounds acting as corrosion inhibitors. Compared to conventional methods like multilayer perceptron neural networks (MLPNN), the VQC model predicts the CIE more accurately. With a coefficient of determination (R 2 ), root mean square error (RMSE), mean absolute error (MAE), and mean absolute deviation (MAD) values of 0.989, 0.027, 0.024, and 0.019, respectively, VQC performs better. The established VQC model predicts the CIE with outstanding predictive accuracy for four newly synthesized pyrimidine derivative compounds: 1-(4-fluorophenyl)- 3-(4-(pyridin-4-ylmethyl)phenyl)urea (P1) , 1-phenyl-3-(4-(pyridin-4-ylmethyl)phenyl)urea (P2) , 1-(4-methylphenyl)-3-(4-(pyridin-4-ylmethyl)phenyl)urea (P3) , and quaternary ammonium salt dimer (P4) . It generates remarkably high CIE values of 92.87, 94.05, 94.96, and 96.93 for P1, P2, P3, and P4, respectively. With its ability to streamline the testing and production processes for novel anti-corrosion materials, this innovative approach holds the potential to revolutionize the market.

关键词： Variational quantum circuit QSPR Corrosion inhibition Pyridine-quinoline

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Absence of superconductivity in micrometer-sized ɛ-NbN single crystals

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Physical Review B 2022年第17期105卷 174512-174512页

作者： Fan-Yun Chiu Tsu-Lien Hung Cheng-Yen Liu Ya-Hsin Pai Wei-Liang Chien Peng-Jen Chen Ting-Kuo Lee Ming-Jye Wang Min-Nan Ou Chang C. Tsuei Maw-Kuen Wu Chia-Seng Chang Yang-Yuan Chen Department of Physics National Taiwan University Taipei 106319 Taiwan Republic of China Institute of Physics Academia Sinica Taipei 115201 Taiwan Republic of China Nano science and Technology program Taiwan International Graduate Program Taipei 115201 Taiwan Republic of China Department of Materials Science and Engineering National Taiwan University Taipei 106319 Taiwan Republic of China Department of Mechanical Engineering City University of Hong Kong Kowloon Hong Kong SAR China Hong Kong Institute for Advanced Study City University of Hong Kong Kowloon Hong Kong SAR China Department of Physics National Sun Yat-sen University Kaohsiung 804201 Taiwan Republic of China Institute of Astronomy and Astrophysics Academia Sinica Taipei 106319 Taiwan Republic of China Graduate Institute of Applied Physics National Chengchi University Taipei 116011 Taiwan Republic of China

It is important to study the properties of high quality single crystal in order to resolve the issue of an interesting material in which certain debatable fundamental properties exist. However, it is unfortunate that a sizable single crystal for experimental measurements is not always available. NbN is one of the examples; it has attracted scientific and engineering interest due to its diverse physical properties and a variety of structural phases. Until now superconductivity is only observed in cubic δ- and tetragonal γ-NbN but not in hexagonal ɛ-NbN. Recently, Zou et al. reported the observation of superconductivity with Tc∼11.6K in a hexagonal ɛ-NbN based on the measurement on a multiphase powder specimen. In order to resolve the issue, the work used the electron backscattering diffraction technique to characterize phases of micron-size NbN crystals from commercial powders and measure their transport properties. Our results unambiguously confirm that the hexagonal ɛ-NbN phase is not superconducting.

关键词： Electrical conductivity Specific heat Superconductors

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Biomass waste as an alternative source of carbon and silicon-based absorbents for CO2 capturing application

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Chemosphere 2023年 343卷

作者： Suresh, R. Gnanasekaran, Lalitha Rajendran, Saravanan Jalil, A.A. Soto-Moscoso, Matias Khoo, Kuan Shiong Ma, Zengling Halimatul Munawaroh, Heli Siti Show, Pau Loke Departamento de Ingeniería Mecánica Facultad de Ingeniería Universidad de Tarapacá Avda. General Velásquez 1775 Arica Chile University Centre for Research & Development Department of Mechanical Engineering Chandigarh University Punjab Mohali140413 India Department of Chemical Engineering Lebanese American University Byblos Lebanon Centre of Hydrogen Energy Institute of Future Energy Johor UTM Johor Bahru81310 Malaysia Faculty of Chemical and Energy Engineering Universiti Teknologi Malaysia Johor UTM Johor Bahru81310 Malaysia Universidad Autónoma de Chile Chile Department of Chemical Engineering and Materials Science Yuan Ze University Taoyuan Taiwan Centre for Herbal Pharmacology and Environmental Sustainability Chettinad Hospital and Research Institute Chettinad Academy of Research and Education Tamil Nadu Kelambakkam603103 India Zhejiang Provincial Key Laboratory for Subtropical Water Environment and Marine Biological Resources Protection Wenzhou University Wenzhou325035 China Study Program of Chemistry Faculty of Mathematics and Science Education Universitas Pendidikan Indonesia Jalan Dr. Setiabudhi 229 Bandung40154 Indonesia Department of Chemical Engineering Khalifa University P.O. Box 127788 Abu Dhabi United Arab Emirates Department of Chemical and Environmental Engineering Faculty of Science and Engineering University of Nottingham Malaysia Jalan Broga Selangor Darul Ehsan Semenyih Malaysia

