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Tungsten Nitride (W5N6): An Ultraresilient 2D Semimetal

Nano Letters 2024年第1期24卷 67-73页

作者： Chin, Hao-Ting Wang, Deng-Chi Gulo, Desman Perdamaian Yao, Yu-Chi Yeh, Hao-Chen Muthu, Jeyavelan Chen, Ding-Rui Kao, Tzu-Chun Kalbáč, Martin Lin, Ping-Hui Cheng, Cheng-Maw Hofmann, Mario Liang, Chi-Te Liu, Hsiang-Lin Chuang, Feng-Chuan Hsieh, Ya-Ping Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica Taipei10617 Taiwan International Graduate Program of Molecular Science and Technology National Taiwan University Taipei10617 Taiwan Institute of Atomic and Molecular Sciences Academia Sinica Taipei10617 Taiwan Department of Physics National Sun Yat-Sen University Kaohsiung80424 Taiwan Department of Physics National Taiwan Normal University Taipei11677 Taiwan Department of Physics National Taiwan University Taipei10617 Taiwan Institute of Physics Academia Sinica Taipei115201 Taiwan International Graduate Program of Nano Science and Technology National Taiwan University Taipei10617 Taiwan Graduate Institute of Applied Physics National Taiwan University Taipei10617 Taiwan J. Heyrovský Institute of Physical Chemistry Czech Academy of Sciences Dolejškova 2155/3 Prague182 23 Czech Republic Hsinchu300092 Taiwan Physics Division National Center for Theoretical Sciences Taipei10617 Taiwan Center for Theoretical and Computational Physics National Sun Yat-sen University Kaohsiung80424 Taiwan

Two-dimensional transition metal nitrides offer intriguing possibilities for achieving novel electronic and mechanical functionality owing to their distinctive and tunable bonding characteristics compared to other 2D materials. We demonstrate here the enabling effects of strong bonding on the morphology and functionality of 2D tungsten nitrides. The employed bottom-up synthesis experienced a unique substrate stabilization effect beyond van-der-Waals epitaxy that favored W5N6 over lower metal nitrides. Comprehensive structural and electronic characterization reveals that monolayer W5N6 can be synthesized at large scale and shows semimetallic behavior with an intriguing indirect band structure. Moreover, the material exhibits exceptional resilience against mechanical damage and chemical reactions. Leveraging these electronic properties and robustness, we demonstrate the application of W5N6 as atomic-scale dry etch stops that allow the integration of high-performance 2D materials contacts. These findings highlight the potential of 2D transition metal nitrides for realizing advanced electronic devices and functional interfaces. © 2023 American Chemical Society

关键词： Tungsten compounds

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Pathogen inhibition and indication by gelatin nonwoven mats with incorporation of polyphenol derivatives

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RSC Advances 2023年第45期13卷 31602-31615页

作者： Bai, By Meng-Yi Wang, Ting-Teng Chen, Xin-An Wu, Chia-Chun Graduate Institute of Biomedical Engineering and Biomedical Engineering Program Graduate Institute of Applied Science and Technology National Taiwan University of Science and Technology TR-917 AAEON Building No. 43 Keelung Rd. Sec. 4 Da'an Dist. Taiwan Taipei City10607 Taiwan Adjunct Appointment to the National Defense Medical Center Taiwan Taipei11490 Taiwan Institute of Prevention Medicine National Defense Medical Center Taiwan Taipei11490 Taiwan

There is a need for non-pharmaceutical intervention methods that can prevent and indicate the risk of airborne disease spread. In this study, we developed a nonwoven mat based on the polyphenol gallic acid, which can inhibit pathogens growth and also indicate pathogen levels in the surrounding environment. Using nuclear magnetic resonance, Fourier-transform infrared spectroscopy, and high-performance liquid chromatography, we characterized this novel gelatin-based nonwoven mat and investigated the mechanism governing its ability to indicate pathogen levels. We demonstrated that the incorporation of gallic acid serves a vital role in indicating the presence of bacteria, causing the nonwoven mat to change in color from white to brown. We have proposed a plausible mechanism for this color change behavior based on a reaction of gallic acid with components excreted by bacteria, including glutamate, valine, and leucine. The concentrations of these components reflect the bacterial counts, enabling a real-time indication of pathogen levels in the surrounding air. In summary, the nonwoven mat presented herein can serve as an excellent antibacterial agent and as an indicator of nearby bacteria for fabricating personal protection equipment like filtration mask. © 2023 The Royal Society of Chemistry.