The production of low-cost solid adsorbents for carbon dioxide (CO2) capture has gained massive consideration. Biomass wastes are preferred as precursors for synthesis of CO2 solid adsorbents, due to their high CO2 adsorption efficiency, and ease of scalable low-cost production. This review particularly focuses on waste biomass-derived adsorbents with their CO2 adsorption performances. Specifically, studies related to carbon (biochar and activated carbon) and silicon (silicates and geopolymers)-based adsorbents were summarized. The impact of experimental parameters including nature of biomass, synthesis route, carbonization temperature and type of activation methods on the CO2 adsorption capacities of biomass-derived pure carbon and silicon-based adsorbents were evaluated. The development of various enhancement strategies on biomass-derived adsorbents for CO2 capture and their responsible factors that impact adsorbent's CO2 capture proficiency were also reviewed. The possible CO2 adsorption mechanisms on the adsorbent's surface were highlighted. The challenges and research gaps identified in this research area have also been emphasized, which will help as further research prospects. © 2023 Elsevier Ltd

关键词： Carbon dioxide

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A comprehensive approach utilizing quantum machine learning in the study of corrosion inhibition on quinoxaline compounds

Artificial Intelligence Chemistry

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Artificial Intelligence Chemistry 2024年第2期2卷

作者： Muhamad Akrom Supriadi Rustad Hermawan Kresno Dipojono Ryo Maezono Study Program in Informatics Engineering Faculty of Computer Science Universitas Dian Nuswantoro Semarang 50131 Indonesia Research Center for Materials Informatics Faculty of Computer Science Universitas Dian Nuswantoro Semarang 50131 Indonesia Quantum and Nano Technologies Research Group Faculty of Industrial Technology Institut Teknologi Bandung Bandung 40132 Indonesia School of Information Science Japan Advanced Institute of Science and Technology Ishikawa 923-1292 Japan

In this investigation, a quantitative structure-property relationship (QSPR) model coupled with a quantum neural network (QNN) was used to explore the corrosion inhibition efficiency (CIE) of quinoxaline compounds. Integrating quantum chemical properties (QCP) features reduced computational burden by strategically reducing the features from 11 to 4 while maintaining prediction accuracy. QNN models outperform traditional methods like artificial neural networks (ANN) and multilayer perceptron neural networks (MLPNN), with a coefficient of determination (R 2 ) value of 0.987, coupled with diminished root mean square error (RMSE), mean absolute error (MAE), and mean absolute deviation (MAD) values of 0.97, 0.92, and 1.10, respectively. Predictions for six newly synthesized quinoxaline derivatives: quinoxaline-6-carboxylic acid (Q1) , methyl quinoxaline-6-carboxylate (Q2) , (2 E ,3 E )-2,3-dihydrazono-1,2,3,4-tetrahydroquinoxaline (Q3) , (2 E ,3 E ) 2,3-dihydrazono-6-methyl-1,2,3,4-tetrahydroquinoxaline (Q4) , ( E )-3-(4-methoxyethyl)-7-methylquinoxalin-2(1 H)-one (Q5) , and 2-(4-methoxyphenyl)-7-methylthieno[3,2- b ] quinoxaline (Q6) , show remarkable CIE values of 95.12, 96.72, 91.02, 92.43, 89.58, and 93.63 %, respectively. This breakthrough technique simplifies testing and production procedures for new anti-corrosion materials.

关键词： Quantum neural network QSPR Corrosion inhibition Quinoxaline

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Preparation of Nanocellulose-Alginate Nanocomposites for Chlorhexidine Digluconate Drug Carrier 1

Preparation of Nanocellulose-Alginate Nanocomposites for Chl...

引用

1st International Conference on Design and Application of engineering materials 2018, IC-DAEM 2018 in conjunction with 11th Seminar Nasional Metalurgi dan Material, SENAMM 2018

作者： Evelyna, Angela Astifanni, Tiara Khumaira Ruth, Imelda Asri, Lia Purwasasmita, Bambang Sunendar Faculty of Dentistry Maranatha Christian University Indonesia Materials Science and Engineering Bandung Institute of Technology Indonesia Advanced Materials Processing Group Engineering Physics Study Program Bandung Institute of Technology Indonesia Research Center for Nanosciences and Nanotechnology Bandung Institute of Technology Indonesia

Root canal treatment failures generally caused by microorganisms that have ability to invade dentinal tubules. Chlorhexidine is widely known to effectively eradicate broad spectrum bacteria that infected dentinal tubules. The delivery of chlorhexidine to the infected site of root canal still becomes an issue. In order to increase the stability and to regulate the release of chlorhexidine, encapsulation of chlorhexidine digluconate was conducted by employing nanocellulose and alginate nanocomposites. Nanocellulose was prepared from palm kernel cake using acid hydrolysis method. Transmission electron microscopy images showed the formation of whisker and fiber nanocellulose with the average diameter of 20 nm. Resulting nanocellulose was combined with alginate in the presence of Ca2+ crosslinker. Scanning electron microscopy images displayed sphere and oval morphologies of microcapsules with diameter of 500 nm. The microcapsules were further loaded with chlorhexidine digluconate 2% (w/v). In vitro drug release properties were evaluated in PBS at pH 7.4 (normal tooth environment) and at pH 5.5 (infected tooth environment). The UV-VIS results showed that chlorhexidine digluconate has higher release rate at pH 5.5 than at pH 7.4, suggesting that the microcapsule is a good candidate for the delivery of chlorhexidine digluconate to the infected root canal tooth environment. © 2019 Published under licence by IOP Publishing Ltd.

关键词： Alginate

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Fabrication a sustainable adsorbent nanocellulose-mesoporous hectorite bead for methylene blue adsorption

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Case Studies in Chemical and Environmental engineering 2024年 10卷

作者： Holilah Asranudin El Messaoudi, Noureddine Ulfa, Maria Hamzah, Amir Hamid, Zuratul Ain Abdul Ramadhani, Dini Viandi Suryanegara, Lisman Mahardika, Melbi Melenia, Alvina Tata Pratama, Agus Wedi Prasetyoko, Didik Research Center for Biomass and Bioproducts National Research and Innovation Agency of Indonesia (BRIN) Research Collaboration Center for Nanocellulose BRIN-Andalas University Research Collaboration Center for Biomass and Biorefinery Between BRIN and Universitas Padjadjaran Laboratory of Applied Chemistry and Environment Faculty of Sciences Ibn Zohr University Chemistry Education Study Program Faculty of Teacher Training and Education Sebelas Maret University Deputy for Infrastructure Research and Innovation National Research and Innovation Agency of Indonesia (BRIN) School of Materials & Mineral Resources Engineering Universiti Sains Malaysia Department of Biology Faculty of Science and Data Analytics Institut Teknologi Sepuluh Nopember Department of Chemistry Faculty of Science and Data Analytics Institut Teknologi Sepuluh Nopember (ITS) Kampus ITS Sukolilo

In this study, fabrication of mesoporous nanocellulose-hectorite-alginate bead (B-NcH) composites and their application for adsorption of MB from water was carried out. The synthesis of nanocellulose (NC) was conducted from mangosteen waste peel (Garcinia mangostana L.). Garcinia mangostana L. peel had 58.9 ± 0,41 % content of cellulose. NCs was successfully isolated using the acid hydrolysis method. NC from Garcinia mangostana L. peel had a diameter of 24.5 ± 0.2 nm and a length of 381.2 ± 10.4 nm. The superabsorbent was composed of nanocrystalline cellulose, mesoporous hectorite, and alginate. The functional group, phase, and morphology of composite was investigated. The composite with 5 % NC had excellent mechanical strength. The B-NcH5 showed a high adsorption capacity of methylene blue (MB), reaching 98.64 % at an adsorbent dose of 30 mg for 90 min. The presence of hectorite can increase the adsorption ability compared to NCs-alginate. The equilibrium adsorption data followed the Freundlich isotherm;however, the kinetics of adsorption showed the usefulness of adopting the PSO kinetic model. The highest adsorption capacity of B-NcH5 for MB was determined to be 57.59 mg/g. For thermodynamic studies, it was revealed that the adsorption of MB on BNcH-5 is a spontaneous and endothermic process. The removal efficiency was observed in six consecutive cycles, indicating at the favorable reusability of this adsorbent. These results validate the potential use of this B-NcH5 adsorbent for water treatment applications. © 2024