关键词： Bacteria

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Investigating Cases and Clusters-Based Reuse Policies for Card-Playing Agents 5

Investigating Cases and Clusters-Based Reuse Policies for Ca...

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5th Annual IEEE Conference on Games, CoG 2023

作者： Paulus, Gustavo B. Vargas, Daniel P. Assuncao, Joaquim V. C. Silva, Luis A. L. Federal Institute of Education Science and Technology of Rio Grande do Sul Ibirubá Brazil Federal University of Santa Maria Graduate Program in Computer Science Santa Maria Brazil Federal University of Santa Maria Applied Computing Department Santa Maria Brazil

ISBN: (纸本)9798350322774

Computer games continue to present challenging experimental fields for developing Artificial Intelligence (AI) models. With Case-Based Reasoning and Clustering, this work proposes novel cases and clusters-based reuse criteria for implementing card-playing agents with diversified playing skills. Using the game of Truco, a common game in South America, we detail how game actions are reused from past cases selected as query answers for given game problems. In doing so, the majority rule, the probability-based lottery, the probability of victory, and the number of points won reuse policies are used to select a cluster of cases. Then these policies are also used to select game actions from the cases within the selected cluster. Investigating the combined exploration of reuse policies, experiments of different natures evaluate the performance of implemented Truco bots disputing matches against each other. Players in these tournaments are equipped with varied policies and use case bases constructed differently. © 2023 IEEE.

关键词： Case based reasoning

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Edible coating from VCO, iota-carrageenan and alginate blends for pindang fish preservation

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Green Materials 2023年第1期13卷 3-16页

作者： Iswahyuni, Hana Suyatma, Nugraha Edhi Wulandari, Nur Irianto, Hari Eko Dewi, Fera Roswita Nurhayati Sinurat, Ellya Nurbayasari, Rodiah Giyatmi Fransiska, Dina Analyst Ministry for Marine Affairs and Fisheries IPB University Bogor Indonesia Master of Food Technology Study Program Graduate School IPB University Bogor Indonesia Department of Food Science and Technology Faculty of Agricultural Engineering and Technology IPB University Bogor Indonesia Research Center for Marine and Land Bioindustry National Research and Innovation Agency of the Republic of Indonesia Lombok Indonesia Food Technology Study Program Faculty of Food Technology and Health Sahid University Jakarta Indonesia Research Center for Applied Microbiology National Research and Innovation Agency of the Republic of Indonesia Cibinong Indonesia

This study aims to develop an edible coating based on virgin coconut oil (VCO) nanoemulsion, iota-carrageenan and alginate to prolong the shelf life of pindang (mildly salted cooked) fish products. The research involved three stages: material preparation, characterization and determination of factors and responses for experimental design;parameter optimization to achieve optimal conditions;and application and analysis of pre- and post-coating characteristics of pindang fish. The parameter ranges were 0.5–1.5% for alginate concentration, 0.5–1.5% for iota-carrageenan concentration and 0.5–1.0% for VCO nanoemulsion concentration. The result of this study was an optimized food coating solution that was clear and bright white in color. Pindang fish coated with this layer showed improved quality in terms of water content (48.46%), weight loss (0.39%), pH (5.84), total volatile base (47.01%), salt content (2.9%), appearance (7), texture (7) and slime (7). At the same time, the total bacterial count remained unchanged (8 log colony-forming units (CFU)/g), the mold count remained unchanged (5 log CFU/g) and the aroma and taste received a score of 6. Thus, this study successfully produced an optimized edible coating that can enhance the quality and extend the shelf life of pindang fish, making it suitable for broader market distribution. © 2023 ICE Publishing. All rights reserved.

关键词： Fish

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Advanced TiO2/Al2O3 Bilayer ALD Coatings for Improved Lithium-Rich Layered Oxide Electrodes

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ACS applied Materials and Interfaces 2024年第10期16卷 13029-13040页

作者： Chen, Wei-Ming Hsieh, Hsin-Yu Wu, Dong-Ze Tang, Horng-Yi Chang-Liao, Kuei-Shu Chi, Po-Wei Wu, Phillip M. Wu, Maw-Kuen Institute of Physics Academia Sinica 128 Section 2 Academia Road Taipei11529 Taiwan Nano Science and Technology Program Taiwan International Graduate Program Academia Sinica and National Tsing Hua University 128 Section 2 Academia Road Taipei11529 Taiwan Department of Engineering and System Science National Tsing Hua University 101 Section 2 Kuang-Fu Road Hsinchu300044 Taiwan Graduate Institute of Energy and Sustainability Technology National Taiwan University of Science and Technology 43 Keelung Road Sec 4 Taipei10607 Taiwan Department of Applied Chemistry National Chi Nan University 1 University Road Puli Nantou545301 Taiwan College of Science National Chung Hsing University 145 Xingda Rd. South Dist. Taichung City402 Taiwan