关键词： Adsorption Bead Hectorite Methylene blue Nanocellulose Water treatment

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Critical pore radius and transport properties of disordered hard- and overlapping-sphere models

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Physical Review E 2021年第1期104卷 014127-014127页

作者： Michael A. Klatt Robert M. Ziff Salvatore Torquato Department of Physics Princeton University Princeton New Jersey 08544 USA Institut für Theoretische Physik FAU Erlangen-Nürnberg Staudtstr. 7 91058 Erlangen Germany Center for the Study of Complex Systems and Department of Chemical Engineering University of Michigan Ann Arbor Michigan 48109 USA Department of Chemistry Princeton Institute for the Science and Technology of Materials and Program in Applied and Computational Mathematics Princeton University Princeton New Jersey 08544 USA

Transport properties of porous media are intimately linked to their pore-space microstructures. We quantify geometrical and topological descriptors of the pore space of certain disordered and ordered distributions of spheres, including pore-size functions and the critical pore radius δc. We focus on models of porous media derived from maximally random jammed sphere packings, overlapping spheres, equilibrium hard spheres, quantizer sphere packings, and crystalline sphere packings. For precise estimates of the percolation thresholds, we use a strict relation of the void percolation around sphere configurations to weighted bond percolation on the corresponding Voronoi networks. We use the Newman-Ziff algorithm to determine the percolation threshold using universal properties of the cluster size distribution. The critical pore radius δc is often used as the key characteristic length scale that determines the fluid permeability k. A recent study [Torquato, Adv. Wat. Resour. 140, 103565 (2020)] suggested for porous media with a well-connected pore space an alternative estimate of k based on the second moment of the pore size 〈δ2〉, which is easier to determine than δc. Here, we compare δc to the second moment of the pore size 〈δ2〉, and indeed confirm that, for all porosities and all models considered, δc2 is to a good approximation proportional to 〈δ2〉. However, unlike 〈δ2〉, the permeability estimate based on δc2 does not predict the correct ranking of k for our models. Thus, we confirm 〈δ2〉 to be a promising candidate for convenient and reliable estimates of the fluid permeability for porous media with a well-connected pore space. Moreover, we compare the fluid permeability of our models with varying degrees of order, as measured by the τ order metric. We find that (effectively) hyperuniform models tend to have lower values of k than their nonhyperuniform counterparts. Our findings could facilitate the design of porous media with desirable transport properties via targete

关键词： Geophysical networks materials Patterns in complex systems

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Coulomb interaction-driven reshaped weyl fermionic dispersions in MoTe2

arXiv

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arXiv 2021年

作者： Kang, Seoung-Hun Jeon, Sangjun Kim, Hyun-Jung Ko, Wonhee Cho, Suyeon Kang, Se Hwang Kim, Sung Wng Yang, Heejun Kim, Hyo Won Son, Young-Woo Korea Institute for Advanced Study Seoul02455 Korea Republic of Department of Physics Chung-Ang University Seoul06974 Korea Republic of Peter Grünberg Institute Institute for Advanced Simulation Forschungszentrum Jülich Jülich52428 Germany Samsung Advanced Institute of Technology Suwon16678 Korea Republic of Center for Nanophase Materials Sciences Oak Ridge National Laboratory Oak RidgeTN37831 United States Department of Chemical Engineering and Materials Science Graduate Program in System Health Science and Engineering Ewha Womans University Seoul03760 Korea Republic of Department of Energy Science Sungkyunkwan University Suwon16419 Korea Republic of Department of Physics Korea Advanced Institute of Science and Technology Daejeon34141 Korea Republic of

We report the direct evidence of impacts of the Coulomb interaction in a prototypical Weyl semimetal, MoTe2, that alter its bare bands in a wide range of energy and momentum. Our quasiparticle interference patterns measured using scanning tunneling microscopy are shown to match the joint density of states of quasiparticle energy bands including momentum-dependent self-energy corrections, while electronic energy bands based on the other simpler local approximations of the Coulomb interaction fail to explain neither the correct number of quasiparticle pockets nor shape of their dispersions observed in our spectrum. With this, we predict a transition between type-I and type-II Weyl fermions with doping and resolve its disparate quantum oscillation experiments, thus highlighting the critical roles of Coulomb interactions in layered Weyl semimetals. © 2021, CC BY-NC-ND.

关键词： Dispersions

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