Surface modification is a highly effective strategy for addressing issues in lithium-rich layered oxide (LLO) cathodes, including phase transformation, particle cracking, oxygen gas release, and transition-metal ion dissolution. Existing single-/double-layer coating strategies face drawbacks such as poor component contact and complexity. Herein, we present the results of a low-temperature atomic layer deposition (ALD) process for creating a TiO2/Al2O3 bilayer on composite cathodes made of AS200 (Li1.08Ni0.34Co0.08Mn0.5O2). Electrochemical analysis demonstrates that TiO2/Al2O3-coated LLO electrodes exhibit improved discharge capacities and enhanced capacity retention compared with uncoated samples. The TAA-5/AS200 bilayer-coated electrode, in particular, demonstrates exceptional capacity retention (∼90.4%) and a specific discharge capacity of 146 mAh g-1 after 100 cycles at 1C within the voltage range of 2.2 to 4.6 V. The coated electrodes also show reduced voltage decay, lower surface film resistance, and improved interfacial charge transfer resistances, contributing to enhanced stability. The ALD-deposited TiO2/Al2O3 bilayer coatings exhibit promising potential for advancing the electrochemical performance of lithium-rich layered oxide cathodes in lithium-ion batteries. © 2024 The Authors. Published by American Chemical Society.

关键词： Cathodes

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Influence of Ru-substitution on the performance of pyrochlore catalysts in oxidative steam reforming of ethanol

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Sustainable Energy and Fuels 2024年第9期8卷 2104-2114页

作者： Huang, Yu-Hsuan Hsieh, Ho-Chen Wang, Yun-Hsin Weng, Sheng-Feng Lee, Chi-Shen Department of Applied Chemistry National Yang Ming Chiao Tung University 1001 University Rd Hsinchu 30010 Taiwan Graduate Degree Program of Science and Technology of Accelerator Light Source National Yang Ming Chiao Tung University Hsinchu 30010 Taiwan Center for Emergent Functional Matter Science National Chiao-Tung University Hsinchu 30010 Taiwan

This study introduces a series of Ru-substituted pyrochlore catalysts, achieved by using La2Zr2−xRuxO7−δ (LZRO-00-04, x = 0.0-0.4) during the oxidative steam reforming of ethanol reaction (OSRE). The samples were cha...

This study introduces a series of Ru-substituted pyrochlore catalysts, achieved by using La₂Zr_2−xRu_xO_7−δ (LZRO-00-04, x = 0.0-0.4) during the oxidative steam reforming of ethanol reaction (OSRE). The samples were characterized using X-ray diffraction (XRD), temperature programmed reduction (TPR), and X-ray photoelectron spectroscopy (XPS). The reduction behavior and catalytic performance correlate directly with the Ru content. The 5 wt% LZRO02 catalytic system outperforms the supported Ru-based catalyst (5 wt% RuO₂/LZO), boasting lower Ru concentrations (2.66 wt%). The enhancement is attributed to the uniform dispersion of Ru ≥ 4+ ions embedded within the pyrochlore structure, as convincingly supported by the XPS result. This underscores notable distinctions between the internal and external structures of the two systems. On the other hand, our extensive long-term testing of LZRO02 across γ-Al₂O₃ and lab-made LZO carriers, coupled with meticulous mapping and Raman analysis, revealed a significant observation: the catalyst exhibits notably reduced aggregation tendencies and enhanced activity when utilized on the LZO carrier. The La₂Zr_1.8Ru_0.2O_7−δ catalyst supported on LZO demonstrated selectivity of hydrogen S_H = 86.4(1)%;Y_H = 2.55(3) (mol/mol EtOH) for long-term stability tests at T = 400 °C, C/O = 0.6, and O₂/C₂H₅OH = 1.5. This discovery underscores the catalyst's remarkable stability and activity, making it a promising candidate for catalytic applications. © 2024 The Royal Society of Chemistry.

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Detection of Femtomolar Amyloid-β Peptides for Early-Stage Identification of Alzheimer’s Amyloid-β Aggregation with Functionalized Gold Nanoparticles

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ACS applied Materials and Interfaces 2024年第3期16卷 3819-3828页

作者： Chang, Yu-Jen Chien, Yi-Hsin Chang, Chieh-Chun Wang, Pei-Ning Chen, Yun-Ru Chang, Yun-Chorng Genomics Research Center Academia Sinica Taipei115 Taiwan Taiwan International Graduate Program in Interdisciplinary Neuroscience National Taiwan University and Academia Sinica Taipei115 Taiwan Research Center for Applied Sciences Academia Sinica Taipei115 Taiwan Department of Physics National Taiwan University Taipei106 Taiwan Nano Science and Technology Program Taiwan International Graduate Program Academia Sinica and National Taiwan University Taipei115 Taiwan Brain Research Center National Yang Ming Chiao Tung University Taipei112 Taiwan Division of General Neurology Department of Neurological Institute Taipei Veterans General Hospital Taipei112 Taiwan

Progressive amyloid-β (Aβ) fibrillar aggregates have long been considered as the pathogenesis of Alzheimer’s disease (AD). Biocompatible and stable cysteine-Aβ peptide-conjugated gold nanoparticles (Cys-Aβ@AuNP) are demonstrated as suitable materials for detecting subfemtomolar Aβ peptides in human plasma. Incubation with Aβ peptides causes the Cys-Aβ@AuNP to aggregate and changes its absorption spectra. The spectral change is especially apparent and noticeable when detecting subfemtomolar Aβ peptides, and the aggregates contain only two or three AuNPs. Cys-Aβ@AuNP can also be used to identify early-stage Aβ oligomerization, which is not possible using the conventional method, in which the fluorescence of thioflavin-T is measured. The ability to detect Aβ oligomerization can facilitate therapeutics for AD. In addition, the binding of Aβ peptides by Cys-Aβ@AuNP in combination with centrifugation redirects the conventional Aβ aggregation pathway and can effectively inhibit the formation of toxic Aβ oligomers or fibrils. Therefore, the proposed Cys-Aβ@AuNP can also be used to develop effective therapeutic agents to inhibit Aβ aggregation. The results obtained in this study are expected to open revolutionary ways to both detect and inhibit Aβ aggregation at an early stage. © 2024 American Chemical Society

关键词： Oligomers

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A versatile in situ cofactor enhancing system for meeting cellular demands for engineered metabolic pathways

A versatile in situ cofactor enhancing system for meeting ce...

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作者： Jaroensuk, Juthamas Sutthaphirom, Chalermroj Phonbuppha, Jittima Chinantuya, Wachirawit Kesornpun, Chatchai Akeratchatapan, Nattanon Kittipanukul, Narongyot Phatinuwat, Kamonwan Atichartpongkul, Sopapan Fuangthong, Mayuree Pongtharangkul, Thunyarat Hollmann, Frank Chaiyen, Pimchai Rayong Thailand Faculty of Science Department of Biochemistry and Center for Excellence in Protein and Enzyme Technology Mahidol University Bangkok Thailand Program in Applied Biological Sciences Chulabhorn Graduate Institute Bangkok Thailand Laboratory of Biotechnology Chulabhorn Research Institute Bangkok Thailand Faculty of Science Department of Biotechnology Mahidol University Bangkok Thailand Department of Biotechnology Delft University of Technology Delft Netherlands

Cofactor imbalance obstructs the productivities of metabolically engineered cells. Herein, we employed a minimally perturbing system, xylose reductase and lactose (XR/lactose), to increase the levels of a pool of sugar phosphates which are connected to the biosynthesis of NAD(P)H, FAD, FMN, and ATP in Escherichia coli. The XR/lactose system could increase the amounts of the precursors of these cofactors and was tested with three different metabolically engineered cell systems (fatty alcohol biosynthesis, bioluminescence light generation, and alkane biosynthesis) with different cofactor demands. Productivities of these cells were increased 2-4-fold by the XR/lactose system. Untargeted metabolomic analysis revealed different metabolite patterns among these cells, demonstrating that only metabolites involved in relevant cofactor biosynthesis were altered. The results were also confirmed by transcriptomic analysis. Another sugar reducing system (glucose dehydrogenase) could also be used to increase fatty alcohol production but resulted in less yield enhancement than XR. This work demonstrates that the approach of increasing cellular sugar phosphates can be a generic tool to increase in vivo cofactor generation upon cellular demand for synthetic biology. © 2023 The Authors

关键词： Biosynthesis

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The core morning clock component CCA1 enhances UPR target gene expression to facilitate ER stress recovery

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Plant Communications 2025年第4期6卷 234-247页

作者： Gyeongik Ahn In Jung Jung Gyeong-Im Shin Song Yi Jeong Myung Geun Ji Jin-Sung Huh Ji-Won Hwang Jeongsik Kim Joon-Yung Cha Sang Yeol Lee Min Gab Kim Woe-Yeon Kim Division of Applied Life Science(BK21 Four) PBRRCPMBBRCRILS&IALSGyeongsang National UniversityJinju 52828Republic of Korea National Institute of Wildlife Disease Control and Prevention(NIWDC) Ministry of EnvironmentGwangju 62407Republic of Korea Faculty of Science Education and Interdisciplinary Graduate Program in Advanced Convergence Technology and Science Jeju National UniversityJeju 63243Republic of Korea College of Pharmacy and Research Institute of Pharmaceutical Science PMBBRCGyeongsang National UniversityJinju 52828Republic of Korea

The endoplasmic reticulum(ER)is a cellular organelle responsible for protein synthesis and *** its protein folding capacity is exceeded,unfolded or misfolded proteins accumulate,causing ER stress and triggering the unfolded protein response(UPR)to restore ER *** UPR gene expression in plants follows a diel cycle,the mechanisms by which the circadian clock regulates these genes remain ***,we demonstrate that sensitivity to ER stress in root growth exhibits time-of-day phases and that the circadian clock regulates UPR target gene expression during ER ***,mutations in the core morning clock component CIRCADIAN CLOCK ASSOCIATED 1(CCA1)impair ER stress ***1 forms a complex with the UPR modulator basic leucine zipper 28(bZIP28)and acts as an upstream regulator of ER stress *** ER stress,CCA1 is stabilized and associates with bZIP28 at the ER stress response element within the BiP3 promoter,enhancing the ER stress ***,CCA1 and bZIP28 coordinate a time-dependent adaptive response to ER stress to maintain ER *** re-sults suggest that the circadian clock primes the timing and levels of ER chaperone expression to enhance ER stress tolerance.

关键词： circadian clock ER stress ER chaperone CCA1 bZIP28

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Cascaded-Type Band Alignment of a WBG Perovskite/NBG Perovskite For Heterostructure Solar Cells

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ACS applied Energy Materials 2024年第8期7卷 3039-3048页

作者： Thakran, Anjali Mohapatra, Anisha Verma, Hemant Hofmann, Mario Ansari, Zeeshan Alam Hanmandlu, Chintam Lu, Chung Hsin Chu, Chih Wei Department of Physics National Taiwan University Taipei106 Taiwan Research Center for Applied Sciences Academia Sinica 128 Academia Road Section 2 Nangang Taipei11529 Taiwan Nano-Science and Technology Program Taiwan International Graduate Program Academia Sinica Taipei106 Taiwan Department of Chemical Engineering National Taiwan University Taipei106 Taiwan Department of Photonics National Yang Ming Chiao Tung University Hsinchu City30010 Taiwan College of Engineering Center for Green Technology Chang Gung University Taoyuan City333002 Taiwan

The performance of single-junction mixed-halide perovskite-based solar cells is limited by thermalization and spectral losses. With advanced device architectures, the perovskite/perovskite heterostructure, where two or more photoactive layers are stacked together, can help to minimize these losses. In this work, we conformally transfer printed a narrow-band-gap perovskite over a spin-coated wide-band-gap perovskite layer to form a perovskite/perovskite heterostructure. This heterostructure results in broader spectral coverage and the higher position of the lowest unoccupied molecular orbital (LUMO) level of MAPbBrxI3-x compared to MA0.7FA0.3Pb0.5Sn0.5I3, forming a cascaded energy level alignment between photoactive layers. Additionally, direct evidence of improved morphology has been observed with the transfer-printing technique in heterostructure formation. The bottom layer provides favorable assistance for the growth of the top perovskite near the interface with good coverage and maintains the quality of the film. Thus, the increased crystallinity and reduced grain boundaries lead to less defects. This reduction played a key role in suppressing recombination losses at the interfaces, ultimately leading to improved device performance. These inherent properties have a positive impact on the photovoltaic response of the device, resulting in broader spectral response and power conversion efficiencies (PCEs) of 14.76% in the heterostructure device. A notable improvement is achieved compared to control single-junction devices, which typically have a PCE of nearly 10% with printed-Sn and 12% with spin-Br-based devices. Moreover, the heterostructure-based device exhibits high stability, retaining almost 80% of its initial PCE value for almost 1000 h with proper encapsulation. Our technique can be utilized for designing low-temperature and solution-processed stacked layers, applicable for optoelectronic devices, including light-emitting diodes (LEDs), sensors, and transist

关键词： Perovskite

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